CHLOROMETHYL METHYL SULFIDE

Product Name: CHLOROMETHYL METHYL SULFIDE
CAS No.: 2373-51-5
Chemical Name: CHLOROMETHYL METHYL SULFIDE
Synonyms: (chloroMethyl)(Methyl)sulfane;CH3SCH2Cl;Chloro(methylsulfanyl)methane;Methylthiomethyl chloride;MTMchloride;Clorodimetilsolfuro;CHLORODIMETHYL SULFIDE;chlorodimethylthioether;Chlorodimethyl thioether;methylthiomethylchloride
CBNumber: CB9295856
Molecular Formula: C2H5ClS
Formula Weight: 96.58
MOL File: 2373-51-5.mol

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CHLOROMETHYL METHYL SULFIDE Property

Boiling point:: 105 °C (lit.)
Density: 1.153 g/mL at 25 °C (lit.)
refractive index: n20/D 1.498(lit.)
Flash point:: 63 °F
storage temp.: 2-8°C
form: clear liquid
color: Colorless to Light orange to Yellow
Water Solubility: Soluble in acetonitrile, ether and dichloromethane. Insoluble in water.
Sensitive: Moisture Sensitive
BRN: 1730851
CAS DataBase Reference: 2373-51-5(CAS DataBase Reference)

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Safety

Hazard Codes: F,Xi
Risk Statements: 11-37
Safety Statements: 9-16-33
RIDADR: UN 1993 3/PG 2
WGK Germany: 3
RTECS: WQ3700000
F: 13
HazardClass: 3
PackingGroup: II
HS Code: 2930909899

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: C54007
Product name: Chloromethyl methyl sulfide
Purity: 95%
Packaging: 5g
Price: $80
Updated: 2024/03/01

Sigma-Aldrich

Product number: C54007
Product name: Chloromethyl methyl sulfide
Purity: 95%
Packaging: 25g
Price: $191
Updated: 2024/03/01

TCI Chemical

Product number: C0608
Product name: Chloromethyl Methyl Sulfide
Purity: >97.0%(GC)
Packaging: 25g
Price: $127
Updated: 2024/03/01

TCI Chemical

Product number: C0608
Product name: Chloromethyl Methyl Sulfide
Purity: >97.0%(GC)
Packaging: 100g
Price: $353
Updated: 2024/03/01

Alfa Aesar

Product number: L10858
Product name: Chloromethyl methyl sulfide, 95%
Packaging: 10g
Price: $55.65
Updated: 2024/03/01

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CHLOROMETHYL METHYL SULFIDE Chemical Properties,Usage,Production

Chemical Properties

CLEAR YELLOW TO BROWN LIQUID

Uses

Chloromethyl methyl sulfide is used as a methylene transfer reagent for iron(II) mediated cyclopropanation and for carbonyl and aromatic compounds. It protects alcohols as their methylthiomethyl (MTM) ethers by reaction, e.g. with NaH/NaI in DME. It is also used for the preparation of MTM esters of carboxylic acids, e.g. by treatment of the K salt of the acid in the presence of NaI and 18-crown-6 and for reaction with cyclopentadienyl iron dicarbonyl dimer in the formation of an iron-containing methylene transfer agent.

Uses

Methylthiomethylating reagent for carbonyl and aromatic compounds. Methylene transfer reagent for iron(II) mediated cyclopropanation.

Synthesis Reference(s)

Tetrahedron Letters, 35, p. 6127, 1994 DOI: 10.1016/0040-4039(94)88094-8

CHLOROMETHYL METHYL SULFIDE Preparation Products And Raw materials

Raw materials

Pentane Dimethyl sulfide

Preparation Products

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CHLOROMETHYL METHYL SULFIDE Suppliers

Americas 1 Canada 1 China 75 Europe 1 Germany 3 India 8 Japan 4 Switzerland 1 United Kingdom 6 United States 18 Global 118

Shanghai chuqing Organosilane technology ltd

Tel: 021-61530618
Fax: 86-21-51714575
Email: sales@chuqingtech.com
Country: China
ProdList: 274
Advantage: 55

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94657
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 8415
Advantage: 55

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9414
Advantage: 66

Shanghai Longsheng chemical Co.,Ltd.

Tel: 021-58099652-8005 13585536065
Fax: 021-58099609
Email: bin.wu@shlschem.com
Country: China
ProdList: 9809
Advantage: 59

Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
Country: China
ProdList: 19173
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42958
Advantage: 64

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View Lastest Price from CHLOROMETHYL METHYL SULFIDE manufacturers

Hebei Chuanghai Biotechnology Co,.LTD

Product: Chloromethyl Methyl Sulfide 2373-51-5
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-20

Career Henan Chemical Co

Product: Chloromethyl Methyl Sulfide 2373-51-5
Price: US $3.00/KG
Min. Order: 1KG
Purity: 99
Supply Ability: 100kg
Release date: 2019-07-10

2373-51-5, CHLOROMETHYL METHYL SULFIDERelated Search:

Stannous chloride dihydrate CHLOROMETHYL PHENYL SULFIDE CHLOROMETHYL METHYL SULFIDE CHLOROMETHYL PHENYL SULFONE bis(trichloromethyl) sulphone PHENYL CHLOROTHIOFORMATE CHLOROMETHYL 4-CHLOROPHENYL SULFIDE CHLOROMETHYL PHENYL SULFOXIDE Ethyl chlorothioformate CHLOROMETHYL THIOCYANATE 2-chloromethyl methyl sulfide CHLOROMETHYL TRIFLUOROMETHYL SULFIDE P-TOLUENESULFONYLMETHYL CHLORIDE N-PROPYL CHLOROTHIOFORMATE 1-chloro-4-[(chloromethyl)sulphonyl]benzene BIS(CHLOROMETHYL) SULFIDE PHENYL CHLORODITHIOFORMATE P-CHLOROPHENYL TRICHLOROMETHYL SULFIDE

alpha-Chlorodimethyl sulfide

alpha-chlorodimethylsulfide

CH3SCH2Cl

Chloro(methylsulfanyl)methane

chloro(methylthio)-methan

chloro(methylthio)methane

Chlorodimethyl thioether

chlorodimethylthioether

Chloromethyl methyl thioether

chloromethylmethylthioether

Clorodimetilsolfuro

Methane, chloro(methylthio)-

Methylthiomethyl chloride

methylthiomethylchloride

Monochlorodimethyl sulfide

monochlorodimethylsulfide

Sulfide, chloromethyl methyl

sulfide,chloromethylmethyl

CHLORODIMETHYL SULFIDE

CHLOROMETHYL METHYL SULFIDE

CHLOROMETHYL METHYL SULPHIDE

Chlorodimethyl sulphide~Methyl chloromethyl sulphide~Methylthiomethyl chloride~MTM chloride

CHLOROMETHYL METHYL SULFIDE, ~80-85%

Methylchloromethylsulfide

MTMchloride

(Methylthio)chloromethane

Chloromethyl methyl sulfide,95%

Chloro(methylsulphanyl)methane

(chloroMethyl)(Methyl)sulfane

ChloroMethyl Methyl sulfide 95%

Chloro(methylsulphanyl)methane, Chloro(methylthio)methane

Chloromethyl Methyl Sulfide &gt

2373-51-5

2375-51-5

Synthetic Reagents

Others

Protection and Derivatization

Protecting and Derivatizing Reagents