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Beryllium nitrate

Product Name
Beryllium nitrate
CAS No.
13597-99-4
Chemical Name
Beryllium nitrate
Synonyms
Nsc84265;solution35%;Berylliumnitrat;BERYLLIUM NITRATE;Beryllium dinitrate;Nitricacid,berylliumsalt;Beryllium nitrate solution;beryllium standard for icp;beryllium standard for aas;BERYLLIUM STANDARD SOLUTION
CBNumber
CB0287162
Molecular Formula
BeN2O6
Formula Weight
133.02
MOL File
13597-99-4.mol
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Beryllium nitrate Property

Melting point:
~60℃ [MER06]
Boiling point:
decomposes at 100–200℃ [HAW93]
Density 
1.02 g/mL at 20 °C
storage temp. 
Store at +15°C to +25°C.
solubility 
soluble in ethanol
form 
Liquid
color 
Clear colorless
PH
0.5 (H2O, 20°C)
Water Solubility 
g Ba(NO3)2/100g H2O: 97 (0°C), 108 (20°C), 178 (60°C); soluble alcohol [LAN05] [HAW93]
Merck 
13,1174
CAS DataBase Reference
13597-99-4
EPA Substance Registry System
Beryllium nitrate (Be(NO3)2) (13597-99-4)
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Safety

Hazard Codes 
T,T+,O,N
Risk Statements 
49-23-36/38-43-48/23-36/37/38-20-34-26-21/22-8-61-45-51/53-25-48/20
Safety Statements 
53-26-36/37-45-23-36/37/39-17-61-28
RIDADR 
UN 3264 8/PG 3
WGK Germany 
1
RTECS 
DS3675000
HS Code 
3822 00 00
HazardClass 
5.1
PackingGroup 
II
Hazardous Substances Data
13597-99-4(Hazardous Substances Data)
Toxicity
LD50 ivn-mus: 3160 mg/kg CUSCAM 55,899,86
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H272May intensify fire; oxidizer

H301Toxic if swalloed

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H331Toxic if inhaled

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H335May cause respiratory irritation

H372Causes damage to organs through prolonged or repeated exposure

H373May cause damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P220Keep/Store away from clothing/…/combustible materials.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P311Call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
1.70207
Product name
Beryllium standard solution
Purity
Be?O(C?H?O?)? in HNO? 0.5 mol/l 1000 mg/l Be Certipur?
Packaging
100mL
Price
$69.9
Updated
2024/03/01
Sigma-Aldrich
Product number
1.70207
Product name
Beryllium standard solution
Purity
Be?O(C?H?O?)? in HNO? 0.5 mol/l 1000 mg/l Be Certipur?
Packaging
500mL
Price
$169
Updated
2024/03/01
Usbiological
Product number
263674
Product name
Beryllium Nitrate
Packaging
25mg
Price
$512
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB30613
Product name
Beryllium Nitrate
Packaging
250mg
Price
$892.5
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0008930
Product name
BERYLLIUM NITRATE (1G/L IN NITRIC ACID)
Purity
95.00%
Packaging
100ML
Price
$1296.55
Updated
2021/12/16
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Beryllium nitrate Chemical Properties,Usage,Production

Description

Beryllium nitrate is said to have the molecular formula of Be(NO3)2 and the molecular weight of grams per mole. It is very soluble in water.
It could be prepared by the action of nitric acid on beryllium carbonate, oxide or hydroxide:
BeCO3 + 2HNO3 ? Be(NO3)2 + CO2 +H2O
Be(OH)2 + 2HNO3 ? Be(NO3)2 + 2H2O
It is described as Be(NO3)2·4H2O, a compound that forms colorless, deliquescent crystals that are soluble in water, and used to introduce beryllium oxide into materials used in incandescent mantles. However, in view of recent developments concerning the behavior of the Be3+ cation in solution, the more likely reactions are:
BeCO3 + 2HNO3 ? Be(OH)NO3 + CO2 + 1/2H2O
Be(OH)2 + 2HNO3 ? Be(OH)NO3 + 3/2H2O

Chemical Properties

White to faintly yellowish, deliquescent mass. Soluble in water, alcohol.

Physical properties

DTA analysis of the tetrahydrate showed that it dissolves in its own waters of hydration at about 60.4°C. Heating above 101°C causes decomposition with loss of water and oxides of nitrogen plus formation of the oxide. The decomposition is complete at 250°C. Thermal decomposition of these salt hydrates occurs by release of nitric acid which then breaks down to form the nitrogen oxides, rather than break down of the nitrate anion itself. The anhydrate has been prepared by the reaction of beryllium chloride with N2O4 dissolved in ethylacetate. If heated in a vacuum above 50°C, the product, Be(NO3)2·2N2O4, evolves oxides of nitrogen to produce the anhydrate.
The tetrahydrate has a CAS number of 13597-99-4 and molecular weight is grams per mole. Anhydrous beryllium nitrate is a white to pale yellow crystalline solid. Beryllium nitrate trihydrate (CAS number = 7787-55-5) forms slightly yellow crystals with a vapor pressure 49.8 mm Hg at 25°C. Its melting point is 60.5°C and it decomposes completely at 102.3°C. Its Enthalpy of vaporization = 37.72 kJ/mol and its boiling point is 83°C at 760 mm Hg where it becomes anhydrous. Beryllium nitrate is a tumorigen, mutagen and reproductive effector in rats and, presumably in humans.
Beryllium metal dissolves readily in nonoxidizing acids such as HCl and H2SO4, but not in nitric acid as this forms the oxide (this behavior is similar to that of aluminum metal). Beryllium, again similarly to aluminum, dissolves in warm alkali to form the beryllate anion, Be(OH)42-, and hydrogen gas.

Physical properties

Beryllium nitrate, also known as beryllium dinitrate, is an ionic beryllium salt of nitric acid with the chemical formula Be(NO).Each formula unit is composed of one Be2+ cation and two NO-anions.

Uses

Beryllium nitrate is used as a hardening agent for mantles on gas lanterns.

Uses

Chemical reagent, gas-mantle hardener.

Preparation

Anhydrous beryllium nitrate has been prepared by the reaction of anhydrous beryllium chloride with an ethylacetate-dinitrogen tetroxide mixture to give Be(NO3)2 · 2N2O4 [Addison and Walker 1963]. When heated above 50 °C (120 °F) in a vacuum, oxides of nitrogen are evolved, leaving anhydrous beryllium nitrate. The anhydrous salt is stable to approximately 125 °C (255 °F), when a sudden decomposition occurs to give nitrogen tetroxide and a volatile compound that separates from the gas phase as colorless Be4O(NO3)6 crystals. These crystals are slowly hydrolyzed when added to water.

Hazard

Beryllium nitrate is a toxic chemical,like all other beryllium compounds. It is also an irritant in small doses. When burned, it gives off irritating or toxic fumes. However, when massive short-term exposure occurs, acute pneumonitis can set in, but symptoms do not manifest themselves for 3 days.

Hazard

Very toxic. Oxidizing material, dangerous fire risk.

Safety Profile

Confirmed carcinogen. Poison byintraperitoneal, intravenous, and subcutaneous routes.Experimental reproductive effects. When heated todecomposition it emits very toxic fumes of BeO and NOx.

Synthesis

Beryllium nitrate can be prepared by reacting beryllium hydroxide in nitric acid.
Be(OH) + 2 HNO → Be(NO) + 2 HO

Beryllium nitrate Preparation Products And Raw materials

Raw materials

Preparation Products

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Beryllium nitrate Suppliers

3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
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Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
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Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Beijing HuaMeiHuLiBiological Chemical
Tel
010-56205725
Fax
010-65763397
Email
waley188@sohu.com
Country
China
ProdList
12335
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58
Shanghai Meishui Chemical Technology Co., Ltd
Tel
021-60549325 18616193163
Fax
021-33250306
Country
China
ProdList
4526
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Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
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VWR(Shanghai) Co., Ltd
Tel
400-821-8006
Fax
+86-21-58558801
Email
info_china@vwr.com
Country
China
ProdList
3040
Advantage
75
Shandong Xiya Chemical Co., Ltd.
Tel
4009903999 13395398332
Fax
0539-6365991
Email
sales@xiyashiji.com
Country
China
ProdList
20806
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Shandong Ono Chemical Co., Ltd.
Tel
0539-6362799 20)
Fax
0539-6362799(To 20)
Country
China
ProdList
9998
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58
Shaanxi Dideu Medichem Co. Ltd
Tel
+86-029-89586680 +86-18192503167
Fax
+86-29-88380327
Email
1026@dideu.com
Country
China
ProdList
7724
Advantage
58
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View Lastest Price from Beryllium nitrate manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
BERYLLIUM NITRATE 13597-99-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

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