ChemicalBook > CAS DataBase List > (+)-Diisopinocampheyl chloroborane

(+)-Diisopinocampheyl chloroborane

Product Name
(+)-Diisopinocampheyl chloroborane
CAS No.
112246-73-8
Chemical Name
(+)-Diisopinocampheyl chloroborane
Synonyms
(+)DPC;oroborane;(+)-IPC2BCL;(+)-DIP CHLORIDE;(+)-DIP-CHLORIDE;(+)-DIP chloride[R];(+)-DIP-CHLORIDE(TM);(+)-DiisopinocampheyL;(+)-DIP CHLORIDE SOLUTION;(+)-DIP-Chloride?
CBNumber
CB0413893
Molecular Formula
C20H34BCl
Formula Weight
320.75
MOL File
112246-73-8.mol
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(+)-Diisopinocampheyl chloroborane Property

Melting point:
53-55 °C(lit.)
Boiling point:
369.6±25.0 °C(Predicted)
Density 
0.91
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
sol in both polar and nonpolar aprotic solvents like diethyl ether, THF, methylene chloride, pentane, hexane, etc
form 
clear liquid
color 
Colorless to Almost colorless
InChI
InChI=1S/C20H34BCl/c1-11-15-7-13(19(15,3)4)9-17(11)21(22)18-10-14-8-16(12(18)2)20(14,5)6/h11-18H,7-10H2,1-6H3/t11-,12-,13+,14+,15-,16-,17-,18-/m0/s1
InChIKey
PSEHHVRCDVOTID-YYNWCRCSSA-N
SMILES
B(Cl)([C@H]1C[C@@]2([H])C[C@]([H])(C2(C)C)[C@@H]1C)[C@H]1C[C@@]2([H])C[C@]([H])(C2(C)C)[C@@H]1C
CAS DataBase Reference
112246-73-8(CAS DataBase Reference)
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Safety

Hazard Codes 
C
Risk Statements 
34-37
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
10-21
HazardClass 
8
PackingGroup 
III
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
317012
Product name
(+)-DIP-Chloride?
Purity
90-105% (approx.)
Packaging
5g
Price
$105.2
Updated
2025/07/31
Sigma-Aldrich
Product number
317012
Product name
(+)-DIP-Chloride?
Purity
90-105% (approx.)
Packaging
25g
Price
$192
Updated
2025/07/31
TCI Chemical
Product number
C1614
Product name
(+)-B-Chlorodiisopinocampheylborane (58% in Hexane, ca. 1.6mol/L)
Packaging
100mL
Price
$268
Updated
2025/07/31
TRC
Product number
D486760
Product name
(+)-DIP-chloride(60%inn-Heptane)
Packaging
1ml
Price
$50
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC59961
Product name
(+)-B-Chlorodiisopinocampheylborane - 58% in Hexane
Packaging
5G
Price
$60
Updated
2021/12/16
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(+)-Diisopinocampheyl chloroborane Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols.

Precautions

(+)-Diisopinocampheyl chloroborane and its solutions are moisture and air sensitive. The reagent reacts instantaneously with water and protic solvents to liberate HCl. Containers of DIP-Chloride should be stored in the absence of moisture. Cans or bottles of DIP-Chloride should be flushed with N2 and kept tightly sealed to avoid contact of oxygen and moisture.

storage

(+)-Diisopinocampheyl chloroborane should be crushed, transferred, or weighed only in glove bag or dry box under N2 atmosphere. The reagent can be stored for several years under N2 atmosphere below 25 °C.

(+)-Diisopinocampheyl chloroborane Preparation Products And Raw materials

Raw materials

Preparation Products

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(+)-Diisopinocampheyl chloroborane Suppliers

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View Lastest Price from (+)-Diisopinocampheyl chloroborane manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
(+)-Diisopinocampheyl chloroborane 112246-73-8
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-26
Zhuozhou Wenxi import and Export Co., Ltd
Product
(+)-Diisopinocampheyl chloroborane 112246-73-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
(+)-DIP-Chloride(TM) 90-105% (approx.) 112246-73-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

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  • 112246-73-8
  • C20H34BC
  • C20H34BCl
  • Boranes
  • Reduction
  • B (Classes of Boron Compounds)
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • B (Classes of Boron Compounds)
  • Boranes