3,6-Diphenyl-9H-carbazole
Uses- Product Name
- 3,6-Diphenyl-9H-carbazole
- CAS No.
- 56525-79-2
- Chemical Name
- 3,6-Diphenyl-9H-carbazole
- Synonyms
- 3,6-Diphenylcarbazole;EFFA;3,6-Diphenylcarbazole>,6-Diphenyl-9H-carbazole;3,6-Biphenyl-9H-carbazole;9H-Carbazole,3,6-diphenyl-;3,6-DIPHENYL-9H-CARBAZOLE;3,6-DIPHENYL-9H-CARBAZOLE 99%
- CBNumber
- CB11119047
- Molecular Formula
- C24H17N
- Formula Weight
- 319.4
- MOL File
- 56525-79-2.mol
3,6-Diphenyl-9H-carbazole Property
- Melting point:
- 186℃
- Boiling point:
- 575℃
- Density
- 1.198
- Flash point:
- 256℃
- storage temp.
- Sealed in dry,Room Temperature
- form
- powder to crystal
- pka
- 16.82±0.30(Predicted)
- color
- White to Almost white
- InChI
- InChI=1S/C24H17N/c1-3-7-17(8-4-1)19-11-13-23-21(15-19)22-16-20(12-14-24(22)25-23)18-9-5-2-6-10-18/h1-16,25H
- InChIKey
- PCMKGEAHIZDRFL-UHFFFAOYSA-N
- SMILES
- N1C2=C(C=C(C3=CC=CC=C3)C=C2)C2=C1C=CC(C1=CC=CC=C1)=C2
- CAS DataBase Reference
- 56525-79-2
Safety
- HS Code
- 2933.99.8290
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- D4433
- Product name
- 3,6-Diphenylcarbazole
- Purity
- >99.0%(GC)
- Packaging
- 1g
- Price
- $41
- Updated
- 2025/07/31
- Product number
- D4433
- Product name
- 3,6-Diphenylcarbazole
- Purity
- >99.0%(GC)
- Packaging
- 5g
- Price
- $70
- Updated
- 2025/07/31
- Product number
- D493845
- Product name
- 3,6-Diphenyl-9H-carbazole
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- CHM0098171
- Product name
- 3,6-DIPHENYL-9H-CARBAZOLE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $847.72
- Updated
- 2021/12/16
- Product number
- FD62358
- Product name
- 3,6-Diphenylcarbazole
- Packaging
- 100g
- Price
- $600
- Updated
- 2021/12/16
3,6-Diphenyl-9H-carbazole Chemical Properties,Usage,Production
Uses
Used as an intermediate in organic synthesis and materials.
Description
3,6-Diphenyl-9H-carbazole, also known as 3,6-Diphenylcarbazole (DPhCz), is another electron-donating 9H-carbazole derivative that has an extended π-π conjugation from the carbazole fusion ring to the phenyl group attached to the 3,-6 position. The degree of electron donating strength is in the order of carbazole 3,6-dimethylcarbazole 3,6-diphenylcarbazole, resulting in the relatively red-shift of emissions of 3,6-dimethylcarbazole and 3,6-diphenylcarbazole while comparing non-substituted carbazoles.
Synthesis
6825-20-3
98-80-6
56525-79-2
Under nitrogen protection, 3,6-dibromocarbazole (5 g, 15.4 mmol), phenylboronic acid (4.1 g, 33.9 mmol), palladium triphenylphosphine (0.7 g, 0.6 mmol) and toluene (45 ml) were sequentially added to a dry reaction flask. Subsequently, 2M aqueous sodium carbonate solution (45 ml) was slowly added. The reaction mixture was stirred at 80°C for 8 hours. After completion of the reaction, the organic phase was separated and concentrated under reduced pressure using a rotary evaporator. Finally, the concentrated residue was purified by silica gel column chromatography to afford the target product 3,6-diphenylcarbazole (3.6 g, 74% yield).
References
[1] Patent: KR2015/6758, 2015, A. Location in patent: Paragraph 0362-0364
[2] Patent: EP2818468, 2014, A2. Location in patent: Paragraph 0102; 0103
[3] Patent: WO2010/46259, 2010, A1. Location in patent: Page/Page column 55
[4] Patent: TWI554499, 2016, B. Location in patent: Page/Page column 89
[5] Patent: TW2016/38086, 2016, A. Location in patent: Page/Page column 41; 42
3,6-Diphenyl-9H-carbazole Preparation Products And Raw materials
Raw materials
Preparation Products
3,6-Diphenyl-9H-carbazole Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28387
- Advantage
- 80
View Lastest Price from 3,6-Diphenyl-9H-carbazole manufacturers
- Product
- 3,6-Diphenyl-9H-carbazole 56525-79-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 10000KGS
- Release date
- 2025-05-16
- Product
- 3,6-Diphenylcarbazole 56525-79-2
- Price
- US $0.00/Kg
- Min. Order
- 1Kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2025-04-12
- Product
- 3,6-diphenyl-9H-carbazole 56525-79-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 5mg
- Purity
- 99%HPLC
- Supply Ability
- 2000tons
- Release date
- 2020-01-06