Trifluoromethyl iodide
Uses Reactions- Product Name
- Trifluoromethyl iodide
- CAS No.
- 2314-97-8
- Chemical Name
- Trifluoromethyl iodide
- Synonyms
- CF3I;Trifluoroiodomethane;CIF3;IODOTRIFLUOROMETHANE;R13I1;FIC-1311;FIC-13I1;freon13t1;Freon13I1;uoroiodomethane
- CBNumber
- CB7356124
- Molecular Formula
- CF3I
- Formula Weight
- 195.91
- MOL File
- 2314-97-8.mol
Trifluoromethyl iodide Property
- Melting point:
- <−78 °C(lit.)
- Boiling point:
- −22.5 °C(lit.)
- Density
- 2.361
- vapor pressure
- 540.5kPa at 25℃
- refractive index
- 1.379
- Flash point:
- -22.5°C
- form
- Gas
- Water Solubility
- Slightly soluble in water.
- Sensitive
- Light Sensitive
- BRN
- 1732740
- Stability:
- Stable. Substances to be avoided include strong oxidizing agents. Avoid direct sunlight. Risk of explosion if heated under confinement. Flammable.
- LogP
- 2.41 at 22.85℃
- CAS DataBase Reference
- 2314-97-8(CAS DataBase Reference)
- NIST Chemistry Reference
- Methane, trifluoroiodo-(2314-97-8)
- EPA Substance Registry System
- Trifluoroiodomethane (2314-97-8)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H280Contains gas under pressure; may explode if heated
H341Suspected of causing genetic defects
H420Harms public health and the environment by destroying ozone in the upper atmosphere
- Precautionary statements
-
P201Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313IF exposed or concerned: Get medical advice/attention.
P410+P403Protect from sunlight. Store in a well-ventilated place.
P502Refer to manufacturer/supplier for information on recovery/recycling
N-Bromosuccinimide Price
- Product number
- 171441
- Product name
- Trifluoroiodomethane
- Purity
- 99%
- Packaging
- 25g
- Price
- $264
- Updated
- 2024/03/01
- Product number
- 171441
- Product name
- Trifluoroiodomethane
- Purity
- 99%
- Packaging
- 100g
- Price
- $455
- Updated
- 2024/03/01
- Product number
- 041479
- Product name
- Trifluoroiodomethane
- Purity
- 97+%
- Packaging
- 25g
- Price
- $369
- Updated
- 2023/06/20
- Product number
- 041479
- Product name
- Trifluoroiodomethane
- Purity
- 97+%
- Packaging
- 100g
- Price
- $651
- Updated
- 2023/06/20
- Product number
- 09-7680
- Product name
- Trifluoromethyliodide, min. 97%
- Packaging
- 100g
- Price
- $654
- Updated
- 2024/03/01
Trifluoromethyl iodide Chemical Properties,Usage,Production
Uses
Trifluoroiodomethane is used as a gaseous fire suppression flooding agent for in-flight aircraft and electronic equipment fires. It is also an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals. It is involved in the rhodium-catalyzed alfa-trifluoromethylation of alfa,beta-unsaturatedketones. It plays an important role as catalyst in the enantioselective alfa -trifluoromethylation of aldehydes through photoredox organocatalysis using a readily available iridium photocatalyst.
Reactions
Trifluoromethyl iodide reacts with [AuMeL] to give [AuMe2(CF3)L] and [AuIL](L = PMe3 or PMe2Ph), or [Au(CF3)L] and Mel (L = PPh3), or a mixture of these products (L = PMePh2). In some cases reaction of [AuMe(PMe3)] with CF3I gives [AuMe(CF3)I(PMe3)]. Evidence is presented that the reactions proceed, at least in part, by a free-radical chain mechanism.
Chemical Properties
colourless gas
Uses
Trifluoroiodomethane is used as a gaseous fire suppression flooding agent for in-flight aircraft and electronic equipment fires. It is also an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals. It is involved in the rhodium-catalyzed alfa-trifluoromethylation of alfa,beta-unsaturatedketones. It plays an important role as catalyst in the enantioselective alfa -trifluoromethylation of aldehydes through photoredox organocatalysis using a readily available iridium photocatalyst.
Uses
Reagent used in the rhodium-catalyzed α-trifluoromethylation of α,?-unsaturated ketones.
Synthesis Reference(s)
Journal of the American Chemical Society, 107, p. 5014, 1985 DOI: 10.1021/ja00303a042
Flammability and Explosibility
Not classified
Trifluoromethyl iodide Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Trifluoromethyl iodide manufacturers
- Product
- Trifluoromethyl iodide 2314-97-8
- Price
- US $8.00-1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-03
- Product
- Trifluoromethyl iodide 2314-97-8
- Price
- US $1310.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1-10mt
- Release date
- 2021-06-22
- Product
- Trifluoromethyl iodide 2314-97-8
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99.99%
- Supply Ability
- 50000kg
- Release date
- 2023-04-06