TERT-BUTYL-3-BROMOBENZOATE

Product Name: TERT-BUTYL-3-BROMOBENZOATE
CAS No.: 69038-74-0
Chemical Name: TERT-BUTYL-3-BROMOBENZOATE
Synonyms: t-Butyl-3-bromobenzoate;TERT-BUTYL-3-BROMOBENZOATE;3-bromo-2-tert-butylbenzoate;tert-Butyl 3-bromobenzoate 95+%;Tert-Butyl 3-Bromobenzoate,Canonical;3-Bromobenzoic Acid-tert-Butyl Ester;Benzoic acid, 3-broMo-, 1,1-diMethylethyl ester
CBNumber: CB3486003
Molecular Formula: C11H13BrO2
Formula Weight: 257.12
MOL File: 69038-74-0.mol

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TERT-BUTYL-3-BROMOBENZOATE Property

storage temp.: Sealed in dry,Room Temperature
form: liquid
color: Colourless
InChI: InChI=1S/C11H13BrO2/c1-11(2,3)14-10(13)8-5-4-6-9(12)7-8/h4-7H,1-3H3
InChIKey: NPVLZVSAZXTBSR-UHFFFAOYSA-N
SMILES: C(OC(C)(C)C)(=O)C1=CC=CC(Br)=C1

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Safety

HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B690513
Product name: t-Butyl3-bromobenzoate
Packaging: 500mg
Price: $65
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2623-9-03
Product name: tert-Butyl 3-bromobenzoate
Purity: 98%
Packaging: 250mg
Price: $15
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2623-9-03
Product name: tert-Butyl 3-bromobenzoate
Purity: 98%
Packaging: 1g
Price: $45
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB142657
Product name: tert-Butyl 3-bromobenzoate
Packaging: 2g
Price: $51
Updated: 2021/12/16

ChemScene

Product number: CS-M2538
Product name: Benzoicacid,3-bromo-,1,1-dimethylethylester
Purity: 99.57%
Packaging: 5g
Price: $54
Updated: 2021/12/16

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TERT-BUTYL-3-BROMOBENZOATE Chemical Properties,Usage,Production

Synthesis

585-76-2

83766-88-5

69038-74-0

Boron trifluoride diethyl ether compound (0.31 g, 2.21 mmol) was added as m-bromobenzoic acid (0.2 g, 1.64 mmol) and 2-(tert-butoxy)pyridine (0.33 g, 2.21 mmol) after dissolution in anhydrous toluene (2 mL). The reaction mixture was stirred at room temperature for 30 min, followed by quenching the reaction with anhydrous sodium bicarbonate. The reaction mixture was diluted with ethyl acetate (30 mL) and washed sequentially with water (20 mL) and brine (20 mL). The organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting residue was purified by fast column chromatography on silica gel with dichloromethane/hexane (0:4 to 1:4) as eluent to afford the target product tert-butyl m-bromobenzoate (5a) as a colorless oil.

References

[1] Tetrahedron, 2018, vol. 74, # 27, p. 3748 - 3754

TERT-BUTYL-3-BROMOBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TERT-BUTYL-3-BROMOBENZOATE Suppliers

China 109 India 1 United Kingdom 5 United States 12 Global 127

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View Lastest Price from TERT-BUTYL-3-BROMOBENZOATE manufacturers

Career Henan Chemical Co

Product: TERT-BUTYL-3-BROMOBENZOATE 69038-74-0
Price: US $1.00/kg
Min. Order: 1kg
Purity: 95%-99%
Supply Ability: 100kg
Release date: 2018-12-20

69038-74-0, TERT-BUTYL-3-BROMOBENZOATERelated Search:

Tert-butyl 3-chloro-2-methoxyisonicotinate tert-butyl 3-fluoro-5-(methylthio)benzoate Tert-butyl 3-bromo-4-methoxybenzoate tert-butyl 3-Bromo-4-iodo-5-methylbenzoate tert-Butyl 3-fluoro-4-methylbenzoate 3-Bromo-5-trifluoromethyl-benzoic acid tert-butyl ester 2,2-Dimethoxy-2-phenylacetophenone TERT-BUTYL-4-BROMOBENZOATE TERT-BUTYL-2-BROMOBENZOATE Tert-Butyl-4'-bromobenzoate-2'-boronicacid tert-Butyl 5-bromo-2-chlorobenzoate TERT-BUTYL 3-BROMO-4-NITROBENZOATE TERT-BUTYL-3-BROMOBENZOATE T-BUTYL 3-BROMO-4-FLUOROBENZOATE

3-bromo-2-tert-butylbenzoate

tert-Butyl 3-bromobenzoate 95+%

t-Butyl-3-bromobenzoate

Benzoic acid, 3-broMo-, 1,1-diMethylethyl ester

TERT-BUTYL-3-BROMOBENZOATE

3-Bromobenzoic Acid-tert-Butyl Ester

Tert-Butyl 3-Bromobenzoate,Canonical

69038-74-0

Esters

Phenyls & Phenyl-Het

Aryl

Ester

Organohalides

Phenyls & Phenyl-Het