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Acetophenone oxime

Product Name
Acetophenone oxime
CAS No.
613-91-2
Chemical Name
Acetophenone oxime
Synonyms
HYPNONE OXINIE;ACETOPHENONE OXIME;ACETYLBENZENE OXIME;methylphenylketoxime;4-ACETOPHENONE OXIME;AcetophenoneOxime>Acetophenoneoxime,98%;BENZOYL METHIDE OXIME;1-phenyl-ethanonoxime;1-Phenylethanone oxime
CBNumber
CB0758064
Molecular Formula
C8H9NO
Formula Weight
135.16
MOL File
613-91-2.mol
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Acetophenone oxime Property

Melting point:
55-60 °C (lit.)
Boiling point:
118-120 °C/20 mmHg (lit.)
Density 
1.11 g/mL at 25 °C (lit.)
refractive index 
1.5302 (rough estimate)
Flash point:
118-120°C/20mm
storage temp. 
-20°C
pka
11.43±0.70(Predicted)
form 
powder to crystal
color 
White to Light yellow
Water Solubility 
slightly soluble
Sensitive 
Air & Moisture Sensitive
BRN 
1562059
InChIKey
JHNRZXQVBKRYKN-CLFYSBASSA-N
CAS DataBase Reference
613-91-2(CAS DataBase Reference)
NIST Chemistry Reference
Ethanone, 1-phenyl-, oxime(613-91-2)
EPA Substance Registry System
Ethanone, 1-phenyl-, oxime (613-91-2)
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Safety

Hazard Codes 
T,Xi
Risk Statements 
25-41-36/37/38
Safety Statements 
26-39-37/39
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
3
RTECS 
AM9654000
TSCA 
Yes
HazardClass 
IRRITANT
HS Code 
29280090
Toxicity
LD50 orl-mus: 2 g/kg MEXPAG 11,137,64
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H318Causes serious eye damage

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P330Rinse mouth.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
647659
Product name
Acetophenone oxime
Purity
95%
Packaging
5g
Price
$54
Updated
2024/03/01
Sigma-Aldrich
Product number
647659
Product name
Acetophenone oxime
Purity
95%
Packaging
25g
Price
$156
Updated
2024/03/01
TCI Chemical
Product number
A0807
Product name
Acetophenone Oxime
Purity
>98.0%(GC)(N)
Packaging
25g
Price
$60
Updated
2024/03/01
Alfa Aesar
Product number
A11804
Product name
Acetophenone oxime, 98%
Packaging
10g
Price
$36.65
Updated
2024/03/01
Alfa Aesar
Product number
A11804
Product name
Acetophenone oxime, 98%
Packaging
50g
Price
$118.65
Updated
2024/03/01
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Acetophenone oxime Chemical Properties,Usage,Production

Description

Acetophenone oxime is a solid but slightly soluble substance. Acetophenone oxime is incompatible with strong oxidising agents, moisture, acids, and metal and alkali compounds. Acetophenone oxime on decomposition releases irritating and toxic fumes and gases. There is no published data about the hazardous polymerisation of acetophenone oxime.

Chemical Properties

Acetophenone oxime is a solid but slightly soluble substance. It is incompatible with strong oxidizing agents, moisture, acids, metal, and alkali compounds. On decomposition, acetophenone oxime releases irritating and toxic fumes and gases. There are no published data about the hazardous polymerization of acetophenone oxime.

Chemical Properties

WHITE TO CREAM CRYSTALLINE POWDER

Uses

1-Phenylethanone Oxime is a useful reagent for organic synthesis

Synthesis Reference(s)

The Journal of Organic Chemistry, 52, p. 5089, 1987 DOI: 10.1021/jo00232a005
Tetrahedron Letters, 30, p. 5763, 1989 DOI: 10.1016/S0040-4039(00)76191-0

Health Hazard

Exposures to acetophenone oxime cause irritation to the eyes, skin, and the respiratory and digestive tracts. The toxicological properties of acetophenone oxime are not been fully investigated.

Safety Profile

Poison by an unspecified route.Slightly toxic by ingestion. When heated to decomposition itemits toxic vapors of NOx.

storage

Acetophenone oxime should be kept stored in a cool, dry place and in a closed container when not in use.

Precautions

On exposures to acetophenone oxime, occupational workers should immediately fl ush the eyes with plenty of water. Workers should use proper personal protective equipment, wear appropriate gloves to prevent skin exposure, and wear appropriate protective eyeglasses or chemical safety goggles as described.

Acetophenone oxime Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Acetophenone oxime manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
Acetophenone oxime 613-91-2
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Career Henan Chemical Co
Product
Acetophenone oxime 613-91-2
Price
US $2.00/KG
Min. Order
1KG
Purity
≥98%
Supply Ability
100kg
Release date
2019-12-20

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