Hydroxyacetone

ChemicalBook > CAS DataBase List > Hydroxyacetone

Product Name: Hydroxyacetone
CAS No.: 116-09-6
Chemical Name: Hydroxyacetone
Synonyms: 2-Propanone, 1-hydroxy-;1-hydroxypropan-2-one;ACETOL;1-HYDROXY-2-PROPANONE;1-Hydroxyacetone;1-hydroxy-propan-2-one;2-oxopropanol;Acetomethanol;Hydroxyaceton;Hydroxypropanone
CBNumber: CB0714802
Molecular Formula: C3H6O2
Formula Weight: 74.08
MOL File: 116-09-6.mol

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Hydroxyacetone Property

Melting point:: -17 °C (lit.)
Boiling point:: 145-146 °C (lit.)
Density: 1.082 g/mL at 25 °C (lit.)
vapor pressure: 9.01hPa at 25℃
refractive index: n20/D 1.425(lit.)
FEMA: 4462 | HYDROXYACETONE
Flash point:: 133 °F
storage temp.: 2-8°C
solubility: water: miscible
form: clear liquid
pka: 13.14±0.10(Predicted)
color: Colorless liquid
Specific Gravity: 1.090 (20/4℃)
Odor: at 10.00 % in dipropylene glycol. pungent sweet caramellic ethereal
Odor Type: caramellic
Water Solubility: Miscible with water, alcohol and ether.
Sensitive: Hygroscopic
Merck: 14,65
JECFA Number: 1945
BRN: 605368
Stability:: Stable. Flammable. Incompatible with strong oxidizing agents, strong acids. Protect from moisture - hygroscopic.
InChIKey: XLSMFKSTNGKWQX-UHFFFAOYSA-N
LogP: 0.3 at 25℃
CAS DataBase Reference: 116-09-6(CAS DataBase Reference)
NIST Chemistry Reference: 2-Propanone, 1-hydroxy-(116-09-6)
EPA Substance Registry System: 1-Hydroxyacetone (116-09-6)

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Safety

Risk Statements: 2017/10/16
Safety Statements: 23-24/25-5
RIDADR: UN 1224 3/PG 3
WGK Germany: 1
RTECS: UC2800000
TSCA: Yes
HazardClass: 3
PackingGroup: III
HS Code: 29144090
Toxicity: mmo-sat 500 mg/plate ABCHA6 47,2461,83

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 138185
Product name: Hydroxyacetone
Purity: contains ≤500ppm sodium carbonate as stabilizer, technical grade, 90%
Packaging: 5g
Price: $41
Updated: 2024/03/01

Sigma-Aldrich

Product number: 138185
Product name: Hydroxyacetone
Purity: contains ≤500ppm sodium carbonate as stabilizer, technical grade, 90%
Packaging: 100g
Price: $44.3
Updated: 2024/03/01

TCI Chemical

Product number: H0388
Product name: Hydroxyacetone
Purity: >80.0%(GC)
Packaging: 25mL
Price: $34
Updated: 2024/03/01

TCI Chemical

Product number: H0388
Product name: Hydroxyacetone
Purity: >80.0%(GC)
Packaging: 100mL
Price: $58
Updated: 2024/03/01

Alfa Aesar

Product number: L15008
Product name: Hydroxyacetone, 95%
Packaging: 100g
Price: $43.7
Updated: 2024/03/01

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Hydroxyacetone Chemical Properties,Usage,Production

Chemical Properties

colourless to yellow liquid

Uses

Hydroxyacetone is a chemical reagent used in various organic chemical reactions. It is a component of the Mannich reaction, amino acid caalyzes direct asymmetric aldol reactions. In the pharmaceutical setting, this compound is used in the synthesis of imidazoles acting as potent and orally active antihypertensive agents. It is also used in the syntheses of 2-oxo-propionaldehyde, imidazoles, polyols, acrolein, dyes and skin tanning agents. It yields (R)-1,2-propanediol upon reduction of hydroxyacetone in the presence of a microbial cell catalyst.

Definition

ChEBI: A propanone that is acetone in which one of the methyl hydrogens is replaced by a hydroxy group.

General Description

Hydroxyacetone (Acetol) is important for the manufacture of polyols, acrolein, dyes and skin tanning agents. It undergoes asymmetric reduction to yield (R)-1,2-propanediol in the presence of microbial cell catalyst.

Safety Profile

Moderately toxic by ingestion. Mutation data reported. An allergen. Implicated in aplastic anemia. A 10 gram dose may be fatal to an adult. skin contact, inhalation, or ingestion can cause asthma, sneezing, irritation of eyes and nose, hives, and eczema. Combustible when exposed to heat or flame. When heated to decomposition it emits acrid smoke and fumes.

Synthesis

Hydroxyacetone is produced from Bromoacetone plus sodium formate, followed by Methanol hydrolysis of the formed ester. Or by biochemical synthesis from Propylene glycol with sorbose bacterium.

Hydroxyacetone Preparation Products And Raw materials

Raw materials

Methanol solution Potassium bromide BROMOACETONE Potassium formate Methanol

Preparation Products

Solvent Yellow 114 2-methylquinolin-3-ol

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View Lastest Price from Hydroxyacetone manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: Hydroxyacetone 116-09-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-12-10

Hebei Chuanghai Biotechnology Co,.LTD

Product: Hydroxyacetone 116-09-6
Price: US $10.70/kg
Min. Order: 10kg
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-16

JINING XINHE CHEMICAL CO., LTD

Product: Hydroxyacetone 116-09-6
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 10ton
Release date: 2024-07-16

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116-09-6

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