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4-(3'-fluorophenyl)-cyclohexanone

Product Name
4-(3'-fluorophenyl)-cyclohexanone
CAS No.
40503-87-5
Chemical Name
4-(3'-fluorophenyl)-cyclohexanone
Synonyms
KP(F);3-fluoro-4'-pentylcyclohexyl;4-(3'-fluorophenyl)-cyclohexanone;Cyclohexanone, 4-(3-fluorophenyl)-;4-(3-fluorophenyl)cyclohexan-1-one
CBNumber
CB11117568
Molecular Formula
C12H13FO
Formula Weight
192.23
MOL File
40503-87-5.mol
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4-(3'-fluorophenyl)-cyclohexanone Property

Boiling point:
289℃
Density 
1.121
Flash point:
126℃
storage temp. 
Sealed in dry,Room Temperature
Appearance
White to light yellow Solid
InChI
InChI=1S/C12H13FO/c13-11-3-1-2-10(8-11)9-4-6-12(14)7-5-9/h1-3,8-9H,4-7H2
InChIKey
LIAPPURFKRACQO-UHFFFAOYSA-N
SMILES
C1(=O)CCC(C2=CC=CC(F)=C2)CC1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

AK Scientific
Product number
2324CY
Product name
4-(3-Fluorophenyl)cyclohexanone
Packaging
100mg
Price
$223
Updated
2021/12/16
Chemenu
Product number
CM203145
Product name
4-(3-fluorophenyl)cyclohexan-1-one
Purity
95%
Packaging
1g
Price
$235
Updated
2021/12/16
Alichem
Product number
40503875
Product name
4-(3-Fluorophenyl)cyclohexanone
Packaging
1g
Price
$243.47
Updated
2021/12/16
Crysdot
Product number
CD41001075
Product name
4-(3-Fluorophenyl)cyclohexanone
Purity
95+%
Packaging
1g
Price
$570
Updated
2021/12/16
Chemenu
Product number
CM203145
Product name
4-(3-fluorophenyl)cyclohexan-1-one
Purity
95%
Packaging
5g
Price
$704
Updated
2021/12/16
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4-(3'-fluorophenyl)-cyclohexanone Chemical Properties,Usage,Production

Synthesis

217476-14-7

40503-87-5

The compound (CAS:217476-14-7) (61.9 g) was added to a reaction vessel with formic acid (120 g) and toluene (120 ml) under nitrogen protection. After heating and refluxing the reaction for 3 hours, it was slowly cooled to room temperature. To the reaction mixture, water (300 ml) and toluene (300 ml) were added, mixed thoroughly and left to stand until it was layered into organic and aqueous phases. The organic phase was separated and washed sequentially with saturated aqueous sodium bicarbonate and water, followed by drying with anhydrous magnesium sulfate. The solvent was removed by distillation under reduced pressure and the residue was purified by column chromatography using a solvent mixture of toluene and ethyl acetate (toluene: ethyl acetate = 9:1, v/v) as eluent and silica gel as stationary phase. The target fraction was collected and dried to give 47.2 g of 4-(3-fluorophenyl)cyclohexanone (19) in 93.7% yield (calculated based on compound (18)).

References

[1] Patent: EP2206695, 2010, A1. Location in patent: Page/Page column 57-58
[2] Patent: EP2279990, 2011, A1. Location in patent: Page/Page column 51
[3] Journal of the American Chemical Society, 2012, vol. 134, # 41, p. 17023 - 17026,4
[4] Journal of the American Chemical Society, 2012, vol. 134, # 41, p. 17023 - 17026
[5] Journal of the American Chemical Society, 2012, vol. 134, # 49, p. 20208 - 20208

4-(3'-fluorophenyl)-cyclohexanone Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(3'-fluorophenyl)-cyclohexanone Suppliers

China 47 India 1 United States 4 Global 52
A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
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View Lastest Price from 4-(3'-fluorophenyl)-cyclohexanone manufacturers

Shanghai Bojing Chemical Co.,Ltd.
Product
4-(3'-fluorophenyl)-cyclohexanone 40503-87-5
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99.5%
Supply Ability
10MT
Release date
2024-03-13
Zhuozhou Wenxi import and Export Co., Ltd
Product
4-(3"-fluorophenyl)-cyclohexanone 40503-87-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
4-(3"-fluorophenyl)-cyclohexanone 40503-87-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09

40503-87-5, 4-(3'-fluorophenyl)-cyclohexanoneRelated Search:

4-CYANO-4-(4-FLUOROPHENYL)CYCLOHEXANONE 4-CYANO-4-(3-METHOXYPHENYL)CYCLOHEXANONE 4-CYANO-4-(3,4-DIMETHOXYPHENYL)CYCLOHEXANONE 4-(3-METHOXYPHENYL)CYCLOHEXANONE Cyclohexanone, 4-(4-chlorophenyl)- 4-[P-(BENZYLOXY)PHENYL]CYCLOHEXANONE 4-(4-fluorophenyl)cyclohexanone 4-(4-Nitrophenyl)cyclohexanone 4-(4-OXOCYCLOHEXYL)BENZONITRILE 4-Methyl-4-phenylcyclohexanone 4-(4-BROMOPHENYL)CYCLOHEXANONE 4-(4-Fluorophenyl)-4-hydroxycyclohexanone 4-(4-Methylphenyl)cyclohexanone 1-[3-(CYCLOPENTYLOXY)-4-METHOXYPHENYL]-4-OXOCYCLOHEXANE-1-CARBONITRILE Cyclohexanone 4-Phenylcyclohexanone

  • 4-(3'-fluorophenyl)-cyclohexanone
  • 3-fluoro-4'-pentylcyclohexyl
  • KP(F)
  • 4-(3-fluorophenyl)cyclohexan-1-one
  • Cyclohexanone, 4-(3-fluorophenyl)-
  • 40503-87-5
  • C12H13OF