4-Iodobenzotrifluoride

ChemicalBook > CAS DataBase List > 4-Iodobenzotrifluoride

4-Iodobenzotrifluoride

Product Name: 4-Iodobenzotrifluoride
CAS No.: 455-13-0
Chemical Name: 4-Iodobenzotrifluoride
Synonyms: 1-IODO-4-(TRIFLUOROMETHYL)BENZENE;4-(TRIFLUOROMETHYL)IODOBENZENE;4-IodobenzotrifL;BUTTPARK 45\01-80;4-Iodobenztrifluoride;P-IODOBENZOTRIFLUORIDE;4-IODOBENZOTRIFLUORIDE;Iodine benzotrifluoride;P-IODO TRIFLUORO TOLUENE;p-Iodine Trifluoro Toluene
CBNumber: CB0277912
Molecular Formula: C7H4F3I
Formula Weight: 272.01
MOL File: 455-13-0.mol

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4-Iodobenzotrifluoride Property

Melting point:: -8.33 °C (lit.)
Boiling point:: 185-186 °C/745 mmHg (lit.)
Density: 1.851 g/mL at 25 °C (lit.)
refractive index: n20/D 1.516(lit.)
Flash point:: 156 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: Liquid
color: Clear pale yellow to yellow or red
Specific Gravity: 1.851
Water Solubility: Insoluble in water.
Sensitive: Light Sensitive
BRN: 1944013
InChIKey: UDHAWRUAECEBHC-UHFFFAOYSA-N
CAS DataBase Reference: 455-13-0(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, 1-iodo-4-(trifluoromethyl)-(455-13-0)
EPA Substance Registry System: 4-Iodobenzotrifluoride (455-13-0)

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Safety

Hazard Codes: Xi,T
Risk Statements: 36/37/38
Safety Statements: 26-36-37/39
RIDADR: 1760
WGK Germany: 3
Hazard Note: Toxic/Irritant
TSCA: T
HazardClass: 8
PackingGroup: III
HS Code: 29039990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 365858
Product name: 4-Iodobenzotrifluoride
Purity: 97%
Packaging: 1g
Price: $36.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 365858
Product name: 4-Iodobenzotrifluoride
Purity: 97%
Packaging: 5g
Price: $92.1
Updated: 2024/03/01

TCI Chemical

Product number: I0550
Product name: 4-Iodobenzotrifluoride (stabilized with Copper chip)
Purity: >97.0%(GC)
Packaging: 5g
Price: $61
Updated: 2024/03/01

TCI Chemical

Product number: I0550
Product name: 4-Iodobenzotrifluoride (stabilized with Copper chip)
Purity: >97.0%(GC)
Packaging: 25g
Price: $180
Updated: 2024/03/01

Alfa Aesar

Product number: A12189
Product name: 4-Iodobenzotrifluoride, 98%
Packaging: 1g
Price: $24.65
Updated: 2024/03/01

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4-Iodobenzotrifluoride Chemical Properties,Usage,Production

Chemical Properties

4-Iodobenzotrifluoride is a clear red to pink liquid with has the odor of halogenated benzene, is insoluble in water, and is miscible with benzene, toluene, ethanol, ether, halogenated hydrocarbons, etc.

Uses

4-Iodobenzotrifluoride may be employed as substrate with electron-deficient aromatic ring, during Mizoroki-Heck reaction with acrylic acid, to afford 4-trifluoromethylcinnnamic acid. It undergoes aminocarbonylation in DMF using phosphoryl chloride to give N,N-dimethyl-(4-trifluoromethyl)benzamide.

Preparation

Synthesis of 4-Iodotrifluorotoluene: Prepared by diazotization and iodination of 4-aminobenzotrifluoride or 4-Iodobenzotrifluoride is prepared by direct iodination with trifluorotoluene as raw material.

Application

The fluorine atom in the molecular structure of 4-iodotrifluorotoluene makes it have special activity. It is an important pesticide and pharmaceutical intermediate. It can be used as the intermediate of the insecticide fipronil and used for the synthesis of diphenyl ethers containing fluorine herbicide.

General Description

4-Iodobenzotrifluoride undergoes aminocarbonylation in DMF using phosphoryl chloride to give N,N-dimethyl-(4-trifluoromethyl)benzamide. Mechanism of the copper-free Sonogashira cross-coupling reaction of 4-iodobenzotrifluoride with differently para-substituted phenylacetylenes has been investigated.

4-Iodobenzotrifluoride Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-Iodobenzotrifluoride manufacturers

Hebei Mujin Biotechnology Co.,Ltd

Product: 4-Iodobenzotrifluoride 455-13-0
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-08-18

Hebei Mojin Biotechnology Co.,Ltd

Product: 4-Iodobenzotrifluoride 455-13-0
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2024-08-29

Hebei Weibang Biotechnology Co., Ltd

Product: 4-Iodobenzotrifluoride 455-13-0
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-12-11

455-13-0, 4-IodobenzotrifluorideRelated Search:

Tosufloxacin tosylate Trifluoromethyl iodide Xylene 2-Iodo-1,1,1-trifluoroethane 3-Fluorobenzotrifluoride Benzene Benzotrifluoride 4-Fluorobenzotrifluoride 1,4-Bis(trifluoromethyl)-benzene 3,4-Dichlorobenzotrifluoride Diethylstilbestrol 2-Methylbenzotrifluoride 2-Iodobenzotrifluoride,99%,O-IODOBENZOTRIFLUORIDE,2-IODOBENZOTRIFLUORIDE 99%,2-IODOBENZOTRIFLUORIDE 3-IODOBENZOTRIFLUORIDE,3-Iodobenzotrifluoride 99%,3-Iodobenzotrifluoride, 98+%,M-IODOBENZOTRIFLUORIDE Iodobenzene 4-(TRIFLUOROMETHYL)PHENYL ISOCYANATE 3-(Trifluoromethyl)benzoyl chloride 4-NITRO-3-(TRIFLUOROMETHYL)PHENOL

P-IODO TRIFLUORO TOLUENE

P-IODOBENZOTRIFLUORIDE

4-Iodobenzotrifluoride,4-Iodo-α,α,α-trifluorotoluene

4-Iodobenzotrifluoride, 97% 1GR

4-Iodobenzotrifluoride, 97% 5GR

1-Iodo-4-(trifluoromethyl)benzene 4-Iodo-alpha,alpha,alpha-trifluorotoluene

4-Iodo-alpha,alpha,alpha-trifluorotoluene, 1-Iodo-4-(trifluoromethyl)benzene

Iodine benzotrifluoride

1-iodo-4-(trifluoromethyl)-benzen

BUTTPARK 45\01-80

4-(TRIFLUOROMETHYL)IODOBENZENE

1-IODO-4-(TRIFLUOROMETHYL)BENZENE

4-IODO-1-TRIFLUOROMETHYLBENZENE

4-IODO-ALPHA,ALPHA,ALPHA-TRIFLUOROTOLUENE

4-IODOBENZOTRIFLUORIDE

alpha,alpha,alpha-trifluoro-4-iodotoluene

p-Iodine Trifluoro Toluene

4-iodo-à,à,à-trifluorotoluene

4-iodo-α,α,α-trifluorotoluene

4-Iodobenzotrifluoride 98%

4-Iodobenztrifluoride

4-Iodobenzotrifluoride,98%

4-Iodobenzotrifluoride (stabilized with Copper chip)

1-Trifluoromethyl-4-iodobenzene

a,a,a-Trifluoro-p-iodotoluene

4-(Trifluoromethyl)-1-iodobenzene

4-Iodobenzotrifluoride,97%

4-Iodo(trifluoromethyl)benzene

α,α,α-trifluoro-4-iodotoluene

4-Iodobenzotrifluoride(stabilizedwithCopperchip)&gt

4-IodobenzotrifL

Benzene, 1-iodo-4-(trifluoromethyl)-

455-13-0 C7H4F3I 4-Iodobenzotrifluoride

455-13-0

445-13-0

Halogenated Hydrocarbons

Organic Building Blocks

HALOGEN

Aryl

Building Blocks

Fluorine Compounds

Iodine Compounds

Fluoro-contained Iodo series