Dibutyl sulfide
Description References- Product Name
- Dibutyl sulfide
- CAS No.
- 544-40-1
- Chemical Name
- Dibutyl sulfide
- Synonyms
- FEMA 2215;(n-C4H9)2S;'LGC' (4000);5-Thianonane;Thianonane-5;Thiononane-5;BUTYL SULFIDE;Dibutylsulfid;BUTYL SULPHIDE;dibutylsulfane
- CBNumber
- CB0738088
- Molecular Formula
- C8H18S
- Formula Weight
- 146.29
- MOL File
- 544-40-1.mol
Dibutyl sulfide Property
- Melting point:
- -76 °C (lit.)
- Boiling point:
- 188-189 °C (lit.)
- Density
- 0.838 g/mL at 25 °C (lit.)
- vapor density
- 5.07 (vs air)
- vapor pressure
- 5.17 mm Hg ( 37.7 °C)
- refractive index
- n20/D 1.452(lit.)
- FEMA
- 2215 | BUTYL SULFIDE
- Flash point:
- 170 °F
- storage temp.
- Store below +30°C.
- form
- Liquid
- color
- Clear colorless to very slightly yellow
- Odor
- at 0.10 % in dipropylene glycol. green grassy violet-leaf herbal rose geranium
- Odor Type
- alliaceous
- Odor Threshold
- 0.00051ppm
- Water Solubility
- Silghtly miscible with water. Miscible with olive oil and almond oil.
- JECFA Number
- 455
- Merck
- 14,1590
- BRN
- 1732829
- Dielectric constant
- 4.4100000000000001
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- InChIKey
- HTIRHQRTDBPHNZ-UHFFFAOYSA-N
- LogP
- 3.87
- CAS DataBase Reference
- 544-40-1(CAS DataBase Reference)
- NIST Chemistry Reference
- Di-n-butyl sulfide(544-40-1)
- EPA Substance Registry System
- Dibutyl sulfide (544-40-1)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38-41
- Safety Statements
- 26-36/37/39-24/25-36
- RIDADR
- 2810
- WGK Germany
- 2
- RTECS
- ER6417000
- F
- 13
- TSCA
- Yes
- HazardClass
- 6.1(b)
- PackingGroup
- III
- HS Code
- 29309070
- Toxicity
- LD50 orally in Rabbit: 2220 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H227Combustible liquid
H303May be harmfulif swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- W221503
- Product name
- Butyl sulfide
- Purity
- ≥95%, FG
- Packaging
- 1kg
- Price
- $199
- Updated
- 2024/03/01
- Product number
- W221503
- Product name
- Butyl sulfide
- Purity
- ≥95%, FG
- Packaging
- 4kg
- Price
- $472
- Updated
- 2024/03/01
- Product number
- W221503
- Product name
- Butyl sulfide
- Purity
- ≥95%, FG
- Packaging
- 8kg
- Price
- $936
- Updated
- 2024/03/01
- Product number
- NIST2720
- Product name
- Sulfur in di-n-butyl sulfide
- Purity
- NIST?SRM?2720
- Packaging
- 5x4.5mL
- Price
- $1100
- Updated
- 2024/03/01
- Product number
- 8.20252
- Product name
- Dibutyl sulfide
- Purity
- for synthesis
- Packaging
- 50mL
- Price
- $69.1
- Updated
- 2024/03/01
Dibutyl sulfide Chemical Properties,Usage,Production
Description
Dibutyl sulfide (also named as butyl sulfide; N-butyl sulfide; Di-n-butyl sulfide; butylthiobutane), a colorless to pale yellow clear liquid, is a symmetric thioether. Dibutyl sulfide is found in raw cabbage, boiled and cooked beef, and some varieties of mushroom.
Dibutyl sulfide is typically used as a flavoring agent. As a thioether, dibutyl sulfide has applications in organic synthesis as a solvent as well as a reagent. It is used to synthesize specific compound classes including property-enhancing additives, pharmacological drugs, chemical resistant polymers, detergents, and rubber antioxidants. Dibutyl sulfide can also be used as an agricultural intermediate, a sulfiding agent, a refinery catalyst, a lubricant additive, a gas odorant, and a processing aid in mining applications. Furthermore, it can be used as an internal standard in X-ray fluorescence spectrometry (XRF) measurements of sulfur in oils and other liquid hydrocarbon matrices.
References
[1] George A. Burdock (1996) Encyclopedia of Food and Color Additives, Band 1
[2] http://chemicalland21.com/specialtychem/NH/DIBUTYL%20SULFIDE.htm
Chemical Properties
colourless liquid with a very unpleasant smell
Chemical Properties
Butyl sulfide has an herbaceous, green, garlic, onion, heavy odor.
Occurrence
Reported found in raw cabbage, cooked beef and mushrooms.
Uses
Di-n-butyl sulfide is generally used as an agricultural intermediate, a sulfiding agent, a refinery catalyst, a lubricant additive, a gas odorant and a processing aid in mining applications. It finds application as an internal standard in X-ray fluorescence spectrometry (XRF) measurements of sulfur in oils and other liquid hydrocarbon matrices.
Preparation
From butyl bromide and sodium sulfide in boiling ethanol; according to some authors two forms exist, exhibiting different boiling points but identical solubilities in various solvents; both forms are insoluble in water.
Definition
ChEBI: Dibutyl sulfide is an aliphatic sulfide.
Aroma threshold values
Recognition: 0.88 ppb
Synthesis Reference(s)
Journal of the American Chemical Society, 73, p. 2251, 1951 DOI: 10.1021/ja01149a096
Tetrahedron Letters, 29, p. 4477, 1988 DOI: 10.1016/S0040-4039(00)80527-4
General Description
Butyl sulfide is a volatile sulfur compound that can be used as a flavoring agent.
Biochem/physiol Actions
Taste at 5 ppm
Purification Methods
Wash the sulfide with aqueous 5% NaOH, then water. Dry with CaCl2 and distil it from sodium. [Beilstein 1 IV 1559.]
Dibutyl sulfide Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Dibutyl sulfide manufacturers
- Product
- Butyl sulfide 544-40-1
- Price
- US $550.00/Kg
- Min. Order
- 1Kg
- Purity
- 97
- Supply Ability
- 500 Kg
- Release date
- 2024-04-10
- Product
- Dibutyl sulfide 544-40-1
- Price
- US $8.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-09
- Product
- Dibutyl sulfide 544-40-1
- Price
- US $20.00-1.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 10 tons
- Release date
- 2023-10-26