ChemicalBook > CAS DataBase List > Methyl 4-formylbenzoate

Methyl 4-formylbenzoate

Product Name
Methyl 4-formylbenzoate
CAS No.
1571-08-0
Chemical Name
Methyl 4-formylbenzoate
Synonyms
METHYL P-FORMYLBENZOATE;METHYL TEREPHTHALALDEHYDATE;METHYL BENZALDEHYDE-4-CARBOXYLATE;NSC 28459;AKOS BBS-00003165;TIMTEC-BB SBB008362;Methyl 4-formylbenzo;OTAVA-BB BB7018801965;Mehyl4-Formylbenzoate;Methyl-4-formylbenzoat
CBNumber
CB0333234
Molecular Formula
C9H8O3
Formula Weight
164.16
MOL File
1571-08-0.mol
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Methyl 4-formylbenzoate Property

Melting point:
59-63 °C (lit.)
Boiling point:
265 °C (lit.)
Density 
1,2 g/cm3
refractive index 
1.5260 (estimate)
Flash point:
144 °C
storage temp. 
Store below +30°C.
solubility 
methanol: 0.1 g/mL, clear
form 
Crystalline Powder or Chunks
color 
White to cream or slightly green
Water Solubility 
insoluble
Sensitive 
Air Sensitive
BRN 
775895
Stability:
Stable, though possibly air-sensitive. Combustible. Incompatible with strong oxidizing agents.
InChIKey
FEIOASZZURHTHB-UHFFFAOYSA-N
LogP
2.050 (est)
CAS DataBase Reference
1571-08-0(CAS DataBase Reference)
NIST Chemistry Reference
4-HC(O)-C6H4-COOCH3(1571-08-0)
EPA Substance Registry System
Benzoic acid, 4-formyl-, methyl ester (1571-08-0)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
36/37/38-20/21/22
Safety Statements 
22-24/25
WGK Germany 
2
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29183000
Hazardous Substances Data
1571-08-0(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
244740
Product name
Methyl 4-formylbenzoate
Purity
99%
Packaging
5g
Price
$131
Updated
2024/03/01
Sigma-Aldrich
Product number
244740
Product name
Methyl 4-formylbenzoate
Purity
99%
Packaging
25g
Price
$182
Updated
2024/03/01
TCI Chemical
Product number
T0012
Product name
Methyl Terephthalaldehydate
Purity
>98.0%(GC)
Packaging
25g
Price
$44
Updated
2024/03/01
TCI Chemical
Product number
T0012
Product name
Methyl Terephthalaldehydate
Purity
>98.0%(GC)
Packaging
100g
Price
$132
Updated
2024/03/01
Alfa Aesar
Product number
B24091
Product name
Methyl 4-formylbenzoate, 98+%
Packaging
5g
Price
$40.65
Updated
2024/03/01
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Methyl 4-formylbenzoate Chemical Properties,Usage,Production

Chemical Properties

white crystalline powder

Uses

4-Formylbenzoic Acid Methyl Ester is a benzoic acid derivative with antioxidant activity.

Uses

Methyl 4-formylbenzoate is used in the preparation of dimethyl terephthalate. It is also used as an active pharmaceutical ingredient intermediate and fluorescent brightener intermediate.

Synthesis Reference(s)

Tetrahedron, 64, p. 688, 2008 DOI: 10.1016/j.tet.2007.11.030

General Description

Needles (in water) or white powder.

Air & Water Reactions

Methyl 4-formylbenzoate may be sensitive to prolonged exposure to air. . Insoluble in water.

Reactivity Profile

Methyl 4-formylbenzoate is an aldehyde/ester. Aldehydes are frequently involved in self-condensation or polymerization reactions. These reactions are exothermic; they are often catalyzed by acid. Aldehydes are readily oxidized to give carboxylic acids. Flammable and/or toxic gases are generated by the combination of aldehydes with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. Aldehydes can react with air to give first peroxo acids, and ultimately carboxylic acids. These autoxidation reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). The addition of stabilizers (antioxidants) to shipments of aldehydes retards autoxidation. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Fire Hazard

Flash point data for Methyl 4-formylbenzoate are not available. Methyl 4-formylbenzoate is probably combustible.

Methyl 4-formylbenzoate Preparation Products And Raw materials

Raw materials

Sodium 2-Nitropropane Methyl 4-methylbenzoate Government regulation Sodium carbonate

Preparation Products

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Methyl 4-formylbenzoate Suppliers

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View Lastest Price from Methyl 4-formylbenzoate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Methyl 4-Formylbenzoate 1571-08-0
Price
US $65.00-20.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-31
Hebei Weibang Biotechnology Co., Ltd
Product
Methyl 4-formylbenzoate 1571-08-0
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-21
Hebei Chuanghai Biotechnology Co,.LTD
Product
Methyl 4-formylbenzoate 1571-08-0
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-23

1571-08-0, Methyl 4-formylbenzoateRelated Search:

METSULFURON METHYL Methyl 4-cyanobenzoate Methyl acetate 4-Methylsulphonylbenzoic acid Benzaldehyde Thiophanate-methyl Methyl benzoate Methyl acrylate Methyl salicylate Kresoxim-methyl Methyl 2-iodobenzoate RESMETHRIN 4-Formylcinnamic acid 4-Formylbenzoic acid Bensulfuron methyl 4-(4-Fluorobenzoyl)butyric acid 2-Iodoxybenzoic acid Dibenzoylmethane

  • Methyl 4-formylbenzoate,99%
  • Methyl 4-formylbenzoate,95%
  • Methyl 4-formylbenzoate,Methyl benzaldehyde-4-carboxylate, Methyl terephthalaldehydate
  • Methyl 4-formylbenzo
  • Methyl 4-forMylbenzoate, 99% 10GR
  • NSC 28459
  • Para(Methoxycarbonyl)benzaldehyde
  • 4-Formylbenzoic Acid Methyl Ester Methyl 4-Formylbenzoate Terephthalaldehydic Acid Methyl Ester
  • METHYL 4-FORMYLBENZOATE FOR SYNTHESIS
  • Methyl 4-forMylbenzoate, 98+%
  • 4-forMylbenzoate Methyl
  • P-CarbonMethoxybenzaldehyde
  • The acyl Methyl benzoic acid
  • methyl 4-methanoylbenzoate
  • 2-Methoxycarbonylbenzaldehyde
  • 4-formyl-benzoicacimethylester
  • Terephthalaldehydic acid methyl
  • TIMTEC-BB SBB008362
  • TEREPHTHALALDEHYDIC ACID METHYL ESTER
  • TEREPHTHALALDEHYDIO ACID METHYL ESTER
  • OTAVA-BB BB7018801965
  • P-CARBOMETHOXYBENZALDEHYDE
  • P-METHOXYCARBONYLBENZALDEHYDE
  • Terephthalaldehyde acid methylester
  • Mehyl4-Formylbenzoate
  • METHYL-PARA-FORMYLBENZOATE
  • Methyl-4-formylbenzoat
  • 4-Formylbenzoic acid methyl
  • Benzoic acid, 4-formyl-, methyl ester
  • Methyl terephthaldehydate
  • methylterephthaldehydate
  • p-Formylbenzoic acid methyl ester
  • p-formylbenzoicacidmethylester
  • METHYL TEREPHTHALADEHYDATE
  • METHYL TEREPHTHALALDEHYDATE
  • METHYL P-FORMYLBENZOATE
  • METHYL BENZALDEHYDE-4-CARBOXYLATE
  • METHYL 4-FORMYLBENZOATE
  • LABOTEST-BB LT00941130
  • 4-(methoxycarbonyl)benzaldehyde
  • 4-FORMYLBENZOIC ACID METHYL ESTER
  • 4-CARBOMETHOXYBENZALDEHYDE
  • 4-carboxybenzaldehyde methyl ester
  • AKOS BBS-00003165
  • Methyl benzaldehyde-4-carboxylate, Methyl terephthalaldehydate
  • Methyl Terephthalaldehydate &gt
  • 2H4]-Methyl Terephthalaldehydate
  • Bifeprunox Impurity 29
  • 1571-08-0
  • HCOC6H4CO2CH3
  • ALDEHYDE
  • Building Blocks
  • Aldehydes
  • Carbonyl Compounds
  • C9
  • Organic Building Blocks
  • Aromatic Aldehydes & Derivatives (substituted)
  • Intermediates of Dyes and Pigments