TERT-BUTYLDIMETHYLSILANOL
- Product Name
- TERT-BUTYLDIMETHYLSILANOL
- CAS No.
- 18173-64-3
- Chemical Name
- TERT-BUTYLDIMETHYLSILANOL
- Synonyms
- T-BUTYLDIMETHYLSILANOL;DK157;DK626;DKFELEX0156;Butyldimethylsilanol;TERT-BUTYLDIMETHYLSILANOL;tert-ButyldiMethylsilanol 99%;tert-Butyldimethylhydroxysilane;ert-butyl-hydroxy-dimethylsilane;tert-Butyldimethylsilanol
- CBNumber
- CB4189448
- Molecular Formula
- C6H16OSi
- Formula Weight
- 132.28
- MOL File
- 18173-64-3.mol
TERT-BUTYLDIMETHYLSILANOL Property
- Melting point:
- 18 °C
- Boiling point:
- 139 °C/739 mmHg (lit.)
- Density
- 0.84 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.424(lit.)
- Flash point:
- 113 °F
- storage temp.
- Storage temp. 2-8°C
- solubility
- soluble in Benzene
- form
- clear liquid
- pka
- 15.37±0.53(Predicted)
- Specific Gravity
- 0.840
- color
- Colorless to Almost colorless
- Hydrolytic Sensitivity
- 4: no reaction with water under neutral conditions
- BRN
- 1732777
- InChI
- InChI=1S/C6H16OSi/c1-6(2,3)8(4,5)7/h7H,1-5H3
- InChIKey
- FGWRMMTYIZKYMA-UHFFFAOYSA-N
- SMILES
- [Si](C(C)(C)C)(C)(C)O
Safety
- Hazard Codes
- Xi
- Risk Statements
- 10-36/37/38
- Safety Statements
- 26-36
- RIDADR
- UN 1987 3/PG 3
- WGK Germany
- 3
- F
- 10-21
- TSCA
- No
- HS Code
- 2931.90.9010
- HazardClass
- 3.2
- PackingGroup
- III
- Storage Class
- 3 - Flammable liquids
- Hazard Classifications
- Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 289094
- Product name
- tert-Butyldimethylsilanol
- Purity
- 99%
- Packaging
- 5g
- Price
- $102.02
- Updated
- 2025/07/31
- Product number
- 289094
- Product name
- tert-Butyldimethylsilanol
- Purity
- 99%
- Packaging
- 25g
- Price
- $363.6
- Updated
- 2025/07/31
- Product number
- B5499
- Product name
- tert-Butyldimethylsilanol
- Purity
- >95.0%(GC)
- Packaging
- 5mL
- Price
- $85
- Updated
- 2025/07/31
- Product number
- B5499
- Product name
- tert-Butyldimethylsilanol
- Purity
- >95.0%(GC)
- Packaging
- 25mL
- Price
- $272
- Updated
- 2025/07/31
- Product number
- B943428
- Product name
- tert-Butyldimethylsilanol
- Packaging
- 2.5mg
- Price
- $100
- Updated
- 2021/12/16
TERT-BUTYLDIMETHYLSILANOL Chemical Properties,Usage,Production
Uses
tert-Butyldimethylsilanol can be used as a silylating agent for the protection of hydroxyl groups via silylation. It is used:
- For the preparation of α-chiral ether derivatives by catalytic asymmetric allylic substitution.
- As an initiator for the polymerization of 1,2 benzenedicarboxaldehyde.
- In the synthesis of enol silyl ethers.
Synthesis
Tert-butyldimethylsilanol is prepared as follows:
1.86 mg (0.01 mmol) of 4,4'-diamino-2,2'-bipyridine, 1.77 mg (0.005 mmol) of manganese (II) perchlorate hexahydrate, 1.5 mL of acetone were added to a reaction tube and the reaction was stirred for 2 hr at 80 ??C, cooled down to ambient temperature, 68 mg (0.5 mmol) of tert-butyldimethyl Silane, then 250μL of hydrogen peroxide with a mass concentration of 30% was diluted with 0.5 mL of acetone and added to the reaction tube through a flow syringe pump for 15 minutes in succession, and after addition, the remaining hydrogen peroxide was quenched by adding saturated sodium sulfite to the reaction solution, and the solution was extracted with ethyl acetate to obtain tert-butyldimethylsilanol with a yield of 94%.
TERT-BUTYLDIMETHYLSILANOL Preparation Products And Raw materials
Raw materials
Preparation Products
TERT-BUTYLDIMETHYLSILANOL Suppliers
- Tel
- 18210857532; 18210857532
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 4006356688 18621169109
- Fax
- 86-21-61259102
- market03@meryer.com
- Country
- China
- ProdList
- 40228
- Advantage
- 62
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24529
- Advantage
- 81
- Tel
- 010-89508211 18501085097
- Fax
- 010-89508210
- sales.bj@hwrkchemical.com
- Country
- China
- ProdList
- 9401
- Advantage
- 55
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
- Country
- China
- ProdList
- 42934
- Advantage
- 64
- Tel
- Fax
- E-Mail Inquiry
- info@syntechem.com
- Country
- China
- ProdList
- 12984
- Advantage
- 57
- Tel
- 86-21-63210123
- Fax
- 86-21-63290778 86-21-63218885
- sj_scrc@sinopharm.com
- Country
- China
- ProdList
- 9815
- Advantage
- 79
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28387
- Advantage
- 80
- Tel
- 320-37350700
- Fax
- +32 (0)37350701
- sales@tcieurope.eu
- Country
- Europe
- ProdList
- 23671
- Advantage
- 75
- Tel
- 800-4238616
- Fax
- +1-888-520-1075 / +1-503-283-1987
- sales@tciamerica.com
- Country
- Americas
- ProdList
- 23653
- Advantage
- 75
View Lastest Price from TERT-BUTYLDIMETHYLSILANOL manufacturers
- Product
- TERT-BUTYLDIMETHYLSILANOL 18173-64-3
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-10
- Product
- TERT-BUTYLDIMETHYLSILANOL 18173-64-3
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-08
- Product
- TERT-BUTYLDIMETHYLSILANOL 18173-64-3
- Price
- US $9.80/KG
- Min. Order
- 1g
- Purity
- ≥99%
- Supply Ability
- 100kg
- Release date
- 2020-01-08