(-)-Camphanic acid chloride

Product Name: (-)-Camphanic acid chloride
CAS No.: 39637-74-6
Chemical Name: (-)-Camphanic acid chloride
Synonyms: (+)-(1R,4S)-camphani;(-)-CAMPHANIC CHLORIDE;(-)-Camphanic Chloride;(-)-Camphanoyl chloride;(1S)-(-)CAMPHANYL CHLORIDE;(-)-Camphanic Chloride >(-)-CAMPHANIC ACID CHLORIDE;(1S)-(-)-CAMPHANIC CHLORIDE;(1S)-(-)-CAMPHANOYL CHLORIDE;(S)-(-)-1-CAMPHANYL CHLORIDE
CBNumber: CB0352910
Molecular Formula: C10H13ClO3
Formula Weight: 216.66
MOL File: 39637-74-6.mol

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(-)-Camphanic acid chloride Property

Melting point:: 71-73 °C(lit.)
alpha: -18 º (c=2, CCl4)
Boiling point:: 310.92°C (rough estimate)
Density: 1.2072 (rough estimate)
refractive index: 1.5390 (estimate)
storage temp.: 2-8°C
solubility: soluble in Dichloromethane, Ether, Ethyl Acetate, Methanol
form: Powder
color: Yellow to orange-brown
optical activity: [α]23/D 18°, c = 2 in carbon tetrachloride
Water Solubility: decomposes
Sensitive: Moisture Sensitive
BRN: 3590860
InChIKey: PAXWODJTHKJQDZ-RGURZIINSA-N
CAS DataBase Reference: 39637-74-6(CAS DataBase Reference)

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Safety

Hazard Codes: C,Xi
Risk Statements: 34-29
Safety Statements: 26-36/37/39-45-8-27
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
F: 10-21
HazardClass: 8
PackingGroup: II
HS Code: 29322090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 21287
Product name: (1S)-(−)-Camphanic chloride
Purity: for chiral derivatization, LiChropur?, ≥98.0%
Packaging: 5G
Price: $274
Updated: 2022/05/15

Sigma-Aldrich

Product number: 21287
Product name: (1S)-(−)-Camphanic chloride
Purity: for chiral derivatization, LiChropur?, ≥98.0%
Packaging: 25g
Price: $1080
Updated: 2022/05/15

TCI Chemical

Product number: C1022
Product name: (-)-Camphanic Chloride
Purity: >97.0%(T)
Packaging: 1g
Price: $86
Updated: 2024/03/01

TCI Chemical

Product number: C1022
Product name: (-)-Camphanic Chloride
Purity: >97.0%(T)
Packaging: 5g
Price: $251
Updated: 2024/03/01

Alfa Aesar

Product number: L14148
Product name: (1S)-(-)-Camphanic chloride, 95%
Packaging: 1g
Price: $41.65
Updated: 2024/03/01

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(-)-Camphanic acid chloride Chemical Properties,Usage,Production

Chemical Properties

Off-White Powder

Uses

An optically active resolving agent

Uses

(1S)-(-)-Camphanic chloride is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.

Uses

(1S)-(-)-Camphanic chloride may be used in esterification of enantiomers in volatiles releasedf from wheat, in order to determine the proportion of enantiomers and also in quantifying the esters.

General Description

(1S)-(-)-Camphanic chloride is a chiral derivatizing agent. It can be prepared by reacting (-)-(1S,4R)-camphanic acid with thionyl chloride.

Purification Methods

It is soluble in toluene (50g/100mL at 0o) and crystallises from pet ether (b 40-60o). It sublimes at 70o/5mm, Store it dry at 0o, max (CCl4) 1805s and 1780m cm-1. Armarego et al. J Chem Soc, Perkin Trans I 2229 1976, Gerlach Helv Chim Acta 51 1587 1968, Gerlach Helv Chim Acta 68 1815 1985, Beilstein 18/8 V 101.]

(-)-Camphanic acid chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (-)-Camphanic acid chloride manufacturers

Zibo Hangyu Biotechnology Development Co., Ltd

Product: (-)-Camphanic acid chloride 39637-74-6
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 50000kg/month
Release date: 2024-08-28

Hebei Weibang Biotechnology Co., Ltd

Product: (-)-Camphanic acid chloride 39637-74-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2022-11-17

Hebei Mojin Biotechnology Co., Ltd

Product: (-)-Camphanic acid chloride 39637-74-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-08-17

39637-74-6, (-)-Camphanic acid chlorideRelated Search:

Isovaleryl chloride 4-Methylvaleryl chloride (-)-Camphanic acid chloride 1-CHLORO-3,3-DIMETHYLBUTANE 4-Butoxyphenol 3-METHYLPENTANOYL CHLORIDE 6-Chlorohexanol 2-(CHLOROMETHYL)TETRAHYDROPYRAN Cyclopentanecarbonyl chloride ALPHA,ALPHA-DIMETHYL-GAMMA-BUTYROLACTONE 2-METHYLVALERYL CHLORIDE 1-Pentanol Acetoxyacetyl chloride Heptanoyl chloride DIHYDRO-4,4-DIMETHYL-2(3H)-FURANONE Tetrahydrofurfuryl chloride (S)-(-)-2-ACETOXYPROPIONYL CHLORIDE 2-Ethylbutyryl chloride

(-)-CAMPHANIC ACID CHLORIDE

(-)-CAMPHANIC CHLORIDE

(1S)-(-)-Camphanicacidchloride

3-oxa-2-oxobornane-4-carbonyl chloride

(1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chlorid

(1S)-(-)-Camphanicchloride,95%

(1S,4R)-(-)-Camphanic chloride

(1S)-(-)-Camphanic chloride, 98% (99% EE)

(-)-CAMPHANIC ACID CHLORIDE 98%

4,7,7-trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride

(+)-(1R,4S)-Camphanoyl chloride

2-Oxabicyclo2.2.1heptane-1-carbonyl chloride, 4,7,7-trimethyl-3-oxo-, (1S,4R)-

(-)-Camphanoyl chloride

(-)-Camphanoyl chloride, (1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride

2-Oxabicyclo[2.2.1]heptane-1-carbonyl chloride, 4,7,7-trimethyl-3-oxo-, (1S)-

(1S,4R)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid chloride

(1S,4R)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid chloride

[1S,4R,(-)]-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride

[1S,4R,(-)]-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid chloride

(-)-Camphanic acid chloride,98%

(+)-(1R,4S)-camphani

(-)-Camphanoyl chloride (-)-Camphanic acid chloride

(1S)-(-)-Camphanic chloride 98%

(1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride

[1S]-3-OXO-4,7,7-TRIMETHYL-2-OXABICYCLO[2.2.1]HEPTANE-1-CARBONYL CHLORIDE

(1S)-3-OXO-4,7,7-TRIMETHYL-2-OXABICYCLO[2.2.1]HEPTANE-1-CARBOXYL CHLORIDE

(1S)-(-)-CAMPHANIC CHLORIDE

(1S)-(-)-CAMPHANOYL CHLORIDE

(1S)-(-)CAMPHANYL CHLORIDE

(-)-(1S,4R)-CAMPHANOYL CHLORIDE

(IS)-(-)-Camphenic acid chloride

(-)-CaMphanic acid chloride, 98% 1GR

(S)-(-)-1-CAMPHANYL CHLORIDE

(-)-Camphanic Chloride &gt

(-)-Camphanic acid chloride, 98%, reagent grade

(1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride(Chunks or pellets)

TIANFU-CHEM (-)-Camphanic Chloride

(4S)-1,7,7-trimethyl-2-oxo-3-oxabicyclo[2.2.1]heptane-4-carbonyl chloride

(-)-Camphanic Chloride

(-)-(1S,4R)-Camphanoyl Chloride

39637-74-6

C10H13ClO3

C10H13O3Cl

Analytical Chromatography Product Catalog

Asymmetric Synthesis

Organic Building Blocks

Acid Halides

Derivatization Reagents

Bicyclic Monoterpenes

Terpenes

for Resolution of Alcohols & Thiols

Optical Resolution

ACID CHLORIDE

Chiral Building Blocks

Chiral Derivatization

Chiral Reagents

Chiral Compound

FINE Chemical & INTERMEDIATES