Trifluoromethyl iodide
Uses Reactions- Product Name
- Trifluoromethyl iodide
- CAS No.
- 2314-97-8
- Chemical Name
- Trifluoromethyl iodide
- Synonyms
- CF3I;Trifluoroiodomethane;CIF3;IODOTRIFLUOROMETHANE;R13I1;FIC-1311;FIC-13I1;freon13t1;Freon13I1;uoroiodomethane
- CBNumber
- CB7356124
- Molecular Formula
- CF3I
- Formula Weight
- 195.91
- MOL File
- 2314-97-8.mol
Trifluoromethyl iodide Property
- Melting point:
- <−78 °C(lit.)
- Boiling point:
- −22.5 °C(lit.)
- Density
- 2.361
- vapor pressure
- 540.5kPa at 25℃
- refractive index
- 1.379
- Flash point:
- -22.5°C
- form
- Gas
- Water Solubility
- Slightly soluble in water.
- Sensitive
- Light Sensitive
- BRN
- 1732740
- Stability:
- Stable. Substances to be avoided include strong oxidizing agents. Avoid direct sunlight. Risk of explosion if heated under confinement. Flammable.
- LogP
- 2.41 at 22.85℃
- CAS DataBase Reference
- 2314-97-8(CAS DataBase Reference)
- NIST Chemistry Reference
- Methane, trifluoroiodo-(2314-97-8)
- EPA Substance Registry System
- Trifluoroiodomethane (2314-97-8)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H280Contains gas under pressure; may explode if heated
H341Suspected of causing genetic defects
H420Harms public health and the environment by destroying ozone in the upper atmosphere
- Precautionary statements
-
P201Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313IF exposed or concerned: Get medical advice/attention.
P410+P403Protect from sunlight. Store in a well-ventilated place.
P502Refer to manufacturer/supplier for information on recovery/recycling
N-Bromosuccinimide Price
- Product number
- 171441
- Product name
- Trifluoroiodomethane
- Purity
- 99%
- Packaging
- 25g
- Price
- $264
- Updated
- 2024/03/01
- Product number
- 171441
- Product name
- Trifluoroiodomethane
- Purity
- 99%
- Packaging
- 100g
- Price
- $455
- Updated
- 2024/03/01
- Product number
- 041479
- Product name
- Trifluoroiodomethane
- Purity
- 97+%
- Packaging
- 25g
- Price
- $369
- Updated
- 2023/06/20
- Product number
- 041479
- Product name
- Trifluoroiodomethane
- Purity
- 97+%
- Packaging
- 100g
- Price
- $651
- Updated
- 2023/06/20
- Product number
- 09-7680
- Product name
- Trifluoromethyliodide, min. 97%
- Packaging
- 100g
- Price
- $654
- Updated
- 2024/03/01
Trifluoromethyl iodide Chemical Properties,Usage,Production
Uses
Trifluoroiodomethane is used as a gaseous fire suppression flooding agent for in-flight aircraft and electronic equipment fires. It is also an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals. It is involved in the rhodium-catalyzed alfa-trifluoromethylation of alfa,beta-unsaturatedketones. It plays an important role as catalyst in the enantioselective alfa -trifluoromethylation of aldehydes through photoredox organocatalysis using a readily available iridium photocatalyst.
Reactions
Trifluoromethyl iodide reacts with [AuMeL] to give [AuMe2(CF3)L] and [AuIL](L = PMe3 or PMe2Ph), or [Au(CF3)L] and Mel (L = PPh3), or a mixture of these products (L = PMePh2). In some cases reaction of [AuMe(PMe3)] with CF3I gives [AuMe(CF3)I(PMe3)]. Evidence is presented that the reactions proceed, at least in part, by a free-radical chain mechanism.
Chemical Properties
colourless gas
Uses
Trifluoroiodomethane is used as a gaseous fire suppression flooding agent for in-flight aircraft and electronic equipment fires. It is also an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals. It is involved in the rhodium-catalyzed alfa-trifluoromethylation of alfa,beta-unsaturatedketones. It plays an important role as catalyst in the enantioselective alfa -trifluoromethylation of aldehydes through photoredox organocatalysis using a readily available iridium photocatalyst.
Uses
Reagent used in the rhodium-catalyzed α-trifluoromethylation of α,?-unsaturated ketones.
Preparation
A glass flask provided with a gas outlet is filled with 80 g. (0.153 mole) of CI4 and 30 g. (0.135 mole) of IF5. The gas outlet is connected via short rubber tubes to several gas traps cooled with liquid nitrogen. Agitation of the vessel produces vigorous evolution of gas. When the reaction subsides, the system is heated for 30 min at 90-100°C. The condensate in the gas traps is then washed with 5% NaOH and fractionated. The yield is 90%.
Synthesis Reference(s)
Journal of the American Chemical Society, 107, p. 5014, 1985 DOI: 10.1021/ja00303a042
Flammability and Explosibility
Not classified
Trifluoromethyl iodide Preparation Products And Raw materials
Raw materials
Preparation Products
Trifluoromethyl iodide Suppliers
- Tel
- 0514-82098883; 13761402923
- market@modeltemol.com
- Country
- China
- ProdList
- 901
- Advantage
- 58
- Tel
- +86-21-62456266 18191363752
- Fax
- 021-62456266
- chem@yujigroup.com
- Country
- China
- ProdList
- 66
- Advantage
- 58
- Tel
- 010-82848833 400-666-7788
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30123
- Advantage
- 84
- Tel
- 400-021-7337 2355568890
- Fax
- 0086-21-50182339
- sales@demochem.com
- Country
- China
- ProdList
- 2572
- Advantage
- 57
- Tel
- 010-89508211 18501085097
- Fax
- 010-89508210
- sales.bj@hwrkchemical.com
- Country
- China
- ProdList
- 8415
- Advantage
- 55
- Tel
- 86-027-67849912
- Fax
- 86-027-87531808
- sales@chemwish.com
- Country
- China
- ProdList
- 35896
- Advantage
- 56
- Tel
- 010-82967028 13552068683
- Fax
- +86-10-82967029
- 2355560935@qq.com
- Country
- China
- ProdList
- 12438
- Advantage
- 60
- Tel
- +86-21-54098501
- Fax
- +86-21-54096319
- sales@sinch.com.cn
- Country
- China
- ProdList
- 11598
- Advantage
- 64
- Tel
- 0573-85285100 18627885956
- Fax
- 0573-85285100
- isenchem@163.com
- Country
- China
- ProdList
- 9414
- Advantage
- 66
View Lastest Price from Trifluoromethyl iodide manufacturers
- Product
- Trifluoromethyl iodide 2314-97-8
- Price
- US $1310.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1-10mt
- Release date
- 2021-06-22
- Product
- Trifluoromethyl iodide 2314-97-8
- Price
- US $8.00-1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-03
- Product
- Trifluoromethyl iodide 2314-97-8
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99.99%
- Supply Ability
- 50000kg
- Release date
- 2023-04-06