4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl

Product Name: 4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl
CAS No.: 85954-11-6
Chemical Name: 4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl
Synonyms: TMDE;Tetramethylbiphenyl diglycidyl ether;Bis(glycidyloxy) tetramethylbiphenyl;3,3'5,5'-Tetramethylbiphenyl Diglycidyl Ether;4,4-DIGLYCIDYLOXY-3,3,5,5-TETRAMETHYL BIPHENYL;4,4'-diglycidyloxy-3,3',5,5'-tetramethyl biphenyl;3,3’,5,5’-Tetramethyl-4,4’-(diglycidyloxy)biphenyl;4,4'-bis(glycidyloxy)-3,3',5,5'-tetramethylbiphenyl;3,3',5,5'-Tetramethyl-4,4'-bis(glycidyloxy)biphenyl;(tetramethylbiphenyldiyl)bis(oxymethylene)bisoxirane
CBNumber: CB0855158
Molecular Formula: C22H26O4
Formula Weight: 354.44
MOL File: 85954-11-6.mol

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4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl Property

Melting point:: 105°C
Boiling point:: 473°C
Density: 1.149
Flash point:: 132°C
storage temp.: -20°C Freezer, Under inert atmosphere
solubility: Benzene (Slightly, Sonicated), Chloroform (Slightly, Heated, Sonicated)
form: Solid
color: Pale Yellow to Pale Beige
CAS DataBase Reference: 85954-11-6(CAS DataBase Reference)
EPA Substance Registry System: Oxirane, 2,2'-[(3,3',5,5'-tetramethyl[1,1'-biphenyl]-4,4'-diyl)bis(oxymethylene)]bis- (85954-11-6)

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Safety

Hazard Codes: Xn
Risk Statements: 68
Safety Statements: 22-36-37
TSCA: TSCA listed

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H317May cause an allergic skin reaction

H351Suspected of causing cancer

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P281Use personal protective equipment as required.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

P321Specific treatment (see … on this label).

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P363Wash contaminated clothing before reuse.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Biosynth Carbosynth

Product number: FB150782
Product name: 4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl
Packaging: 100mg
Price: $73
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB150782
Product name: 4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl
Packaging: 250mg
Price: $145
Updated: 2021/12/16

AK Scientific

Product number: 2467CS
Product name: 4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl
Packaging: 100mg
Price: $148
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB150782
Product name: 4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl
Packaging: 500mg
Price: $255
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB150782
Product name: 4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl
Packaging: 1g
Price: $440
Updated: 2021/12/16

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4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl Chemical Properties,Usage,Production

Uses

4,4''-Bis(2,3-epoxypropoxy)-3,3'',5,5''-tetramethylbiphenyl can be used for bisphenol A-free in-can anticorrosive coating for metal packaging container.

Synthesis

The traditional preparation of 3,3'5,5'-tetramethylbiphenyl bisphenol diglycidyl ether is mainly prepared by a one-step method using NaOH, but in order to obtain a product with an epoxy equivalent close to the theoretical value, the addition of NaOH is strictly required, and the post-reaction treatment is cumbersome. Take isopropanol 10mL, epichlorohydrin 110g, 3,3’,5,5’-tetramethyl-4,4’-biphenol 14.52g, tetrabutylammonium bromide 0.15g, 90 ?? nitrogen stirring reaction for 10 hours, dropwise addition of sodium hydroxide containing 8g of a solution with a concentration of 30%, while the decompression of steam to remove the excess epichlorohydrin, dropwise addition of sodium hydroxide to continue the reaction for 30 minutes. After adding continue to stir the reaction for 30 minutes, cold water rinse twice, after filtration with methanol / acetone (2:1 v/v) mixed solution recrystallized twice, activated charcoal discoloration, 70 ?? vacuum drying to get a light yellow 3,3'5,5'-tetramethylbiphenyl bisphenol diglycidyl ether 24.84 g. Yield: 86%, epoxy equivalents: 189g/mol, melting point: 104-106??C.

4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl Preparation Products And Raw materials

Raw materials

Preparation Products

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4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl Suppliers

China 83 United Kingdom 2 United States 2 Global 87

Zouping Mingxing Chemical Co.,Ltd.

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Henan Alfachem Co.,Ltd.

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View Lastest Price from 4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: 4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl 85954-11-6
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100 mt
Release date: 2024-11-19

Hebei Chuanghai Biotechnology Co,.LTD

Product: 4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl 85954-11-6
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-20

Zhuozhou Wenxi import and Export Co., Ltd

Product: 4,4"-Bis(2,3-epoxypropoxy)-3,3",5,5"-tetramethylbiphenyl 85954-11-6
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

85954-11-6, 4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenylRelated Search:

C8E3 Biphenyl Dimethyl ether Ethylbenzene Allyl glycidyl ether BISPHENOL A DIGLYCIDYL ETHER RESIN Glycidyl phenyl ether 1,2,3-PROPANETRIOL GLYCIDYL ETHER DIGLYCIDYL ETHER Ethylene glycol diglycidyl ether 2-Phenyltoluene Diethyl ether 2,2',6,6'-Tetramethyl-4,4'-biphenol 3,3',5,5'-TETRAMETHYLBIPHENYL 3,3',5,5'-Tetramethyl-4,4'-di(2-hydoxethanyoxy)biphenyl 4,4'-DIETHOXYBIPHENYL 4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl

3,3',5,5'-Tetramethyl-4,4'-diphenol diglycidyl ether

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3,5,3`,5`-Tetramethyl-4,4`-di(2,3-epoxypropanoxy)bibenzene

Oxirane, 2,2-(3,3,5,5-tetramethyl1,1-biphenyl-4,4-diyl)bis(oxymethylene)bis-

4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethyl(1,1'-biphenyl)

4,4-DIGLYCIDYLOXY-3,3,5,5-TETRAMETHYL BIPHENYL

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(tetramethylbiphenyldiyl)bis(oxymethylene)bisoxirane

4,4'-bis(glycidyloxy)-3,3',5,5'-tetramethylbiphenyl

4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl

Bis(glycidyloxy) tetramethylbiphenyl

3,3'-(3,3',5,5'-Tetramethyl-1,1'-biphenyl-4,4'-diylbisoxy)bis(1,2-epoxypropane)

3,3',5,5'-Tetramethyl-4,4'-bis(glycidyloxy)biphenyl

3,3',5,5'-Tetramethyl-4,4'-bis(oxiranylmethoxy)-1,1'-biphenyl

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4,4'-Bis(2,3-epoxypropan-1-yloxy)-3,3',5,5'-tetramethylbiphenyl

TMDE

4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl ISO 9001：2015 REACH

TIANFUCHEM--85954-11-6--4,4'-Bis(2,3-epoxypropoxy)-3,3',5,5'-tetramethylbiphenyl in stock

2,2'-(((3,3',5,5'-Tetramethyl-[1,1'-biphenyl]-4,4'-diyl)bis(oxy))bis(methylene))bis(oxirane)

3,3'5,5 '- tetramethylbiphenyl bisphenol diglycidyl ether

4,4'-diglycidyloxy-3,3',5,5'-tetramethyl biphenyl

2,2'-((3,3',5,5'-tetramethyl-(1,1'-biphenyl)-4,4'-diyl)-bis(oxymethylene))-bis-oxirane

3,3'5,5'-Tetramethylbiphenyl Diglycidyl Ether

85954-11-6