ChemicalBook > CAS DataBase List > 2-BROMO-4-CHLORO-6-NITROPHENYLAMINE

2-BROMO-4-CHLORO-6-NITROPHENYLAMINE

Product Name
2-BROMO-4-CHLORO-6-NITROPHENYLAMINE
CAS No.
827-25-8
Chemical Name
2-BROMO-4-CHLORO-6-NITROPHENYLAMINE
Synonyms
2-BROMO-4-CHLORO-6-NITROANILINE;2-Bromo-4-chloro-6-nitrobenzenamine;2-BROMO-4-CHLORO-6-NITROPHENYLAMINE;2-Amino-3-bromo-5-chloronitrobenzene;2-Bromo-4-chloro-6-nitroaniline, 97%;Benzenamine, 2-bromo-4-chloro-6-nitro-;2-BROMO-4-CHLORO-6-NITROPHENYLAMINE ISO 9001：2015 REACH
CBNumber
CB0424570
Molecular Formula
C6H4BrClN2O2
Formula Weight
251.47
MOL File
827-25-8.mol
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2-BROMO-4-CHLORO-6-NITROPHENYLAMINE Property

Melting point:
106 °C
Boiling point:
329.3±37.0 °C(Predicted)
Density 
1.909±0.06 g/cm3(Predicted)
storage temp. 
2-8°C(protect from light)
pka
-3.20±0.25(Predicted)
Appearance
White to yellow Solid
CAS DataBase Reference
827-25-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
HS Code 
2921420090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B678828
Product name
2-Bromo-4-chloro-6-nitrophenylamine
Packaging
500mg
Price
$60
Updated
2021/12/16
Oakwood
Product number
062563
Product name
2-Bromo-4-chloro-6-nitroaniline
Purity
98%
Packaging
1g
Price
$10
Updated
2021/12/16
Matrix Scientific
Product number
071988
Product name
2-Bromo-4-chloro-6-nitrophenylamine
Purity
95+%
Packaging
5g
Price
$13
Updated
2021/12/16
AK Scientific
Product number
J51164
Product name
2-Bromo-4-chloro-6-nitrophenylamine
Packaging
5g
Price
$14
Updated
2021/12/16
Apolloscientific
Product number
OR7021
Product name
2-Bromo-4-chloro-6-nitroaniline
Packaging
5g
Price
$15
Updated
2021/12/16
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2-BROMO-4-CHLORO-6-NITROPHENYLAMINE Chemical Properties,Usage,Production

Synthesis Reference(s)

Tetrahedron Letters, 35, p. 7055, 1994 DOI: 10.1016/0040-4039(94)88224-X

Synthesis

89-63-4

827-25-8

General procedure for the synthesis of 2-nitro-4-chloro-6-bromoaniline from 4-chloro-2-nitroaniline: 4-chloro-2-nitroaniline (5.1 g, 30 mmol) and N-bromosuccinimide (6.2 g, 36 mmol) were dissolved in acetonitrile (50 mL) and the reaction was heated to reflux overnight. After completion of the reaction, the mixture was cooled to room temperature and diluted with ethyl acetate (50 mL). Subsequently, the mixture was washed with saturated aqueous potassium carbonate (100 mL x 2). The organic phase was separated, dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to afford the target compound 2-nitro-4-chloro-6-bromoaniline (109a) as a yellow solid (8.1 g, 100% yield).LCMS analysis showed [M + H]+ of 253.1 H NMR (500 MHz, CDCl3) δ 8.17 (d, J = 2.5 Hz, 1H), 1 H 7.71 (d, J = 2.5 Hz, 1H), 6.64 (s, 2H).

References

[1] Patent: US2013/116262, 2013, A1. Location in patent: Paragraph 0260
[2] Patent: WO2018/13776, 2018, A1. Location in patent: Page/Page column 108
[3] Patent: WO2018/13770, 2018, A1. Location in patent: Page/Page column 80
[4] Patent: WO2018/13774, 2018, A1. Location in patent: Page/Page column 155
[5] Tetrahedron Letters, 1994, vol. 35, # 38, p. 7055 - 7056

2-BROMO-4-CHLORO-6-NITROPHENYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-BROMO-4-CHLORO-6-NITROPHENYLAMINE Suppliers

China 111 Germany 1 India 4 Switzerland 1 United Kingdom 8 United States 12 Global 137
A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
SL Drugs and Pharmaceuticals Pvt. Ltd.
Tel
--
Fax
--
Email
enquiry@sldrugs.com
Country
India
ProdList
2683
Advantage
50
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View Lastest Price from 2-BROMO-4-CHLORO-6-NITROPHENYLAMINE manufacturers

Henan Fengda Chemical Co., Ltd
Product
2-BROMO-4-CHLORO-6-NITROPHENYLAMINE 827-25-8
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-26
Honest Joy Holdings Limited
Product
2-Bromo-4-chloro-6-nitrophenylamine 827-25-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99.5%
Supply Ability
100 tons
Release date
2022-02-20
Zhuozhou Wenxi import and Export Co., Ltd
Product
2-BROMO-4-CHLORO-6-NITROPHENYLAMINE 827-25-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

827-25-8, 2-BROMO-4-CHLORO-6-NITROPHENYLAMINERelated Search:

Tosyl chloride Aniline 4-bromo-5-chloro-2-nitrophenylamine 3-Bromo-1,2-diaminobenzene 2-BROMO-4-CHLORO-6-NITROPHENYLAMINE 1-BROMO-3-CHLORO-5-NITROBENZENE 2-BROMO-6-NITROANILINE 3-BROMO-5-CHLOROPHENYLAMINE

  • 2-BROMO-4-CHLORO-6-NITROANILINE
  • 2-BROMO-4-CHLORO-6-NITROPHENYLAMINE
  • 2-Bromo-4-chloro-6-nitrobenzenamine
  • 2-Amino-3-bromo-5-chloronitrobenzene
  • Benzenamine, 2-bromo-4-chloro-6-nitro-
  • 2-BROMO-4-CHLORO-6-NITROPHENYLAMINE ISO 9001：2015 REACH
  • 2-Bromo-4-chloro-6-nitroaniline, 97%
  • 827-25-8
  • 927-25-8
  • C6H4BrClN2O2
  • C6H4N2O2BrCl
  • Alkylanilines
  • Anilines, Amides & Amines
  • Bromine Compounds
  • Chlorine Compounds
  • Nitro Compounds