4-Benzyloxyphenylhydrazine hydrochloride

Product Name: 4-Benzyloxyphenylhydrazine hydrochloride
CAS No.: 52068-30-1
Chemical Name: 4-Benzyloxyphenylhydrazine hydrochloride
Synonyms: 52068-30-1;Einecs 257-636-9;1-[4-(BENZYLOXY)PHENYL];Metamizole Impurity 8 HCl;Benzyloxyphenylhydrazine Hcl;4-Benzyloxyphenylhydrazine HCI;4-BENZYLOXYPHENYLHYDRAZINE HYDROCHLORIDE;4-Benzyloxyphenylhydrazine hydrochloride,98%;(4-phenylmethoxyphenyl)hydrazine hydrochloride;1-(Benzyloxy)-4-hydrazinobenzene hydrochloride
CBNumber: CB0255705
Molecular Formula: C13H15ClN2O
Formula Weight: 250.72
MOL File: 52068-30-1.mol

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4-Benzyloxyphenylhydrazine hydrochloride Property

Melting point:: 187-189°C
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
form: Fluffy Powder
color: Cream to brown
InChI: InChI=1S/C13H14N2O.ClH/c14-15-12-6-8-13(9-7-12)16-10-11-4-2-1-3-5-11;/h1-9,15H,10,14H2;1H
InChIKey: OVNUPJXMCMTQCN-UHFFFAOYSA-N
SMILES: C1(=CC=C(NN)C=C1)OCC1=CC=CC=C1.Cl
CAS DataBase Reference: 52068-30-1

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Safety

Risk Statements: 20/21/22-36/37/38
Safety Statements: 26-36/37/39
HS Code: 29280000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B521460
Product name: (4-(Benzyloxy)phenyl)hydrazineHydrochloride
Packaging: 100mg
Price: $75
Updated: 2021/12/16

TRC

Product number: B521460
Product name: (4-(Benzyloxy)phenyl)hydrazineHydrochloride
Packaging: 10mg
Price: $45
Updated: 2021/12/16

Usbiological

Product number: 262073
Product name: 4-Benzyloxyphenylhydrazine HCI
Packaging: 5g
Price: $336
Updated: 2021/12/16

Apolloscientific

Product number: OR6781
Product name: 4-(Benzyloxy)phenylhydrazinehydrochloride
Purity: 97%
Packaging: 100g
Price: $421
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4739-5-X2
Product name: 4-(Benzyloxy)phenylhydrazine hydrochloride
Packaging: 100g
Price: $464
Updated: 2021/12/16

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4-Benzyloxyphenylhydrazine hydrochloride Chemical Properties,Usage,Production

Chemical Properties

Cream to brown fluffy powder

Synthesis

51388-20-6

52068-30-1

General procedure for the synthesis of 4-benzyloxyphenylhydrazine hydrochloride from 4-benzyloxyaniline hydrochloride: (4-(benzyloxy)phenyl)hydrazine hydrochloride (2). Note: Keep the reaction mixture and all added solutions at 0°C during this procedure. Add 4-(benzyloxy)aniline hydrochloride (3.00 g, 12.5 mmol) and water (25 mL) to the reaction flask and stir for 10 minutes at 0°C. Subsequently, a solution of NaNO2 (852 mg, 12.3 mmol) in water (6 mL) was slowly added dropwise over 15 minutes. After the dropwise addition, stirring of the reaction mixture was continued for 15 min. Then, a solution of SnCl2 (6.40 g, 33.1 mmol) in water (7.5 mL) was slowly added. After addition, the reaction mixture was stirred at 0°C for 1 hour. After completion of the reaction, the off-white precipitate was collected by filtration, washed with water and ground with ether (Et2O) to afford the target product 2 (3.01 g, 96% yield). The product characterization data were as follows: IR (ATR, pure) νmax 3232, 2906 (br), 2693, 1568, 1508, 1242, 1177 cm-1; 1H NMR (DMSO-d6, 600 MHz) δ 10.11 (bs, 3H), 7.44-7.40 (m, 2H), 7.40-7.35 (m, 2H ), 7.33-7.29 (m, 1H), 7.01-6.93 (m, 4H), 5.05 (s, 2H); 13C NMR (DMSO-d6, 150MHz) δ 153.7, 139.1, 137.3, 128.5, 128.4, 128.3, 127.9, 127.7, 127.5, 117.1, 116.9, 115.5, 116.9, 115.5, 116.9, 116.9, 115.5, 117.1 116.9, 115.5, 115.3, 69.5; HRMS (EI) m/z calculated value C13H14N2 214.1106, measured value 214.1110.

References

[1] Patent: WO2012/78859, 2012, A2. Location in patent: Page/Page column 47
[2] Bioorganic and Medicinal Chemistry, 2016, vol. 24, # 18, p. 4075 - 4099
[3] Patent: EP427860, 1991, A1
[4] Bioorganic and Medicinal Chemistry, 2010, vol. 18, # 10, p. 3387 - 3402
[5] Patent: US5102891, 1992, A

4-Benzyloxyphenylhydrazine hydrochloride Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Benzyloxyphenylhydrazine hydrochloride Suppliers

Belgium 1 Canada 1 China 164 Europe 1 Germany 3 India 14 Russia 1 Switzerland 1 United Kingdom 11 United States 16 Global 213

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J & K SCIENTIFIC LTD.

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3B Pharmachem (Wuhan) International Co.,Ltd.

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Energy Chemical

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View Lastest Price from 4-Benzyloxyphenylhydrazine hydrochloride manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 4-Benzyloxyphenylhydrazine hydrochloride 52068-30-1
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-02-28

Career Henan Chemical Co

Product: 4-Benzyloxyphenylhydrazine hydrochloride 52068-30-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1kg-1000kg
Release date: 2020-01-02

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Einecs 257-636-9

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52068-30-1

(4-phenylmethoxyphenyl)hydrazine hydrochloride

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52068-30-1

C13H15N2OCl

Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes