Methyl trans-2-nonenoate

ChemicalBook > CAS DataBase List > Methyl trans-2-nonenoate

Methyl trans-2-nonenoate

Product Name: Methyl trans-2-nonenoate
CAS No.: 111-79-5
Chemical Name: Methyl trans-2-nonenoate
Synonyms: NEOFOLIONE;BEAUVERTATE;METHYL 2-NONENOATE;Nsc76416;FEMA 2725;AI3-02449;methylnon-2;Wln: 7U1vo1;Methyl 2-none;melon nonenoate
CBNumber: CB0392558
Molecular Formula: C10H18O2
Formula Weight: 170.25
MOL File: 111-79-5.mol

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Methyl trans-2-nonenoate Property

Melting point:: -89.9°C (estimate)
Boiling point:: 115 °C21 mm Hg(lit.)
Density: 0.895 g/mL at 25 °C(lit.)
vapor pressure: 13.33hPa at 95.84℃
refractive index: n20/D 1.444(lit.)
FEMA: 2725 | METHYL 2-NONENOATE
Flash point:: 196 °F
storage temp.: Sealed in dry,Room Temperature
Odor: at 100.00 %. sweet green waxy violet pear fruity melon vegetable
Odor Type: green
Water Solubility: 52.1mg/L at 25℃
JECFA Number: 1813
LogP: 3.6 at 25℃
CAS DataBase Reference: 111-79-5(CAS DataBase Reference)
NIST Chemistry Reference: 2-Nonenoic acid, methyl ester(111-79-5)
EPA Substance Registry System: 2-Nonenoic acid, methyl ester (111-79-5)

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Safety

Hazard Codes: Xi,N
Risk Statements: 36/38-51/53
Safety Statements: 26-61
RIDADR: UN 3082 9/PG 3
WGK Germany: 2
RTECS: RA9470000
Toxicity: Both the acute oral LD₅₀ value in rats and the acute dermal LD₅₀ value in rabbits exceeded 5 g/kg (Moreno, 1975)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

AK Scientific

Product number: 5753AF
Product name: Methyl2-nonenoate
Packaging: 5g
Price: $27
Updated: 2021/12/16

Chem-Impex

Product number: 34596
Product name: Methyltrans-2-nonenoate,95-100%(PuritybyGC),meetsFGspecifications,KOSHER,FEMA2725Hazmat
Purity: 95-100%(PuritybyGC)
Packaging: 5G
Price: $29.12
Updated: 2021/12/16

AK Scientific

Product number: 2106AA
Product name: Methyl2-methylnon-2-enoate
Packaging: 100g
Price: $118
Updated: 2021/12/16

Chem-Impex

Product number: 34596
Product name: Methyltrans-2-nonenoate,95-100%(PuritybyGC),meetsFGspecifications,KOSHER,FEMA2725Hazmat
Purity: 95-100%(PuritybyGC)
Packaging: 1KG
Price: $471.74
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: FFG0002650
Product name: METHYL TRANS-2-NONENOATE
Purity: 95.00%
Packaging: 100G
Price: $2488.56
Updated: 2021/12/16

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Methyl trans-2-nonenoate Chemical Properties,Usage,Production

Description

Methyl 2-nonenoate has a characteristic violet-like odor. May be obtained in quantitative yields by treating methyl P-chlorocaproate with sodium acetate, or by dehydrogenating the corresponding saturated ester.

Physical properties

Methyl trans-2-nonenoate is colorless to slightly yellow liquid;strong violet-leaf odor. Stable; soluble in alco-hol. Combustible.

Chemical Properties

Methyl 2-Nonenoate is a colorless to pale yellow liquid with a green, floral note. It imparts freshness to floral fragrance compositions and is recommended as a substitute for methyl 2-octynoate.The synthesis consists of a condensation of heptanal withmalonic acid, decarboxylation, and subsequent esterification with methanol.

Occurrence

Methyl trans-2-nonenoate has apparently not been reported to occur in nature.

Uses

Perfumes.

Definition

ChEBI: Methyl 2-nonenoate is a fatty acid ester.

Preparation

Obtained in quantitative yields by treating methyl β-chlorocaproate with sodium acetate, or by dehydrogenating the corresponding saturated ester.

Taste threshold values

Taste characteristics at 5 ppm: green, waxy, oily, fruity, watermelon rind, pear- and apple-like.

Synthesis Reference(s)

The Journal of Organic Chemistry, 54, p. 1831, 1989 DOI: 10.1021/jo00269a017
Synthetic Communications, 24, p. 2069, 1994 DOI: 10.1080/00397919408010217
Tetrahedron Letters, 30, p. 6555, 1989 DOI: 10.1016/S0040-4039(01)89020-1

Flammability and Explosibility

Not classified

Trade name

Neofolione (Givaudan).

Metabolism

2-Nonenoic acid produced by the hydrolysis of methyl nonylenate will presumably pass through the normal pathways of fatty acid metabolism (Lehninger, 1970)

Methyl trans-2-nonenoate Preparation Products And Raw materials

Raw materials

Heptaldehyde Triethylamine METHYL NONANOATE Methanol Malonic acid

Preparation Products

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View Lastest Price from Methyl trans-2-nonenoate manufacturers

Hebei Mojin Biotechnology Co., Ltd

Product: Methyl trans-2-nonenoate 111-79-5
Price: US $100.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5000KG
Release date: 2023-08-31

Hebei Guanlang Biotechnology Co., Ltd.

Product: Methyl trans-2-nonenoate 111-79-5
Price: US $1.00/PCS
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2021-06-10

Zhuozhou Wenxi import and Export Co., Ltd

Product: Methyl trans-2-nonenoate 111-79-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

111-79-5, Methyl trans-2-nonenoateRelated Search:

ETHYL TRANS-2-DECENOATE OLIGOMYCIN B DIGOXIN GITOXIN Digitoxin LANATOSIDE B GITOXIGENIN DIGITOXIGENIN RUBRATOXIN B CYMARIN CYTOCHALASIN A LANATOSIDE A Methyl trans-2-nonenoate G-STROPHANTHIN METHYL NONENOATE METHYL TRANS-3-NONENOATE METHYL TRANS-3-NONENOATE Aliskiren inter-7

RARECHEM AL BF 0154

NEOFOLIONE

2-NONENOIC ACID METHYL ESTER

METHYL NONYLENATE

METHYL NONYLENOATE

METHYL 2-NONENOATE (MAX 90% TRANS)

2-ethylideneoctanoate

Methyl 2-none

METHYL NON-2-ENOATE

METHYL-2-NONENATE

METHYL 2-NONENOATE

BEAUVERTATE

FEMA 2725

Methyl trans-2-nonenoate

METHYL-2-NONENOATE, 1-PEAK

METHYL-2-NONENOATE, 2-PEAK

Methyl (2E)-2-nonenoate

methylnon-2

non-2-enoicacidmethylester

METHYL TRANS-2-NONENOATE 97+%

Methyl 2-nonylenate

AI3-02449

Methylnon-2-enoat

Nsc76416

Wln: 7U1vo1

Methyl trans-2-nonenoate,Methyl 2-nonenoate

melon nonenoate

Methyl 2-Methylnon-2-enoate

(E)-Methyl non-2-enoate

Methyl trans-2-nonenoate USP/EP/BP

Ethyl strawberryrate

Methyl -2-nonenoate(kosher)

Nonenoic acid, methyl ester

111-79-5

CH3CH25CHCHCOOCH3

CH3CH25CHCHCO2CH3