2-Nitrobenzeneboronic acid pinacol ester

Product Name: 2-Nitrobenzeneboronic acid pinacol ester
CAS No.: 190788-59-1
Chemical Name: 2-Nitrobenzeneboronic acid pinacol ester
Synonyms: 2-Nitrobenzeneboronic acid picol ester;2-NITROPHENYLBORONIC ACID, PINACOL ESTER;2-NITROBENZENEBORONIC ACID PINACOL ESTER;2-Nitrophenylboronic Acid,Pinacol Ester,98%;2-Nitrobenzeneboronic acid, pinacol ester 98%;2-nitrophenylboronic acid pinacol cyclic ester;2-Nitrobenzeneboronic acid pinacol ester, 98+%;2-Nitrobenzeneboronic acid pinacol cyclic ester;4,4,5,5-tetramethyl-2-(2-nitrophenyl)-1,3,2-dioxaborolane;2-(2-Nitrophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CBNumber: CB0738093
Molecular Formula: C12H16BNO4
Formula Weight: 249.07
MOL File: 190788-59-1.mol

More

Less

2-Nitrobenzeneboronic acid pinacol ester Property

Melting point:: 42-44°C
Boiling point:: 358.2±25.0 °C(Predicted)
Density: 1.14±0.1 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: soluble in Methanol
form: powder to crystal
color: White to Orange to Green
BRN: 7708824
CAS DataBase Reference: 190788-59-1(CAS DataBase Reference)

More

Less

Safety

Risk Statements: 36/37/38
Safety Statements: 26-36
HS Code: 2931900090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More

Less

N-Bromosuccinimide Price

TCI Chemical

Product number: N1006
Product name: 4,4,5,5-Tetramethyl-2-(2-nitrophenyl)-1,3,2-dioxaborolane
Purity: >98.0%(GC)(T)
Packaging: 1g
Price: $60
Updated: 2025/07/31

TCI Chemical

Product number: N1006
Product name: 4,4,5,5-Tetramethyl-2-(2-nitrophenyl)-1,3,2-dioxaborolane
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $208
Updated: 2025/07/31

TRC

Product number: T889653
Product name: 4,4,5,5-Tetramethyl-2-(2-nitrophenyl)-1,3,2-dioxaborolane
Packaging: 10mg
Price: $45
Updated: 2021/12/16

Matrix Scientific

Product number: 116067
Product name: 4,4,5,5-Tetramethyl-2-(2-nitrophenyl)-1,3,2-dioxaborolane
Purity: >95%
Packaging: 500mg
Price: $47
Updated: 2021/12/16

Matrix Scientific

Product number: 116067
Product name: 4,4,5,5-Tetramethyl-2-(2-nitrophenyl)-1,3,2-dioxaborolane
Purity: >95%
Packaging: 1g
Price: $63
Updated: 2021/12/16

More

Less

2-Nitrobenzeneboronic acid pinacol ester Chemical Properties,Usage,Production

Synthesis

577-19-5

73183-34-3

190788-59-1

1-Bromo-2-nitrobenzene (10.0 g, 49.5 mmol, 1.0 eq.) and pinacol ester of bis(diphenylphosphine) (15.08 g, 59.4 mmol, 1.2 eq.) were added with potassium acetate (14.57 g, 148 mmol, 3.0 eq.) and [1,1'-bis(diphenylphosphino)palladium(II) dichloride] (1.09 g, 1.49 mmol, 0.03 equiv) in dioxane (180 mL). The reaction mixture was stirred at 80 °C for 12 hours under nitrogen protection. After completion of the reaction, the mixture was concentrated under reduced pressure to give the crude product. Purification by silica gel column chromatography (eluent: petroleum ether/ethyl acetate, 100:1 to 80:1) afforded 2-nitrophenylboronic acid pinacol ester as a yellow oil (12.0 g, 97% yield). The product was identified by 1H NMR (DMSO-d6, 400 MHz): δ 8.17 (d, J = 8.0 Hz, 1H), 7.67-7.65 (m, 1H), 7.58-7.54 (m, 2H), 1.44 (s, 12H).

References

[1] Patent: WO2018/144620, 2018, A1. Location in patent: Paragraph 00334
[2] Advanced Synthesis and Catalysis, 2016, vol. 358, # 6, p. 977 - 983
[3] Synlett, 2018, vol. 29, # 8, p. 1055 - 1060
[4] Journal of the American Chemical Society, 2015, vol. 137, # 21, p. 6738 - 6741
[5] Patent: CN108424344, 2018, A. Location in patent: Paragraph 0083; 0084; 0085; 0095

2-Nitrobenzeneboronic acid pinacol ester Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

2-Nitrobenzeneboronic acid pinacol ester Suppliers

Americas 1 China 119 Europe 1 France 1 Germany 2 India 3 Japan 2 Jordan 1 United Kingdom 3 United States 20 Global 153

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Wuhan Chemwish Technology Co., Ltd

Tel: 86-027-67849912
Fax: 86-027-87531808
Email: sales@chemwish.com
Country: China
ProdList: 35896
Advantage: 56

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Country: China
ProdList: 18207
Advantage: 66

Tetranov Biopharm

Tel: 13526569071
Email: sales@leadmedpharm.com
Country: China
ProdList: 7892
Advantage: 64

Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
Country: China
ProdList: 15883
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

More

Less

View Lastest Price from 2-Nitrobenzeneboronic acid pinacol ester manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: (2-Nitrophenyl)boronic acid 190788-59-1
Price: US $3.00-9.00/KG
Min. Order: 0.1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2025-07-03

Zhuozhou Wenxi import and Export Co., Ltd

Product: 2-Nitrobenzeneboronic acid pinacol ester 190788-59-1
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

190788-59-1, 2-Nitrobenzeneboronic acid pinacol esterRelated Search:

Tris(trimethylsilyl)phosphate 4-Nitrobenzoic acid BUTYL OLEATE Sodium 3-nitrobenzenesulphonate Dimethyl succinate Methyl acrylate 4-Nitrobenzaldehyde 4-Fluoronitrobenzene (5-ACETAMIDO-2-NITRO)BENZENEBORONIC ACID (4-BENZYLOXYCARBONYL-2-NITRO)BENZENEBORONIC ACID (4-METHYL-2-NITRO)BENZENEBORONIC ACID 4-CARBOXY-2-NITROPHENYLBORONIC ACID 4-METHOXYCARBONYL-2-NITROPHENYLBORONIC ACID (3-ACETAMIDO-2-NITRO)BENZENEBORONIC ACID Nitrobenzene (4-CYANO-2-NITROPHENYL)BORONIC ACID 4-Methoxy-2-nitrophenylboronic acid 1,3-Dinitrobenzene

2-Nitrobenzeneboronic acid, pinacol ester 98%

2-Nitrobenzeneboronic acid pinacol cyclic ester

2-Nitrophenylboronic acid pinacol cyclic ester~2-(2-Nitrophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-NITROBENZENEBORONIC ACID PINACOL ESTER

2-NITROPHENYLBORONIC ACID, PINACOL ESTER

2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)NITROBENZENE

2-(2-Nitrophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)nitrobenzene

2-Nitrophenylboronic Acid Pinacol Cyclic Ester~2-(2-Nitrophenyl)-

4,4,5,5-tetramethyl-2-(2-nitrophenyl)-1,3,2-dioxaborolane

2-(4,4,5,5-TetraMethyl-1,3,2-diocaborolan-2-yl)nitrobenzene

2-(2-Nitrophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-nitrophenylboronic acid pinacol cyclic ester

2-Nitrobenzeneboronic acid pinacol ester, 98+%

2-Nitrobenzeneboronic acid picol ester

4,4,5,5-Tetramethyl-2-(2-nitrophenyl)-1,3,2-dioxaborolane&gt

2-Nitrophenylboronic Acid,Pinacol Ester,98%

1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(2-nitrophenyl)-

1-Nitro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene

4,4,5,5-Tetramethyl-2-(2-nitrophenyl)-1,3,2-dioxaborolane - [T4762]

190788-59-1

C14H13BNO4

BORONIC ACID

Pyridines

blocks

BoronicAcids

NitroCompounds