ChemicalBook > CAS DataBase List > Pyridinium p-Toluenesulfonate
Pyridinium p-Toluenesulfonate
- Product Name
- Pyridinium p-Toluenesulfonate
- CAS No.
- 24057-28-1
- Chemical Name
- Pyridinium p-Toluenesulfonate
- Synonyms
- PPTS;PPT;PYRIDINIUM TOSYLATE;PYRIDINIUM 4-TOLUENESULFONATE;pyridinium para-toluenesulfonate;PYRIDINE P-TOLUENESULFONATE;pyridinium toluene-4-sulphonate;4-methylbenzenesulfonate,pyridin-1-ium;pyridin-1-iuM;pyridin-1-iuM 4-Methylbenzenesulfonate
- CBNumber
- CB0357874
- Molecular Formula
- C12H13NO3S
- Formula Weight
- 251.3
- MOL File
- 24057-28-1.mol
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Pyridinium p-Toluenesulfonate Property
- Melting point:
- 117-120 °C
- Density
- 1.2829 (rough estimate)
- vapor pressure
- 40Pa at 20℃
- refractive index
- 1.6000 (estimate)
- storage temp.
- Store below +30°C.
- solubility
- DMSO (Sparingly), Methanol (Slightly)
- form
- Crystalline Powder or Crystals
- color
- White to light beige
- Water Solubility
- decomposes
- Sensitive
- Moisture Sensitive
- BRN
- 3764305
- InChI
- InChI=1S/C7H8O3S.C5H5N/c1-6-2-4-7(5-3-6)11(8,9)10;1-2-4-6-5-3-1/h2-5H,1H3,(H,8,9,10);1-5H
- InChIKey
- ZDYVRSLAEXCVBX-UHFFFAOYSA-N
- SMILES
- C1(S(=O)(=O)O)C=CC(C)=CC=1.C1=CC=NC=C1
- CAS DataBase Reference
- 24057-28-1(CAS DataBase Reference)
- EPA Substance Registry System
- Pyridinium p-toluenesulfonate (24057-28-1)
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 232238
- Product name
- Pyridinium p-toluenesulfonate
- Purity
- 98%
- Packaging
- 5g
- Price
- $41.9
- Updated
- 2025/07/31
Sigma-Aldrich
- Product number
- 8.14330
- Product name
- Pyridinium 4-toluenesulfonate
- Purity
- for synthesis
- Packaging
- 25g
- Price
- $66.2
- Updated
- 2025/07/31
Sigma-Aldrich
- Product number
- 232238
- Product name
- Pyridinium p-toluenesulfonate
- Purity
- 98%
- Packaging
- 25g
- Price
- $118
- Updated
- 2025/07/31
Sigma-Aldrich
- Product number
- 8.14330
- Product name
- Pyridinium 4-toluenesulfonate
- Purity
- for synthesis
- Packaging
- 100g
- Price
- $126
- Updated
- 2025/07/31
TCI Chemical
- Product number
- P0942
- Product name
- Pyridinium p-Toluenesulfonate
- Purity
- >98.0%(T)
- Packaging
- 25g
- Price
- $17
- Updated
- 2025/07/31
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Pyridinium p-Toluenesulfonate Chemical Properties,Usage,Production
Chemical Properties
white to light beige crystalline powder or
Uses
As a co-catalyst with L-proline improved both yield and enantioselectivity of an asymmetric aldol condensation between dioxanones and aldehydes.1
Uses
Pyridinium p-Toluenesulfate is used in the synthesis of a subdomain of the cytochrome P450 BM3 enzyme, for use in screening systems for drug candidates.
Uses
Pyridinium p-Toluenesulfonate is used in the synthesis of a subdomain of the cytochrome P450 BM3 enzyme, for use in screening systems for drug candidates.
Flammability and Explosibility
Not classified
Synthesis
110-86-1
104-15-4
24057-28-1
(2) 4-methylbenzenesulfonic acid (5 g, 0.029 mol) and anhydrous tetrahydrofuran (40 mL) were added to the reactor under nitrogen protection and stirred at room temperature. The reaction mixture was cooled to 0-5 °C. At this temperature, a tetrahydrofuran solution of pyridine (2.75 g, 0.035 mol) was slowly added dropwise for 20 to 30 min, followed by continued stirring for 30 min. After completion of the reaction, the reaction mixture was filtered under nitrogen atmosphere and the solid product was collected. The filter cake was washed with anhydrous tetrahydrofuran (5 mL), and then the wet filter cake was placed in a vacuum oven and dried at 45-50 °C for 4 h to obtain the pyridinium salt of 4-methylbenzenesulfonate. The yield of the product was 6 g, the yield was 82.19% and the purity was 100% by HPLC.
References
[1] Patent: CN106565521, 2017, A. Location in patent: Paragraph 0072-0075
[2] Patent: CN106565442, 2017, A. Location in patent: Paragraph 0065; 0066; 0067
[3] Patent: CN106632223, 2017, A. Location in patent: Paragraph 0069; 0070; 0071
[4] Patent: CN106349269, 2017, A. Location in patent: Paragraph 0073; 0074; 0075
[5] Synthetic Communications, 2013, vol. 43, # 21, p. 2906 - 2912
Pyridinium p-Toluenesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Pyridinium p-Toluenesulfonate manufacturers
Nanjing Shunxiang Pharmaceutical Technology Co.,Ltd.
- Product
- Pyridinium toluene-4-sulphonate 24057-28-1
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 200tons
- Release date
- 2025-09-26
Hebei Chuanghai Biotechnology Co., Ltd
- Product
- Pyridinium p-Toluenesulfonate 24057-28-1
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-26
Hebei Chuanghai Biotechnology Co,.LTD
- Product
- Pyridinium p-Toluenesulfonate 24057-28-1
- Price
- US $9.00/KG
- Min. Order
- 1KG
- Purity
- 99.9
- Supply Ability
- 1 ton
- Release date
- 2024-08-21
24057-28-1, Pyridinium p-Toluenesulfonate Related Search:
2,4,6-Collidine
Sodium p-toluenesulfonate
2-Chloro-5-chloromethylpyridine
4-Methylpyridine
Methyl p-toluenesulfonate
p-Toluenesulfonic acid
Azamethiphos
2,6-Lutidine
Ethyl p-toluenesulfonate
Pyridinium chlorochromate
Iron(III) p-toluenesulfonate
3-(4-PHENYL-2-PYRIDYL)-5-PHENYL-1,2,4-TRIAZINE DISULFONIC ACID, DISODIUM SALT
BUFFER SOLUTION
Ferrozine disodium salt
Ferrozine sodium
2-FLUORO-1-METHYLPYRIDINIUM P-TOLUENESULFONATE
Toluene
TMPYP