ChemicalBook > CAS DataBase List > 1-(4-Bromophenyl)hexane

1-(4-Bromophenyl)hexane

Product Name
1-(4-Bromophenyl)hexane
CAS No.
23703-22-2
Chemical Name
1-(4-Bromophenyl)hexane
Synonyms
EA180;1-Bromo-4-hexyL;4-BROMOHEXYLBENZENE;P-BROMOHEXYLBENZENE;4-HEXYLBROMOBENZENE;4-n-Hexylbromobenzene;-4-has1- broMobenzene;1-BROMO-4-HEXYLBENZENE;1-(4-BROMOPHENYL)HEXANE;4-(Hex-1-yl)bromobenzene
CBNumber
CB0378079
Molecular Formula
C12H17Br
Formula Weight
241.17
MOL File
23703-22-2.mol
More
Less

1-(4-Bromophenyl)hexane Property

Boiling point:
280°C
Density 
1,18 g/cm3
refractive index 
1.52-1.522
Flash point:
280°C
storage temp. 
Store at room temperature
form 
clear liquid
Specific Gravity
1.18
color 
Colorless to Light yellow
InChI
InChI=1S/C12H17Br/c1-2-3-4-5-6-11-7-9-12(13)10-8-11/h7-10H,2-6H2,1H3
InChIKey
MXHOLIARBWJKCR-UHFFFAOYSA-N
SMILES
C1(Br)=CC=C(CCCCCC)C=C1
CAS DataBase Reference
23703-22-2(CAS DataBase Reference)
More
Less

Safety

Safety Statements 
24/25
HS Code 
29039990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

More
Less

N-Bromosuccinimide Price

TCI Chemical
Product number
B1606
Product name
1-Bromo-4-hexylbenzene
Purity
>90.0%(GC)
Packaging
5g
Price
$80
Updated
2025/07/31
TCI Chemical
Product number
B1606
Product name
1-Bromo-4-hexylbenzene
Purity
>90.0%(GC)
Packaging
25g
Price
$177
Updated
2025/07/31
TRC
Product number
B685988
Product name
1-Bromo-4-hexylbenzene
Packaging
5g
Price
$55
Updated
2021/12/16
AK Scientific
Product number
J90657
Product name
1-Bromo-4-hexylbenzene
Packaging
1g
Price
$10
Updated
2021/12/16
Oakwood
Product number
092808
Product name
1-Bromo-4-hexylbenzene
Purity
95%
Packaging
5g
Price
$45
Updated
2021/12/16
More
Less

1-(4-Bromophenyl)hexane Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

1-Bromo-4-hexylbenzene is a chemical reagent used in the preparation of conjugated nanoloops that display optoelectronic properties. Also used in the preparation of indacenodithiophene-benzothiadiazole copolymers.

Synthesis

1746-28-7

693-04-9

23703-22-2

General procedure for the synthesis of 1-bromo-4-(2-bromoethyl)benzene with n-butylmagnesium chloride as a raw material for the synthesis of 1-bromo-4-hexylbenzene: coupling reaction of alkyl halides with t-BuMgCl. Step 1 (P1): alkyl halides (1.0 mmol), decane (63 mg, as an internal standard) and LiI (5.3 mg, 0.04 mmol) were added to a reaction tube equipped with a rubber septum and a magnetic stirrer under a dry nitrogen atmosphere. THF (0.8 mL) was then added and the solution was cooled to -78 °C using a dry ice/EtOH bath. Slowly t-BuMgCl(2a) (1.5 mL, 0.81 M of THF solution, 1.2 mmol) was added, followed by isoprene (136.2 mg, 2.0 mmol). To this mixture was added CoCl2 [2.6 mg, 0.02 mmol, as a powder or as a THF solution (0.5 mL, 0.04 M)]. (Note 1: CoCl2 should be added immediately after isoprene addition or the catalytic efficiency will be significantly reduced.) Remove the cold bath, warm the mixture slowly to room temperature (about 10 min), and then heat the reaction vessel in a 50°C oil bath for 5 hr. (Note 2: If the reaction mixture is heated at 30 °C at this stage, unidentified side reactions can occur, resulting in lower yields of coupling products.) Upon completion of the reaction, the mixture is cooled to 0 °C in an ice bath and the reaction is quenched with 1 M aqueous HCl (5 mL). The product was extracted with Et2O (3 x 20 mL). The organic layers were combined, dried with Na2SO4, concentrated and analyzed by gas chromatography to determine the GC yield. The residue was purified by silica gel column chromatography or GPC. Under standard conditions, 1.0 mmol of 1-bromo-4-(2-bromoethyl)benzene was reacted with n-BuMgCl(2j) (1.0 M in THF, 1.2 mmol) in 94% yield (determined by GC using decane as an internal standard).

References

[1] Journal of the American Chemical Society, 2002, vol. 124, # 16, p. 4222 - 4223
[2] Journal of the American Chemical Society, 2013, vol. 135, # 26, p. 9604 - 9607
[3] Synthesis (Germany), 2014, vol. 46, # 12, p. 1583 - 1592
[4] Journal of Organic Chemistry, 2014, vol. 79, # 18, p. 8522 - 8532

1-(4-Bromophenyl)hexane Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

1-(4-Bromophenyl)hexane Suppliers

Americas 1 Belgium 1 China 176 Europe 1 France 1 Germany 3 India 5 Japan 2 Lithuania 1 The Netherlands 1 United Kingdom 8 United States 19 Global 219
Shanghai Meiquan Chemical Technology Co., Ltd.
Tel
15802146997; 15802146997
Email
zkq1984@163.com
Country
China
ProdList
454
Advantage
58
Zhengzhou Huiju Chemical Co., Ltd.
Tel
0371-55900031 18137872243
Fax
QQ：2853979815
Email
2853979815@qq.com
Country
China
ProdList
9975
Advantage
55
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11035
Advantage
64
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
Advantage
57
Shanghai Sunway Pharmaceutical Technology Co., Ltd
Tel
18270980682
Fax
021 51613951
Email
mlcheng@sunwaypharm.cn
Country
China
ProdList
8669
Advantage
57
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
More
Less

View Lastest Price from 1-(4-Bromophenyl)hexane manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
1-(4-Bromophenyl)hexane 23703-22-2
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100 mt
Release date
2025-03-14
Honest Joy Holdings Limited
Product
1-(4-Bromophenyl)hexane 23703-22-2
Price
US $0.00/KG
Min. Order
1KG
Purity
97.8%
Supply Ability
100 tons
Release date
2022-01-26
Zhuozhou Wenxi import and Export Co., Ltd
Product
1-(4-Bromophenyl)hexane 23703-22-2
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

23703-22-2, 1-(4-Bromophenyl)hexaneRelated Search:

Decabromodiphenyl Ethane Bromobenzene Hexane Benzbromarone Benzyldodecyldimethylammonium bromide Methylcyclohexane Cyclohexene oxide 1-Bromohexane Cyclohexane Bromine 1-BROMO-4-N-HEPTYLBENZENE 1-(4-Bromophenyl)octane 4-BROMOPENTANOPHENONE 1-Bromo-4-cyclohexylbenzene 1-BROMO-4-DECYLBENZENE 1-BROMO-4-N-NONYLBENZENE P-BROMOPHENYL N-HEPTYL KETONE 1-BROMO-4-DODECYLBENZENE

  • 1-Bromo-4-n-hexylbenzene,97%
  • 1-Bromo-4-(hex-1-yl)benzene 97%
  • -4-has1- broMobenzene
  • 1-BROMO-4-HEXYLBENZENE
  • 1-BROMO-4-N-HEXYLBENZENE
  • 1-(4-BROMOPHENYL)HEXANE
  • 4-BROMOHEXYLBENZENE
  • 4-n-Hexylbromobenzene
  • 4-HEXYLBROMOBENZENE
  • P-BROMOHEXYLBENZENE
  • 4-(Hex-1-yl)bromobenzene
  • OC1697, 1-Bromo-4-hexylbenzene
  • 1-Bromo-4-hexyL
  • 1-Bromo-4-hexylbenzene &gt
  • Benzene, 1-bromo-4-hexyl-
  • 1-(4-Bromophenyl)hexane ISO 9001：2015 REACH
  • EA180
  • 1-Bromo-4-(hex-1-yl)benzene
  • 23703-22-2
  • 4-Alkylbromobenzenes (Building Blocks for Liquid Crystals)
  • Building Blocks for Liquid Crystals
  • Functional Materials
  • 4-Alkylbromobenzenes (Building Blocks for Liquid Crystals)
  • Building Blocks for Liquid Crystals