ChemicalBook > CAS DataBase List > H-D-TYR-OME HCL

H-D-TYR-OME HCL

Product Name
H-D-TYR-OME HCL
CAS No.
3728-20-9
Chemical Name
H-D-TYR-OME HCL
Synonyms
H-D-Tyr-OMe;D-Tyr-OMe·HCl;H-D-TYR-OME HCL;H-D-Tyr-OMe·HCI;H-D-Try-OMe-HCl;D-TYROSINE-OME HCL;Tirofiban Impurity 45;D-TYROSINE ETHYL OME HCl;H-D-Tyr-OMe hydrochloride;H-D-TYR-OME HCL USP/EP/BP
CBNumber
CB0268840
Molecular Formula
C10H14ClNO3
Formula Weight
231.68
MOL File
3728-20-9.mol
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H-D-TYR-OME HCL Property

Melting point:
177-179℃
storage temp. 
Inert atmosphere,2-8°C
solubility 
Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form 
Powder
color 
White to off-white
CAS DataBase Reference
3728-20-9(CAS DataBase Reference)
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Safety

HS Code 
2922500090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
M332530
Product name
MethylD-TyrosinateHydrochloride
Packaging
2.5g
Price
$130
Updated
2021/12/16
TRC
Product number
M332530
Product name
MethylD-TyrosinateHydrochloride
Packaging
10g
Price
$165
Updated
2021/12/16
Usbiological
Product number
237261
Product name
D-Tyrosine methyl ester hydrochloride 98+%
Packaging
5g
Price
$170
Updated
2021/12/16
Usbiological
Product number
290842
Product name
D-Tyrosine methyl ester hydrochloride
Packaging
5g
Price
$380
Updated
2021/12/16
Chem-Impex
Product number
03900
Product name
D-Tyrosinemethylesterhydrochloride,≥98%(HPLC)
Purity
≥98%(HPLC)
Packaging
5G
Price
$17.47
Updated
2021/12/16
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H-D-TYR-OME HCL Chemical Properties,Usage,Production

Chemical Properties

Crystalline

Uses

D-Tyrosine methyl ester hydrochloride is an intermediate in the synthesis of oxybutynin chloride (O868525), an inhibitor of proliferation and supresses gene expression in bladder smooth muscle cells.

Synthesis

67-56-1

556-02-5

3728-20-9

General procedure for the synthesis of methyl (R)-2-amino-3-(4-hydroxyphenyl)propanoate hydrochloride from methanol and D-tyrosine: (2R)-2-amino-3-(4-hydroxyphenyl)propanoic acid (49) (1.07 g, 5.9 mmol) was dissolved in methanol, and the reaction was completed to give methyl (2R)-2-amino-3-(4-hydroxyphenyl)propanoate (50) . The product characterization data were as follows: melting point 176°C (literature values in agreement); 1H NMR (DMSO-d6) δ: 6.82 (d, J = 8.4 Hz, 2H, ArH3' and ArH5'), 4.13 (t, J = 6.9 Hz, 1H, H2), 3.83 (s, 3H, OCH3), 3.22 (dd, J = 6.0, 14.4 Hz. 1H, 3Ha), 3.12 (dd, J = 6.9, 14.7 Hz, 1H, 3Hb). Mass spectrum (chemical ionization, positive ion mode) m/z: 196 (100%) [M+]. High Resolution Mass Spectrometry (HRMS) calculated value of C10H14NO3: 196.0974, measured value: 196.0985.

References

[1] Organic Letters, 2002, vol. 4, # 2, p. 265 - 267
[2] Organic and Biomolecular Chemistry, 2007, vol. 5, # 4, p. 636 - 643
[3] Patent: WO2006/74501, 2006, A1. Location in patent: Page/Page column 152
[4] Tetrahedron, 2008, vol. 64, # 49, p. 11270 - 11290
[5] Organic and Biomolecular Chemistry, 2005, vol. 3, # 7, p. 1233 - 1239

H-D-TYR-OME HCL Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from H-D-TYR-OME HCL manufacturers

Hebei Fengjia New Material Co., Ltd
Product
H-D-TYR-OME HCL 3728-20-9
Price
US $3.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
1000
Release date
2024-09-05
Hebei Chuanghai Biotechnology Co., Ltd
Product
H-D-TYR-OME HCL 3728-20-9
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-21
Sichuan HongRi Pharma-Tech Co.,Ltd
Product
D-Tyr-Ome.Hcl 3728-20-9
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1T+
Release date
2024-04-02

3728-20-9, H-D-TYR-OME HCLRelated Search:

D-TYROSINE ETHYL ESTER HYDROCHLORIDE D-Tyrosine H-D-TYR-OTBU (R)-2-AMino-3-(4-hydroxyphenyl)propanaMide hydrochloride D-TYROSINE-OBZL P-TOSYLATE H-D-TYR-OME HCL H-L-TYR-OME HCL,H-TYR-OME HCL H-D-TYR(ALL)-OME HCL METHYL (2R)-2-AMINO-3-(2-CHLORO-4-HYDROXYPHENYL)PROPANOATE METHYL (2R)-2-AMINO-3-(3-CHLORO-4-METHOXYPHENYL)PROPANOATE H-3,5-DIIODO-TYR-OME HCL,H-D-3,5-DIIODO-TYR-OME HCL H-DL-TYR-OME HCL METHYL (2R)-2-AMINO-3-(3-CHLORO-4-HYDROXYPHENYL)PROPANOATE H-D-TYR(TBU)-ALLYL ESTER HCL Boc-Tyr-Ome·HCl N-ME-TYR-OME HCL N-ME-DL-TYR-OME HCL H-LEU-LEU-LEU-TYR-OME HCL

  • (R)-Methyl 2-aMino-3-(4-hydroxyphenyl)propanoate hydrochloride
  • H-D-Tyr-OMe hydrochloride
  • H-D-Tyr-OMe
  • D-Tyr-OMe·HCl
  • D-Tyrosine methyl ester hydrochloride≥ 98% (HPLC)
  • D-TYROSINE ETHYL OME HCl
  • Methyl D-Tyrosinate Hydrochloride,99%e.e.
  • H-D-TYR-OME HCL
  • D-TYROSINE METHYL ESTER HYDROCHLORIDE
  • D-TYROSINE-OME HCL
  • METHYL D-TYROSINATE HYDROCHLORIDE
  • H-D-Tyr-OMe·HCI
  • D-Tyrosine Methyl Ester HCl
  • H-D-Try-OMe-HCl
  • (2R)-2-amino-3-(4-hydroxyphenyl)propionic acid methyl ester hydrochloride
  • methyl (2R)-2-amino-3-(4-hydroxyphenyl)propanoate hydrochloride
  • methyl (2R)-2-azanyl-3-(4-hydroxyphenyl)propanoate hydrochloride
  • H-D-Tyr-OMe·HCl D-Tyrosine Methyl ester hydrochloride
  • D-Tyrosine methyl ester hydrochloride 98+%
  • D-Tyrosine, methylester, hydrochloride (1:1)
  • Tirofiban Impurity 45
  • H-D-TYR-OME HCL USP/EP/BP
  • D-Tyrosine, methyl ester, hydrochloride (9CI)
  • Ethyl Acetate Impurity 36
  • Methyl (R)-2-amino-3-(4-hydroxy-phenyl)-propanoate HCl
  • 3728-20-9
  • C10H14ClNO3
  • Amino Acids and Derivatives
  • Amino hydrochloride
  • Amino Acid Derivatives