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Hexamethylene diacrylate

Description Sources
Product Name
Hexamethylene diacrylate
CAS No.
13048-33-4
Chemical Name
Hexamethylene diacrylate
Synonyms
HDDA;1,6-HEXANEDIOL DIACRYLATE;Hexanediol acrylate;HDODA;Hexamethylendiacrylat;Hexane-1,6-diyl diacrylate;c716;sr238;nkesterahd;viscoat230
CBNumber
CB1114704
Molecular Formula
C12H18O4
Formula Weight
226.27
MOL File
13048-33-4.mol
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Hexamethylene diacrylate Property

Melting point:
6°C
Boiling point:
295°C
Density 
1.01 g/mL at 25 °C (lit.)
vapor density 
>1 (vs air)
vapor pressure 
<0.01 mm Hg ( 20 °C)
refractive index 
n20/D 1.456(lit.)
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
solubility 
Chlroform (Slightly), DMSO (Slightly)
form 
Liquid
color 
Colourless
Specific Gravity
1.01
Water Solubility 
Slightly miscible with water.
FreezingPoint 
6
Sensitive 
Hygroscopic
Stability:
Light Sensitive
InChIKey
FIHBHSQYSYVZQE-UHFFFAOYSA-N
LogP
2.81 at 25℃
CAS DataBase Reference
13048-33-4(CAS DataBase Reference)
NIST Chemistry Reference
Hexamethylene diacrylate(13048-33-4)
EPA Substance Registry System
1,6-Hexanediol diacrylate (13048-33-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/38-43
Safety Statements 
39
RIDADR 
UN 3082 9/PG 3
WGK Germany 
2
RTECS 
AT1430000
TSCA 
Yes
HazardClass 
9
PackingGroup 
III
HS Code 
29161290
Hazardous Substances Data
13048-33-4(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
246816
Product name
1,6-Hexanediol diacrylate
Purity
technical grade, 80%
Packaging
100g
Price
$51
Updated
2024/03/01
Sigma-Aldrich
Product number
246816
Product name
1,6-Hexanediol diacrylate
Purity
technical grade, 80%
Packaging
500g
Price
$122
Updated
2024/03/01
TCI Chemical
Product number
B2936
Product name
1,6-Bis(acryloyloxy)hexane (stabilized with MEHQ)
Purity
>85.0%(GC)
Packaging
25g
Price
$27
Updated
2024/03/01
TCI Chemical
Product number
B2936
Product name
1,6-Bis(acryloyloxy)hexane (stabilized with MEHQ)
Purity
>85.0%(GC)
Packaging
500g
Price
$103
Updated
2024/03/01
Alfa Aesar
Product number
043203
Product name
1,6-Hexanediol diacrylate, 99% (reactive esters), stab. with 90ppm hydroquinone
Packaging
50g
Price
$44.5
Updated
2024/03/01
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Hexamethylene diacrylate Chemical Properties,Usage,Production

Description

Hexamethylene diacrylate (also known as hexanediol diacrylate) is a di-functional acrylic monomer that can be polymerized by free radicals. It is used in ultra violet (UV) and electron beam (EB) applications as a reactive component in formulating coatings and inks, furniture and floor coatings, coatings on plastic substrates, varnishes for packing items and more1. The hexamethylene diacrylate cross-linked polystyrene resin can be used for the solid phase synthesis of hydrophobic peptides2-3.

Sources

  1. https://www.ashland.com/file_source/Ashland/Documents/Sustainability/rc_hexanediol_diacrylate.pdf
  2. Varkey, J. T., and V. N. Pillai. "Solid phase synthesis of hydrophobic peptides on 1,6-hexanediol diacrylate cross-linked polystyrene resin." Journal of Peptide Science 5.12(1999): 577-81.
  3. https://www.palmerholland.com/Assets/User/Documents/Product/40781/4988/MITM00481.pdf

Description

Sensitizaion occurred after accidental occupational exposure in an employee in the laboratory of a plastic paint factory.

Chemical Properties

Colorless transparent liquid

Uses

1,6-Hexandiol diacrylate is used in organic synthesis; common acrylic monomer in UV -cured inks, adhesives, coatings, photoresists, castings, artificial nails, etc.; monomer in dental composite materials.

Uses

1,6-Hexanediol diacrylate is used as a functional monomer for polymers. It acts as a cross linking agent between the molecular chains of polymers. Further, it is used in adhesives, sealants, alkyd coatings, elastomers, photopolymers, and inks for improved adhesion, hardness, abrasion and heat resistance.

General Description

Clear yellow liquid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Hexamethylene diacrylate is temperature sensitive . May react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release gaseous hydrogen. Can undergo very exothermic addition polymerization reactions. May undergo autoxidation upon exposure to the air to form explosive peroxides.

Fire Hazard

Hexamethylene diacrylate is probably combustible.

Flammability and Explosibility

Non flammable

Hexamethylene diacrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Hexamethylene diacrylate Suppliers

Suzhou Senfeida Chemical Material Co., Ltd.
Tel
512-83500002 13862111431
Fax
0512-66387035
Email
sales2@senfeida.com
Country
China
ProdList
299
Advantage
58
Hubei Xingyan New Material Technology Co., Ltd
Tel
13129948835
Email
2756772312@qq.com
Country
China
ProdList
5007
Advantage
58
Guangzhou Shanghe Chemical Technology Co., Ltd
Tel
13352869970
Email
272907493@qq.com
Country
China
ProdList
1138
Advantage
58
IGM RESINS
Tel
021-52080993 13917193189
Fax
021-5208 0930,010-62620366,020-32008365
Email
selene.wu@igmresins.com
Country
China
ProdList
89
Advantage
57
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1995
Advantage
65
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
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View Lastest Price from Hexamethylene diacrylate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Hexamethylene diacrylate 13048-33-4
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-07
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Hexamethylene diacrylate 13048-33-4
Price
US $0.00/KG
Min. Order
200KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-06
Hebei Weibang Biotechnology Co., Ltd
Product
Hexamethylene diacrylate 13048-33-4
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10mt
Release date
2024-11-06

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