2-(TRIMETHYLSILYLOXY)FURAN

Product Name: 2-(TRIMETHYLSILYLOXY)FURAN
CAS No.: 61550-02-5
Chemical Name: 2-(TRIMETHYLSILYLOXY)FURAN
Synonyms: TRIMETHYLSILYLOXYFURAN;2-(TRIMETHYLSILOXY)FURAN;2-Furyloxytrimethylsilane;2-(TRIMETHYLSILYLOXY)FURAN;(2-Furyloxy)trimethylsilane;2-(Trimethylsilyloxy)furane;2-(TriMethylsiloxy)furan 97%;Trimethyl(2-furanyloxy)silane;(2-FURANYLOXY)TRIMETHYLSILANE;2-Furyl(trimethylsilyl) ether
CBNumber: CB0749048
Molecular Formula: C7H12O2Si
Formula Weight: 156.25
MOL File: 61550-02-5.mol

More

Less

2-(TRIMETHYLSILYLOXY)FURAN Property

Boiling point:: 34-35 °C/9 mmHg (lit.)
Density: 0.929 g/mL at 25 °C (lit.)
refractive index: n20/D 1.436(lit.)
Flash point:: 76 °F
storage temp.: -20°C
solubility: sol most organic solvents, e.g. CH2Cl2, Et2O, benzene, THF, MeCN.
form: clear liquid
color: Colorless to Light orange to Yellow
Specific Gravity: 0.950
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
BRN: 1423066
CAS DataBase Reference: 61550-02-5(CAS DataBase Reference)

More

Less

Safety

Hazard Codes: F,Xi
Risk Statements: 11-36/37/38
Safety Statements: 26
RIDADR: UN 1993 3/PG 2
WGK Germany: 3
F: 10-21
TSCA: No
HS Code: 2932.19.5100
HazardClass: 3.2
PackingGroup: III

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 308064
Product name: 2-(Trimethylsiloxy)furan
Purity: 97%
Packaging: 5g
Price: $176.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 308064
Product name: 2-(Trimethylsiloxy)furan
Purity: 97%
Packaging: 1g
Price: $187
Updated: 2024/03/01

TCI Chemical

Product number: T1536
Product name: 2-(Trimethylsilyloxy)furan
Purity: >96.0%(GC)
Packaging: 5g
Price: $280
Updated: 2024/03/01

TCI Chemical

Product number: T1536
Product name: 2-(Trimethylsilyloxy)furan
Purity: >96.0%(GC)
Packaging: 25g
Price: $876
Updated: 2024/03/01

TRC

Product number: T896600
Product name: 2-(Trimethylsilyloxy)furan
Packaging: 100mg
Price: $60
Updated: 2021/12/16

More

Less

2-(TRIMETHYLSILYLOXY)FURAN Chemical Properties,Usage,Production

Physical properties

bp 44–46 °C/17 mmHg; d 0.93 gmL?1.

Uses

2-Trimethylsilyloxyfuran provides 5-substituted 2(5H)-furanones by alkylation, aldolization, 3 and conjugate addition; transforms quinones into furo-[3,2-b]benzofurans; useful for the four-carbon elongation of sugars. It is used in Synthetic Applications, Carbon–Heteroatom Bond Formation, Alkylation, Aldol-Type Reactions, Conjugate Addition, and Diels–Alder Reaction.

Uses

2-(Trimethylsilyloxy)furan is a useful reagent for the preparation of natural and synthetic furanones with anticancer activity.

Preparation

Accessible by silylation of 2(5H)-furanone, which is obtained at very low cost by oxidation of furfural.

Purification Methods

Fractionally distil it using a short path column. 1H NMR in CCl4 has : 4.90 (dd, J 1.3Hz, 3H), 6.00 (t, J 3Hz, 4H) and 6.60 (m, 5H). [Yoshii et al. Heterocycles 4 1663 1976.] 4-Trimethylsilyloxy-3-penten-2-one (cis) (acetylacetone enol trimethylsilyl ether) [13257-81-3] M 172.3, b 66-68o/4mm, 61-63o/5mm, d 4 0.917, n D 1.452. Fractionally distil it and store it in glass ampoules which are sealed under N2. It hydrolyses readily in contact with moisture giving, as likely impurities, hexamethyldisiloxane and 2,4-pentanedione. [West J Am Chem Soc 80 3246 1958, Beilstein 4 IV 4003.]

2-(TRIMETHYLSILYLOXY)FURAN Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

2-(TRIMETHYLSILYLOXY)FURAN Suppliers

China 56 France 1 Germany 2 India 1 Japan 1 Singapore 1 Switzerland 1 United Kingdom 3 United States 9 Global 75

Fluorochem Ltd

Tel: --
Fax: --
Email: vernam@fluorochem.co.uk
Country: United Kingdom
ProdList: 6375
Advantage: 65

Fluorochem Ltd.

Tel: --
Fax: --
Email: enquiries@fluorochem.co.uk
Country: United Kingdom
ProdList: 6401
Advantage: 74

VWR International

Tel: --
Fax: --
Email: solutions@vwr.com
Country: United Kingdom
ProdList: 6548
Advantage: 82

More

Less

View Lastest Price from 2-(TRIMETHYLSILYLOXY)FURAN manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: 2-(TRIMETHYLSILYLOXY)FURAN 61550-02-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Career Henan Chemical Co

Product: 2-(TRIMETHYLSILYLOXY)FURAN 61550-02-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98% HPLC
Supply Ability: 10 tons/month
Release date: 2020-01-09

61550-02-5, 2-(TRIMETHYLSILYLOXY)FURANRelated Search:

4,5-Dihydro-3α,4α-bis(trimethylsilyloxy)furan-2(3H)-one 2-(TRIMETHYLSILYLOXY)FURAN

TRIMETHYLSILYLOXYFURAN

2-(TRIMETHYLSILOXY)FURAN

2-(TRIMETHYLSILYLOXY)FURAN

(2-FURANYLOXY)TRIMETHYLSILANE

2-(TRIMETHYLSILOXY)FURAN, STAB.

2-(Trimethylsilyloxy)furane

(2-Furyloxy)trimethylsilane

[(2-Furyl)oxy]trimethylsilane

2-Furyl(trimethylsilyl) ether

2-Furyloxytrimethylsilane

Trimethyl(2-furanyloxy)silane

(furan-2-yloxy)triMethylsilane

2-(TriMethylsiloxy)furan 97%

2- triMethylsilyloxyindane furan

Furan, 2-[(trimethylsilyl)oxy]-

61550-02-5

Monoalkoxysilanes

Building Blocks

Si-O Compounds

Si (Classes of Silicon Compounds)

Silicon Compounds (for Synthesis)

Heterocyclic Building Blocks

Furans

Monoalkoxysilanes

Si (Classes of Silicon Compounds)

Silicon Compounds (for Synthesis)

Si-O Compounds

Synthetic Organic Chemistry

Building Blocks

Furans

Heterocyclic Building Blocks