4-Benzyloxyphenylhydrazine

Product Name
4-Benzyloxyphenylhydrazine
CAS No.
51145-58-5
Chemical Name
4-Benzyloxyphenylhydrazine
Synonyms
VITAS-BB TBB000092;4-BENZYLOXYPHENYLHYDRAZINE;(4-Phenylmethoxyphenyl)hydrazine;Hydrazine, [4-(phenylmethoxy)phenyl]-
CBNumber
CB0356721
Molecular Formula
C13H14N2O
Formula Weight
214.26
MOL File
51145-58-5.mol
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
B400213
Product name
(4-Phenylmethoxyphenyl)hydrazine
Packaging
50mg
Price
$45
Updated
2021/12/16
Usbiological
Product number
266424
Product name
4-Benzyloxyphenylhydrazine
Packaging
500mg
Price
$333
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB55433
Product name
4-Benzyloxyphenylhydrazine
Packaging
500mg
Price
$60
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB55433
Product name
4-Benzyloxyphenylhydrazine
Packaging
1g
Price
$107
Updated
2021/12/16
AK Scientific
Product number
5574AH
Product name
4-Benzyloxyphenylhydrazine
Packaging
1g
Price
$171
Updated
2021/12/16
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4-Benzyloxyphenylhydrazine Chemical Properties,Usage,Production

Uses

(4-Phenylmethoxyphenyl)hydrazine is used as a reactant in the preparation of indolyl thiazole derivatives as xanthine oxidase inhibitors and antiinflammatory drugs.

Manufacturing Process

Preparation of 4-benzyloxyphenylhydrazine: 200 grams 4-benzyloxyaniline hydrochloride was suspended in a mixture of 264 ml concentrated hydrochloric acid, 528 ml water and 732 grams crushed ice. A solution of 62.4 grams sodium nitrite in 136 ml water was added below the surface of the stirred suspension at -10-(+/-)2°C during 10 minutes. After stirring for 1 hour at 0°C, the suspension was treated with acid-washed charcoal and filtered.
The filtrate was cooled and maintained at -8°C while a solution of 500 grams of stannous chloride in 760 ml concentrated hydrochloric acid was added with stirring. The mixture was stirred for 2 hours at -8°C and the 4- benzyloxyphenylhydrazine hydrochloride which separated was filtered off and washed with water. The product was crystallized by adding 800 ml hot water to a 3 liter solution in ethanol and had a MP of 185° to 189°C (yield 168.5 grams, 79%).

4-Benzyloxyphenylhydrazine Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Benzyloxyphenylhydrazine Suppliers

VITAS-M LABORATORY, LTD.
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Russia
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