ChemicalBook > CAS DataBase List > TERT-BUTYL-2-BROMOBENZOATE

TERT-BUTYL-2-BROMOBENZOATE

Product Name: TERT-BUTYL-2-BROMOBENZOATE
CAS No.: 55666-42-7
Chemical Name: TERT-BUTYL-2-BROMOBENZOATE
Synonyms: TERT-BUTYL-2-BROMOBENZOATE;2-BROMO-BENZOIC ACID TERT-BUTYL ESTER;Benzoic acid, 2-bromo-, 1,1-dimethylethyl ester
CBNumber: CB0401922
Molecular Formula: C11H13BrO2
Formula Weight: 257.12
MOL File: 55666-42-7.mol

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TERT-BUTYL-2-BROMOBENZOATE Property

Boiling point:: 280.3±13.0 °C(Predicted)
Density: 1.331±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
Appearance: Colorless to light yellow Liquid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B789290
Product name: tert-Butyl2-Bromobenzoate
Packaging: 100mg
Price: $75
Updated: 2021/12/16

AK Scientific

Product number: J96520
Product name: tert-Butyl2-bromobenzoate
Packaging: 5g
Price: $80
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0027223
Product name: TERT-BUTYL-2-BROMOBENZOATE
Purity: 95.00%
Packaging: 1G
Price: $685.21
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0027223
Product name: TERT-BUTYL-2-BROMOBENZOATE
Purity: 95.00%
Packaging: 5G
Price: $1103.6
Updated: 2021/12/16

Ambeed

Product number: A252201
Product name: tert-Butyl2-bromobenzoate
Purity: 97%
Packaging: 1g
Price: $23
Updated: 2021/12/16

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TERT-BUTYL-2-BROMOBENZOATE Chemical Properties,Usage,Production

Synthesis

7154-66-7

75-65-0

55666-42-7

Example 64: Synthesis of tert-butyl 2-bromobenzoate Step A. To a solution of 2-bromobenzoyl chloride (2.0 g, 9.11 mmol) in anhydrous ethyl ether (40 mL) was added sequentially tert-butanol (0.96 mL, 10.02 mmol) and 4-(dimethylamino)pyridine (111 mg, 0.91 mmol). The reaction mixture was stirred at room temperature for 48 hours under nitrogen protection. After completion of the reaction, the resulting white suspension was extracted by partitioning with ethyl acetate (100 mL) and 1 M hydrochloric acid (100 mL). The organic phase was separated and washed sequentially with 1 M hydrochloric acid (100 mL), 2 M sodium hydroxide (2 x 100 mL), water (100 mL) and saturated saline (100 mL). The organic phase was dried with anhydrous magnesium sulfate and concentrated under reduced pressure to give a yellow oil. Purification by fast column chromatography with ethyl acetate/hexane as eluent gave tert-butyl 2-bromobenzoate (1.22 g, 52% yield) as a colorless oil.

References

[1] Organic Letters, 2011, vol. 13, # 19, p. 5326 - 5329
[2] Patent: US2006/287522, 2006, A1. Location in patent: Page/Page column 41

TERT-BUTYL-2-BROMOBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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55666-42-7, TERT-BUTYL-2-BROMOBENZOATERelated Search:

Tert-butyl 2-bromo-4,5-dimethylbenzoate Magnesium oxide Chlorine dioxide 2,2-Dimethoxy-2-phenylacetophenone TERT-BUTYL-4-BROMOBENZOATE tert-Butyl 2-bromo-4-fluorobenzoate tert-Butyl 2,6-difluoronicotinate tert-Butyl2-chloro-4-fluoroBenzoate tert-butyl 3,5-dibroMobenzoate Tert-butyl 2-bromo-6-fluoro-3-methoxybenzoate tert-butyl 2-broMo-5-fluorobenzoate Tert-butyl 2-bromo-5-(trifluoromethyl)benzoate tert-Butyl3,5-difluorobenzoate Tert-butyl 3,5-dichloro-2-fluorobenzoate Tert-butyl 3,5-dichloro-4-methoxybenzoate TERT-BUTYL-2-BROMONICOTINATE Tert-butyl 2,6-difluoro-4-iodobenzoate TERT-BUTYL-3-BROMOBENZOATE

TERT-BUTYL-2-BROMOBENZOATE

2-BROMO-BENZOIC ACID TERT-BUTYL ESTER

Benzoic acid, 2-bromo-, 1,1-dimethylethyl ester

55666-42-7

Aryl

Ester

Organohalides