ChemicalBook > CAS DataBase List > CHLOROMETHYL METHYL SULFIDE

CHLOROMETHYL METHYL SULFIDE

Product Name
CHLOROMETHYL METHYL SULFIDE
CAS No.
2373-51-5
Chemical Name
CHLOROMETHYL METHYL SULFIDE
Synonyms
(chloroMethyl)(Methyl)sulfane;CH3SCH2Cl;Chloro(methylsulfanyl)methane;Methylthiomethyl chloride;MTMchloride;Clorodimetilsolfuro;CHLORODIMETHYL SULFIDE;chlorodimethylthioether;Chlorodimethyl thioether;methylthiomethylchloride
CBNumber
CB9295856
Molecular Formula
C2H5ClS
Formula Weight
96.58
MOL File
2373-51-5.mol
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CHLOROMETHYL METHYL SULFIDE Property

Boiling point:
105 °C (lit.)
Density 
1.153 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.498(lit.)
Flash point:
63 °F
storage temp. 
2-8°C
form 
clear liquid
color 
Colorless to Light orange to Yellow
Water Solubility 
Soluble in acetonitrile, ether and dichloromethane. Insoluble in water.
Sensitive 
Moisture Sensitive
BRN 
1730851
CAS DataBase Reference
2373-51-5(CAS DataBase Reference)
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Safety

Hazard Codes 
F,Xi
Risk Statements 
11-37
Safety Statements 
9-16-33
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
RTECS 
WQ3700000
13
HazardClass 
3
PackingGroup 
II
HS Code 
2930909899
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
C54007
Product name
Chloromethyl methyl sulfide
Purity
95%
Packaging
5g
Price
$80
Updated
2024/03/01
Sigma-Aldrich
Product number
C54007
Product name
Chloromethyl methyl sulfide
Purity
95%
Packaging
25g
Price
$191
Updated
2024/03/01
TCI Chemical
Product number
C0608
Product name
Chloromethyl Methyl Sulfide
Purity
>97.0%(GC)
Packaging
25g
Price
$127
Updated
2024/03/01
TCI Chemical
Product number
C0608
Product name
Chloromethyl Methyl Sulfide
Purity
>97.0%(GC)
Packaging
100g
Price
$353
Updated
2024/03/01
Alfa Aesar
Product number
L10858
Product name
Chloromethyl methyl sulfide, 95%
Packaging
10g
Price
$55.65
Updated
2024/03/01
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CHLOROMETHYL METHYL SULFIDE Chemical Properties,Usage,Production

Chemical Properties

CLEAR YELLOW TO BROWN LIQUID

Uses

Chloromethyl methyl sulfide is used as a methylene transfer reagent for iron(II) mediated cyclopropanation and for carbonyl and aromatic compounds. It protects alcohols as their methylthiomethyl (MTM) ethers by reaction, e.g. with NaH/NaI in DME. It is also used for the preparation of MTM esters of carboxylic acids, e.g. by treatment of the K salt of the acid in the presence of NaI and 18-crown-6 and for reaction with cyclopentadienyl iron dicarbonyl dimer in the formation of an iron-containing methylene transfer agent.

Uses

Methylthiomethylating reagent for carbonyl and aromatic compounds. Methylene transfer reagent for iron(II) mediated cyclopropanation.

Synthesis Reference(s)

Tetrahedron Letters, 35, p. 6127, 1994 DOI: 10.1016/0040-4039(94)88094-8

CHLOROMETHYL METHYL SULFIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from CHLOROMETHYL METHYL SULFIDE manufacturers

Hebei Chuanghai Biotechnology Co,.LTD
Product
Chloromethyl Methyl Sulfide 2373-51-5
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-20
Career Henan Chemical Co
Product
Chloromethyl Methyl Sulfide 2373-51-5
Price
US $3.00/KG
Min. Order
1KG
Purity
99
Supply Ability
100kg
Release date
2019-07-10

2373-51-5, CHLOROMETHYL METHYL SULFIDERelated Search:


  • alpha-Chlorodimethyl sulfide
  • alpha-chlorodimethylsulfide
  • CH3SCH2Cl
  • Chloro(methylsulfanyl)methane
  • chloro(methylthio)-methan
  • chloro(methylthio)methane
  • Chlorodimethyl thioether
  • chlorodimethylthioether
  • Chloromethyl methyl thioether
  • chloromethylmethylthioether
  • Clorodimetilsolfuro
  • Methane, chloro(methylthio)-
  • Methylthiomethyl chloride
  • methylthiomethylchloride
  • Monochlorodimethyl sulfide
  • monochlorodimethylsulfide
  • Sulfide, chloromethyl methyl
  • sulfide,chloromethylmethyl
  • CHLORODIMETHYL SULFIDE
  • CHLOROMETHYL METHYL SULFIDE
  • CHLOROMETHYL METHYL SULPHIDE
  • Chlorodimethyl sulphide~Methyl chloromethyl sulphide~Methylthiomethyl chloride~MTM chloride
  • CHLOROMETHYL METHYL SULFIDE, ~80-85%
  • Methylchloromethylsulfide
  • MTMchloride
  • (Methylthio)chloromethane
  • Chloromethyl methyl sulfide,95%
  • Chloro(methylsulphanyl)methane
  • (chloroMethyl)(Methyl)sulfane
  • ChloroMethyl Methyl sulfide 95%
  • Chloro(methylsulphanyl)methane, Chloro(methylthio)methane
  • Chloromethyl Methyl Sulfide &gt
  • 2373-51-5
  • 2375-51-5
  • Synthetic Reagents
  • Others
  • Protection and Derivatization
  • Protecting and Derivatizing Reagents