ChemicalBook > CAS DataBase List > 4-Benzyloxyphenylhydrazine hydrochloride

4-Benzyloxyphenylhydrazine hydrochloride

Product Name
4-Benzyloxyphenylhydrazine hydrochloride
CAS No.
52068-30-1
Chemical Name
4-Benzyloxyphenylhydrazine hydrochloride
Synonyms
52068-30-1;Einecs 257-636-9;1-[4-(BENZYLOXY)PHENYL];Metamizole Impurity 8 HCl;Benzyloxyphenylhydrazine Hcl;4-Benzyloxyphenylhydrazine HCI;4-BENZYLOXYPHENYLHYDRAZINE HYDROCHLORIDE;4-Benzyloxyphenylhydrazine hydrochloride,98%;(4-phenylmethoxyphenyl)hydrazine hydrochloride;1-(Benzyloxy)-4-hydrazinobenzene hydrochloride
CBNumber
CB0255705
Molecular Formula
C13H15ClN2O
Formula Weight
250.72
MOL File
52068-30-1.mol
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4-Benzyloxyphenylhydrazine hydrochloride Property

Melting point:
187-189°C
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
Fluffy Powder
color 
Cream to brown
InChI
InChI=1S/C13H14N2O.ClH/c14-15-12-6-8-13(9-7-12)16-10-11-4-2-1-3-5-11;/h1-9,15H,10,14H2;1H
InChIKey
OVNUPJXMCMTQCN-UHFFFAOYSA-N
SMILES
C1(=CC=C(NN)C=C1)OCC1=CC=CC=C1.Cl
CAS DataBase Reference
52068-30-1
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Safety

Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36/37/39
HS Code 
29280000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B521460
Product name
(4-(Benzyloxy)phenyl)hydrazineHydrochloride
Packaging
100mg
Price
$75
Updated
2021/12/16
TRC
Product number
B521460
Product name
(4-(Benzyloxy)phenyl)hydrazineHydrochloride
Packaging
10mg
Price
$45
Updated
2021/12/16
Usbiological
Product number
262073
Product name
4-Benzyloxyphenylhydrazine HCI
Packaging
5g
Price
$336
Updated
2021/12/16
Apolloscientific
Product number
OR6781
Product name
4-(Benzyloxy)phenylhydrazinehydrochloride
Purity
97%
Packaging
100g
Price
$421
Updated
2021/12/16
SynQuest Laboratories
Product number
4739-5-X2
Product name
4-(Benzyloxy)phenylhydrazine hydrochloride
Packaging
100g
Price
$464
Updated
2021/12/16
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4-Benzyloxyphenylhydrazine hydrochloride Chemical Properties,Usage,Production

Chemical Properties

Cream to brown fluffy powder

Synthesis

51388-20-6

52068-30-1

General procedure for the synthesis of 4-benzyloxyphenylhydrazine hydrochloride from 4-benzyloxyaniline hydrochloride: (4-(benzyloxy)phenyl)hydrazine hydrochloride (2). Note: Keep the reaction mixture and all added solutions at 0°C during this procedure. Add 4-(benzyloxy)aniline hydrochloride (3.00 g, 12.5 mmol) and water (25 mL) to the reaction flask and stir for 10 minutes at 0°C. Subsequently, a solution of NaNO2 (852 mg, 12.3 mmol) in water (6 mL) was slowly added dropwise over 15 minutes. After the dropwise addition, stirring of the reaction mixture was continued for 15 min. Then, a solution of SnCl2 (6.40 g, 33.1 mmol) in water (7.5 mL) was slowly added. After addition, the reaction mixture was stirred at 0°C for 1 hour. After completion of the reaction, the off-white precipitate was collected by filtration, washed with water and ground with ether (Et2O) to afford the target product 2 (3.01 g, 96% yield). The product characterization data were as follows: IR (ATR, pure) νmax 3232, 2906 (br), 2693, 1568, 1508, 1242, 1177 cm-1; 1H NMR (DMSO-d6, 600 MHz) δ 10.11 (bs, 3H), 7.44-7.40 (m, 2H), 7.40-7.35 (m, 2H ), 7.33-7.29 (m, 1H), 7.01-6.93 (m, 4H), 5.05 (s, 2H); 13C NMR (DMSO-d6, 150MHz) δ 153.7, 139.1, 137.3, 128.5, 128.4, 128.3, 127.9, 127.7, 127.5, 117.1, 116.9, 115.5, 116.9, 115.5, 116.9, 116.9, 115.5, 117.1 116.9, 115.5, 115.3, 69.5; HRMS (EI) m/z calculated value C13H14N2 214.1106, measured value 214.1110.

References

[1] Patent: WO2012/78859, 2012, A2. Location in patent: Page/Page column 47
[2] Bioorganic and Medicinal Chemistry, 2016, vol. 24, # 18, p. 4075 - 4099
[3] Patent: EP427860, 1991, A1
[4] Bioorganic and Medicinal Chemistry, 2010, vol. 18, # 10, p. 3387 - 3402
[5] Patent: US5102891, 1992, A

4-Benzyloxyphenylhydrazine hydrochloride Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Benzyloxyphenylhydrazine hydrochloride Suppliers

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View Lastest Price from 4-Benzyloxyphenylhydrazine hydrochloride manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
4-Benzyloxyphenylhydrazine hydrochloride 52068-30-1
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2025-02-28
Career Henan Chemical Co
Product
4-Benzyloxyphenylhydrazine hydrochloride 52068-30-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1kg-1000kg
Release date
2020-01-02

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