2-Aminobenzonitrile

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2-Aminobenzonitrile

Product Name: 2-Aminobenzonitrile
CAS No.: 1885-29-6
Chemical Name: 2-Aminobenzonitrile
Synonyms: ANTHRANILONITRILE;Aminobenzonitrile;2-CYANOANILINE;Benzonitrile, 2-amino-;AKOS 91125;2-CYANANILINE;O-CYANOANILINE;JACS-1885-29-6;O-aminonitrile;Anthranilonotrile
CBNumber: CB0766038
Molecular Formula: C7H6N2
Formula Weight: 118.14
MOL File: 1885-29-6.mol

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2-Aminobenzonitrile Property

Melting point:: 45-48 °C (lit.)
Boiling point:: 267-268 °C (lit.)
Density: 1.11 g/cm3 (50℃)
refractive index: 1.5500 (estimate)
Flash point:: >230 °F
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form: Crystalline Flakes
pka: 0.77(at 25℃)
color: Yellow to beige-brown
Water Solubility: INSOLUBLE
BRN: 907187
InChIKey: HLCPWBZNUKCSBN-UHFFFAOYSA-N
LogP: 0.901
CAS DataBase Reference: 1885-29-6(CAS DataBase Reference)
NIST Chemistry Reference: Benzonitrile, 2-amino-(1885-29-6)
EPA Substance Registry System: Benzonitrile, 2-amino- (1885-29-6)

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Safety

Hazard Codes: Xn,T,Xi
Risk Statements: 20/21/22-36/37/38-43
Safety Statements: 26-36/37-36
RIDADR: 3276
WGK Germany: 2
RTECS: CB4575000
TSCA: T
HazardClass: 6.1
PackingGroup: III
HS Code: 29269095
Toxicity: LD50 ivn-mus: 180 mg/kg CSLNX* NX#00381

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: A89901
Product name: 2-Aminobenzonitrile
Purity: 98%
Packaging: 25g
Price: $65.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: A89901
Product name: 2-Aminobenzonitrile
Purity: 98%
Packaging: 100g
Price: $184
Updated: 2024/03/01

TCI Chemical

Product number: A0861
Product name: 2-Aminobenzonitrile
Purity: >98.0%(GC)
Packaging: 25g
Price: $25
Updated: 2024/03/01

TCI Chemical

Product number: A0861
Product name: 2-Aminobenzonitrile
Purity: >98.0%(GC)
Packaging: 100g
Price: $70
Updated: 2024/03/01

Alfa Aesar

Product number: A12286
Product name: 2-Aminobenzonitrile, 98%
Packaging: 50g
Price: $53.3
Updated: 2024/03/01

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2-Aminobenzonitrile Chemical Properties,Usage,Production

Chemical Properties

It is a chemically stable yellow solid that readily forms salts when it encounters acid. It can be oxidized to nitrogen oxide by oxidants but has certain toxicity. The substance is easily soluble in common organic solvents but hardly soluble in low-polarity solvents, and it is insoluble in water.

Uses

2-Aminobenzonitrile is used for induction of nitrilase activity in Arthrobacter and for radioprotective agent.

Preparation

Synthesis of 2-Aminobenzonitrile: 2-Aminobenzamide was dehydrated to 2-aminobenzonitrile without protection of the amino group in the presence of phenylphosphonyl dichloride and pyridine. The highest yield of 96% was obtained using reagent 2d, while reagents 2a-c yielded less than 60%.

The reagents used for the reaction included phosphoryl chloride (2a), phenyl phosphoryl dichloride (2b), 4-chlorophenyl phosphoryl dichloride (2c), and phenylphosphonic dichloride (2d) in pyridine.
synthesis of aminobenzonitrile by dehydration of aminobenzamide using phenylphosphonic dichloride in pyridine

Synthesis Reference(s)

Journal of the American Chemical Society, 96, p. 5933, 1974 DOI: 10.1021/ja00825a039
The Journal of Organic Chemistry, 43, p. 944, 1978 DOI: 10.1021/jo00399a030
Tetrahedron Letters, 32, p. 1007, 1991 DOI: 10.1016/S0040-4039(00)74473-X
Improving a process for the preparation of 2-aminobenzonitrile by reduction of 2-nitrobenzonitrile.

Safety Profile

Poison by intravenous route. Seealso NITRILES. When heated to decomposition it emitstoxic fumes of NOx and CN^- .

2-Aminobenzonitrile Preparation Products And Raw materials

Raw materials

Preparation Products

2-Amino-5-chlorobenzonitrile 1,2,3,4-TETRAHYDRO-9-ACRIDINAMINE 6-CHLOROQUINAZOLIN-4-AMINE

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View Lastest Price from 2-Aminobenzonitrile manufacturers

Zhengzhou Lingzhiyue Technology Co., Ltd

Product: 2-Aminobenzonitrile 1885-29-6
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 9999
Release date: 2023-10-28

Henan Fengda Chemical Co., Ltd

Product: 2-Aminobenzonitrile 1885-29-6
Price: US $5.00-0.10/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-16

Hebei Yanxi Chemical Co., Ltd.

Product: 2-Aminobenzonitrile 1885-29-6
Price: US $20.00-18.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 200tons
Release date: 2023-08-29

1885-29-6, 2-AminobenzonitrileRelated Search:

Sulfamic acid EC 2.6.1.2 4-Nitrobenzonitrile Acetaminophen 2-Cyanophenol Glucosamine Benzonitrile p-Tolunitrile Anthranilic acid 4-Aminobenzonitrile 2-Amino-6-fluorobenzonitrile Anthranilonitrile, 5-nitro- 5-Chloro-2-nitrobenzonitrile 2-Nitrobenzonitrile 2-CHLORO-6-NITROBENZONITRILE 2-Amino-6-chlorobenzonitrile 2-Amino-4-chlorobenzonitrile 4,5-DIMETHOXY-2-NITROBENZONITRILE

O-AMINOBENZONITRILE

O-CYANOANILINE

2-amino-benzonitril

2-Cyano-1-aminobenzene

Benzonitrile, o-amino-

2-Aminobenzonitrile, (Anthranilonitrile

Aminobenzonitrile

2-AMINOBENZONITRILE

2-CYANOANILINE

2-CYANANILINE

AKOS 91125

ANTHRANILIC ACID NITRILE

ANTHRANILONITRILE

AMINOBENZONITRILE(2-)

LABOTEST-BB LTBB000570

Neighboring aMino cyanobenzene

JACS-1885-29-6

Anthranilonitrile~2-Cyanoaniline

2-Aminobenzontrile

2-Aminoobenzonitrile

Benzonitrile, 2-amino-

2-AMINO BENZONITRILE (2-CYANO ANILINE)

o-anthranilonitrile

ORTHO-AMINOBENZONITRILE

Anthranilonitrile 98%

1-Amino-2-cyanobenzene

2-Cyanophenylamine

o-Aminocyanobenzene

2-Cyanoaniline, Anthranilonitrile

Anthranilonotrile

Anthranilonitrile,98%

2-Aminobenzonitrile ,98%

2-Aminobenzonitrile,2-Cyanoaniline, Anthranilonitrile

2-AMinobenzonitrile, 98% 100GR

2-AMinobenzonitrile, 98% 10GR

2-AMINOBENZONITRILE FOR SYNTHESIS

2-Aminobenzonitrile &gt

O-aminonitrile

O-aminophenonitrile

1885-29-6

H2NC6H4CN

NH2C6H4CN

Building Blocks

C6 to C7

Cyanides/Nitriles

Organic Building Blocks

Nitrogen Compounds

Pharmaceutical intermdiate

Chemical Amines

Amines

Aromatics

FINE Chemical & INTERMEDIATES

Aromatic Nitriles

Nitriles