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METHYL ISOCYANOACETATE

Product Name
METHYL ISOCYANOACETATE
CAS No.
39687-95-1
Chemical Name
METHYL ISOCYANOACETATE
Synonyms
Methyl 2-isocyanoacetate;ISOCYANOACETIC ACID METHYL ESTER;ROXA-015;METHYL ISOCYANOACETATE;Methyl isocyanoformate;Methyl Isocyanoacetate >Methyl Isocyanoacetate,>97%;2-Oxo-2-methoxyethyl isocyanide;(2-Oxo-2-methoxyethyl) isocyanide;39687-95-1 METHYL ISOCYANOACETATE
CBNumber
CB0700977
Molecular Formula
C4H5NO2
Formula Weight
99.09
MOL File
39687-95-1.mol
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METHYL ISOCYANOACETATE Property

Boiling point:
75-76 °C10 mm Hg(lit.)
Density 
1.09 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.417(lit.)
Flash point:
193 °F
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form 
Liquid
color 
Clear yellow to brown
Water Solubility 
Miscible with organic solvents. Slightly miscible with water.
BRN 
3537963
CAS DataBase Reference
39687-95-1(CAS DataBase Reference)
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Safety

Hazard Codes 
C
Risk Statements 
20/21/22-34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 2922 8/PG 2
WGK Germany 
3
8-9-32-13-19
HazardClass 
8
PackingGroup 
II
HS Code 
29291090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
238880
Product name
Methyl isocyanoacetate
Purity
technical grade, 95%
Packaging
1g
Price
$63.7
Updated
2024/03/01
Sigma-Aldrich
Product number
238880
Product name
Methyl isocyanoacetate
Purity
technical grade, 95%
Packaging
5g
Price
$177
Updated
2024/03/01
TCI Chemical
Product number
M2549
Product name
Methyl Isocyanoacetate
Purity
>97.0%(GC)
Packaging
1g
Price
$35
Updated
2024/03/01
TCI Chemical
Product number
M2549
Product name
Methyl Isocyanoacetate
Purity
>97.0%(GC)
Packaging
5g
Price
$119
Updated
2024/03/01
Alfa Aesar
Product number
H31069
Product name
Methyl isocyanoacetate, 95%
Packaging
1g
Price
$38.1
Updated
2024/03/01
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METHYL ISOCYANOACETATE Chemical Properties,Usage,Production

Chemical Properties

CLEAR YELLOW TO BROWN LIQUID

Uses

Methyl isocyanoacetate is used in the copper-catalyzed, diastereoselective synthesis of oxazolines. It is involved in the direct aldol reaction with carbonyl compounds to prepare corresponding oxazoline by using catechol-copper network catalyst. Further, it is also involved in four-component Ugi condensation reaction. It undergoes asymmetric aldol reaction with fluorinated benzaldehyde using gold(I) as a catalyst.

Uses

Methyl isocyanoacetate has been used in the copper-catalyzed, diastereoselective synthesis of oxazolines.

General Description

Methyl isocyanoacetate undergoes direct aldol reaction with carbonyl compounds in the presence of solid-phase catechol-copper network catalyst to yield corresponding oxazolines. It also participates in four-component Ugi condensation reaction.

METHYL ISOCYANOACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL ISOCYANOACETATE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
PharmaBlock Sciences (Nanjing),Inc.
Tel
025-86918202 4000255188
Fax
86-025-86918232
Email
sales@pharmablock.com
Country
China
ProdList
4986
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55
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11655
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
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View Lastest Price from METHYL ISOCYANOACETATE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
METHYL ISOCYANOACETATE 39687-95-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

39687-95-1, METHYL ISOCYANOACETATERelated Search:


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