CHLOROMETHYL METHYL SULFIDE
- Product Name
- CHLOROMETHYL METHYL SULFIDE
- CAS No.
- 2373-51-5
- Chemical Name
- CHLOROMETHYL METHYL SULFIDE
- Synonyms
- (chloroMethyl)(Methyl)sulfane;CH3SCH2Cl;Chloro(methylsulfanyl)methane;Methylthiomethyl chloride;MTMchloride;Clorodimetilsolfuro;CHLORODIMETHYL SULFIDE;chlorodimethylthioether;Chlorodimethyl thioether;methylthiomethylchloride
- CBNumber
- CB9295856
- Molecular Formula
- C2H5ClS
- Formula Weight
- 96.58
- MOL File
- 2373-51-5.mol
CHLOROMETHYL METHYL SULFIDE Property
- Boiling point:
- 105 °C (lit.)
- Density
- 1.153 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.498(lit.)
- Flash point:
- 63 °F
- storage temp.
- 2-8°C
- form
- clear liquid
- color
- Colorless to Light orange to Yellow
- Water Solubility
- Soluble in acetonitrile, ether and dichloromethane. Insoluble in water.
- Sensitive
- Moisture Sensitive
- BRN
- 1730851
- CAS DataBase Reference
- 2373-51-5(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242Use only non-sparking tools.
P243Take precautionary measures against static discharge.
N-Bromosuccinimide Price
- Product number
- C54007
- Product name
- Chloromethyl methyl sulfide
- Purity
- 95%
- Packaging
- 5g
- Price
- $80
- Updated
- 2024/03/01
- Product number
- C54007
- Product name
- Chloromethyl methyl sulfide
- Purity
- 95%
- Packaging
- 25g
- Price
- $191
- Updated
- 2024/03/01
- Product number
- C0608
- Product name
- Chloromethyl Methyl Sulfide
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $127
- Updated
- 2024/03/01
- Product number
- C0608
- Product name
- Chloromethyl Methyl Sulfide
- Purity
- >97.0%(GC)
- Packaging
- 100g
- Price
- $353
- Updated
- 2024/03/01
- Product number
- L10858
- Product name
- Chloromethyl methyl sulfide, 95%
- Packaging
- 10g
- Price
- $55.65
- Updated
- 2024/03/01
CHLOROMETHYL METHYL SULFIDE Chemical Properties,Usage,Production
Chemical Properties
CLEAR YELLOW TO BROWN LIQUID
Uses
Chloromethyl methyl sulfide is used as a methylene transfer reagent for iron(II) mediated cyclopropanation and for carbonyl and aromatic compounds. It protects alcohols as their methylthiomethyl (MTM) ethers by reaction, e.g. with NaH/NaI in DME. It is also used for the preparation of MTM esters of carboxylic acids, e.g. by treatment of the K salt of the acid in the presence of NaI and 18-crown-6 and for reaction with cyclopentadienyl iron dicarbonyl dimer in the formation of an iron-containing methylene transfer agent.
Uses
Methylthiomethylating reagent for carbonyl and aromatic compounds. Methylene transfer reagent for iron(II) mediated cyclopropanation.
Synthesis Reference(s)
Tetrahedron Letters, 35, p. 6127, 1994 DOI: 10.1016/0040-4039(94)88094-8
CHLOROMETHYL METHYL SULFIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from CHLOROMETHYL METHYL SULFIDE manufacturers
- Product
- Chloromethyl Methyl Sulfide 2373-51-5
- Price
- US $5.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-08-20
- Product
- Chloromethyl Methyl Sulfide 2373-51-5
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 99
- Supply Ability
- 100kg
- Release date
- 2019-07-10