tert-Butyldimethylsilane

Product Name: tert-Butyldimethylsilane
CAS No.: 29681-57-0
Chemical Name: tert-Butyldimethylsilane
Synonyms: CFS-570;DKSI032;Co-Formula CFS-570;Butyldimethylsilane;t-Butyldimethylsilyl;T-BUTYLDIMETHYLSILANE;triethyl-propyl-silane;TERT-BUTYLDIMETHYLSILANE;Dimethyl tert-butylsilane;tert-butyl(dimethyl)silicon
CBNumber: CB0399704
Molecular Formula: C6H16Si
Formula Weight: 116.28
MOL File: 29681-57-0.mol

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tert-Butyldimethylsilane Property

Melting point:: 13°C
Boiling point:: 81-83 °C (lit.)
Density: 0.701 g/mL at 25 °C (lit.)
refractive index: n20/D 1.4(lit.)
Flash point:: −9 °F
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: clear liquid
color: Colorless to Almost colorless
Specific Gravity: 0.701
Hydrolytic Sensitivity: 3: reacts with aqueous base
BRN: 2231162
InChI: InChI=1S/C6H16Si/c1-6(2,3)7(4)5/h7H,1-5H3
InChIKey: QCIWZIYBBNEPKB-UHFFFAOYSA-N
SMILES: [SiH](C(C)(C)C)(C)C
CAS DataBase Reference: 29681-57-0

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Safety

Hazard Codes: F,Xi
Risk Statements: 11-36/37/38
Safety Statements: 16-26-36-16/26/36
RIDADR: UN 1993 3/PG 2
WGK Germany: 3
F: 10-21
TSCA: Yes
HazardClass: 3.1
PackingGroup: I
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 294764
Product name: tert-Butyldimethylsilane
Purity: 95%
Packaging: 5g
Price: $67.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 294764
Product name: tert-Butyldimethylsilane
Purity: 95%
Packaging: 25g
Price: $276
Updated: 2024/03/01

TCI Chemical

Product number: B3565
Product name: tert-Butyldimethylsilane
Purity: >95.0%(GC)
Packaging: 5g
Price: $76
Updated: 2024/03/01

TRC

Product number: B942780
Product name: tert-Butyldimethylsilane
Packaging: 1g
Price: $75
Updated: 2021/12/16

Usbiological

Product number: 263684
Product name: tert-Butyldimethylsilane
Packaging: 2g
Price: $402
Updated: 2021/12/16

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tert-Butyldimethylsilane Chemical Properties,Usage,Production

Uses

Tert-Butyldimethylsilane (t-BuMe2SiH) is widely used for the protection of hydroxy groups in sugars. Its oxidation product, tert-butyldimethylsilyl hydroperoxide (t-BuMe2SiOOH), is used for preparing luminiscent sources and prostanoids, specifically clavulons[1].

Reactions

The iridium complex [Ir(COD)(PPh3)2]+SbF6- reacts with tert-butyldimethylsilane in DMA to form [IrH2(Sol)2(PPh3)2]+SbF6-, which is an active catalyst for the regioselective di- and trisilylation of a series of representative methyl hexopyranosides, β-1,6-anhydrohexopyranosides and 1,3,5-O-methylidene inositol.The silylcarbobicyclization of 4,4-disubstituted 1,6-heptadiynes with tert-butyldimethylsilane catalyzed by Rh(acac)(CO)2, Co2Rh2(CO)12, or (t-BuNC)4RhCo(CO)4 under 50 atm of carbon monoxide gives the corresponding novel 7,7-disubstituted 2-silylbicyclo[3.3.0]octa-1,5-dien-3-ones in good yields[2-3].

References

[1] Iwao Ojima, Jiawang Zhu, Dora Fracchiolla Kass. “New and Efficient Catalytic Route to Bicyclo[3.3.0]octa-1,5-dien-3-ones.” Organometallics 15 24 (1996): 5191–5195.
[2] Mee-Kyung Chung, Marcel Schlaf. “Regioselectively Trisilylated Hexopyranosides through Homogeneously Catalyzed Silane Alcoholysis.” Journal of the American Chemical Society 127 51 (2005): 18085–18092.
[3] Iwao Ojima, Jiawang Zhu, Dora Fracchiolla Kass. “New and Efficient Catalytic Route to Bicyclo[3.3.0]octa-1,5-dien-3-ones.” Organometallics 15 24 (1996): 5191–5195.

tert-Butyldimethylsilane Preparation Products And Raw materials

Raw materials

Preparation Products

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tert-Butyldimethylsilane Suppliers

Americas 1 China 116 Europe 1 Germany 1 India 8 Italy 1 Japan 1 Singapore 1 Switzerland 2 United Kingdom 4 United States 21 Global 157

Alfa Chemistry

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View Lastest Price from tert-Butyldimethylsilane manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: T-BUTYLDIMETHYLSILANE 29681-57-0
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-11-01

Hebei Yanxi Chemical Co., Ltd.

Product: T-BUTYLDIMETHYLSILANE 29681-57-0
Price: US $30.00-10.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10 tons
Release date: 2023-11-14

Hebei Mojin Biotechnology Co., Ltd

Product: T-BUTYLDIMETHYLSILANE 29681-57-0
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-10-11

29681-57-0, tert-ButyldimethylsilaneRelated Search:

TERT-BUTYLDIMETHYLSILANOL Chloro-tert-butyldimethylsilan t-Butyl methyl fumarate ALLYLOXY-T-BUTYLDIMETHYLSILANE t-butyldimethylIsopropoxylsilane tert-butyl-methoxy-dimethylsilane TERT-BUTYLDIMETHYLSILYL (R)-(-)-GLYCIDY& Tert-butyl-dimethyl-(tributylstannylmethoxy)silane tert-butyldimethyl(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy)silane N-(tert-Butyldimethylsilyl)-N-methyl-trifluoroacetamide AMINOXY-TERT-BUTYLDIMETHYLSILANE DIMETHYLTHEXYLSILYL CHLORIDE N-BUTYLDIMETHYLSILANE 3-BROMOPROPOXY-T-BUTYLDIMETHYLSILANE,(3-BROMOPROPOXY)-TERT-BUTYLDIMETHYLSILANE 5-O-(tert-Butyldimethylsilyl)-2,3-O-isoproylidene-D-ribofuranose (2-BROMOETHOXY)-TERT-BUTYLDIMETHYLSILANE ethynyl-t-butyldimethylsilane,ETHYNYL-TERT-BUTYLDIMETHYLSILANE DIMETHYLSILANE

T-BUTYLDIMETHYLSILANE

TERT-BUTYLDIMETHYLSILANE

Butyldimethylsilane

triethyl-propyl-silane

Dimethyl tert-butylsilane

tert-ButyldiMethylsilane 95%

<i>tert</i>-Butyldimethylsilane

Dimethyl(2-methyl-2-propanyl)silane

CFS-570

(1,1-dimethylethyl)dimethyl-

Co-Formula CFS-570

Silane,(1,1-dimethylethyl)dimethyl-

tert-Butyldimethylsilane &gt

t-Butyldimethylsilyl

tert-butyl(dimethyl)silicon

DKSI032

29681-57-0

CH33CSiHCH32

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Organometallic Reagents

Organosilicon

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