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1-Methylpyrrolidine

Product Name
1-Methylpyrrolidine
CAS No.
120-94-5
Chemical Name
1-Methylpyrrolidine
Synonyms
N-METHYLPYRROLIDINE;1-methyl;Methylpyrrolidine;NSC 65579;1-Methylpyrrodine;Cefepime Impurity 1;1-METHYLPYRROLIDINE;cefepiMe iMpurity G;1-methyl-pyrrolidin;Pyrrolidine, N-methyl
CBNumber
CB0672357
Molecular Formula
C5H11N
Formula Weight
85.15
MOL File
120-94-5.mol
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1-Methylpyrrolidine Property

Melting point:
-90 °C
Boiling point:
76-80 °C (lit.)
Density 
0.800 g/mL at 20 °C (lit.)
vapor pressure 
100 hPa (20 °C)
refractive index 
n20/D 1.425
Flash point:
−7 °F
storage temp. 
Store below +30°C.
solubility 
213g/l
form 
Liquid
pka
10.32(at 25℃)
color 
Clear colorless
PH
11.3 (1g/l, H2O)
explosive limit
1.1-9.1%(V)
Water Solubility 
fully miscible
BRN 
102445
InChIKey
AVFZOVWCLRSYKC-UHFFFAOYSA-N
LogP
1.1 at 23℃
CAS DataBase Reference
120-94-5(CAS DataBase Reference)
NIST Chemistry Reference
Pyrrolidine, 1-methyl-(120-94-5)
EPA Substance Registry System
N-Methylpyrrolidine (120-94-5)
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Safety

Hazard Codes 
F,C,N
Risk Statements 
11-22-34-51/53-35-20/22
Safety Statements 
16-26-36/37/39-45-61-29
RIDADR 
UN 2924 3/PG 2
WGK Germany 
2
RTECS 
UY1420500
Autoignition Temperature
170 °C DIN 51794
TSCA 
Yes
HS Code 
2933 99 80
HazardClass 
3
PackingGroup 
II
Toxicity
LD50 orally in Rabbit: 280 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H301Toxic if swalloed

H314Causes severe skin burns and eye damage

H332Harmful if inhaled

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.16146
Product name
1-Methylpyrrolidine
Purity
for synthesis
Packaging
10ml
Price
$42.9
Updated
2024/03/01
Sigma-Aldrich
Product number
8.16146
Product name
1-Methylpyrrolidine
Purity
for synthesis
Packaging
100mL
Price
$53.6
Updated
2024/03/01
Sigma-Aldrich
Product number
69110
Product name
1-Methylpyrrolidine
Purity
≥98.0% (GC)
Packaging
100ml
Price
$70.8
Updated
2024/03/01
Sigma-Aldrich
Product number
69110
Product name
1-Methylpyrrolidine
Purity
≥98.0% (GC)
Packaging
500ml
Price
$149
Updated
2024/03/01
TCI Chemical
Product number
M0415
Product name
1-Methylpyrrolidine
Purity
>98.0%(GC)(T)
Packaging
25mL
Price
$29
Updated
2024/03/01
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1-Methylpyrrolidine Chemical Properties,Usage,Production

Chemical Properties

colorless transparent volatile liquid. Freely soluble in water, soluble in alcohol, ether and other organic solvents.

Uses

1-Methylpyrrolidine is a methylated pyrollidine and is involved as an essential part of the structure of cefipime. It is also an active component of cigarette smoke.

Preparation

n-methylpyrrolidine was successfully synthesized in an aqueous medium by using methylamine and 1,4-dibromobutane in the presence of catalyst k2co3 at a moderated temperature. here, n-methylpyrrolidine was firstly synthesized via the green chemistry process, in which both the water solvent and potassium carbonate catalyst were inexpensive and environmentally friendly. also, the reaction temperature was quite moderated at 90°C.
green organic synthesis of n-methylpyrrolidine

Hazard

Flammable, dangerous fire risk. Irritant toskin and eyes.

Flammability and Explosibility

Highly flammable

Safety Profile

Poison by intraperitoneal and intravenous routes. This material is strongly alkaline. Liquid and vapors are corrosive to the skin, eyes, or mucous membranes. A very dangerous fire hazard; keep away from sparks, heat sources, and powerful oxidizers. Keep in closed containers. To fight fire, use alcohol foam. When heated to decomposition it emits highly toxic fumes of NOx.

Synthesis

1-Methylpyrrolidine is prepared by hydrogenation of N-Methylpyrrole over Adams' catalyst.

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1-Methylpyrrolidine Suppliers

Shanghai Ze Chong Pharmaceutical Technology Co., Ltd.
Tel
021-67308028 18621330623
Email
sales@zechongchem.com
Country
China
ProdList
60
Advantage
58
Hangzhou Benoy Chemical Co., Ltd.
Tel
17342059697
Fax
QQ:2710089141
Email
sales@benoychem.com
Country
China
ProdList
389
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58
Beijing Solarbio Science & Tecnology Co., Ltd.
Tel
010-50973130 17801761073
Email
Gsiyu@solarbio.com
Country
China
ProdList
50464
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58
NEM Materials Co.,Ltd.
Tel
393-393-+86-393-6101536 +86-13525283508
Fax
0393-6667671
Email
liujunying627@163.com
Country
China
ProdList
5
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J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
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69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820 13031183356
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1390
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Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
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View Lastest Price from 1-Methylpyrrolidine manufacturers

Hebei Chuanghai Biotechnology Co,.LTD
Product
1-Methylpyrrolidine 120-94-5
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-20
Hebei Weibang Biotechnology Co., Ltd
Product
1-Methylpyrrolidine 120-94-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2021-08-20
Guangzhou PI PI BIOTECH INC
Product
Cefepime Impurity 1
Price
US $0.00-0.00/mg
Min. Order
10mg
Purity
90%+
Supply Ability
10g
Release date
2022-04-25

120-94-5, 1-MethylpyrrolidineRelated Search:


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