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Hydroxypropyl acrylate

Product Name
Hydroxypropyl acrylate
CAS No.
25584-83-2
Chemical Name
Hydroxypropyl acrylate
Synonyms
Viscoat HPA;Hydroxypropylacrylat;1,2(or3)-propanediol;Hydroypropyl acrylate;Hydroxypropyl acrylate;2-HYDROXYPROYL ACRYLATE;propyleneglycolacrylate;2-HYDROXYPROPYL ACRYALTE;Hydroxypropyl acrylate,HPA;1,2-Propanediol, monoacrylate
CBNumber
CB1499179
Molecular Formula
C6H10O3
Formula Weight
130.14
MOL File
25584-83-2.mol
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Hydroxypropyl acrylate Property

Melting point:
-92°C
Boiling point:
77 °C5 mm Hg(lit.)
Density 
1.044 g/mL at 25 °C(lit.)
vapor density 
4.5 (vs air)
vapor pressure 
1Pa at 20℃
refractive index 
n20/D 1.445(lit.)
Flash point:
193 °F
form 
clear liquid
color 
Colorless to Almost colorless
Water Solubility 
The water solubility of hydroxypropyl acrylate is estimated to be 307g/L(25°C)
InChIKey
QZPSOSOOLFHYRR-UHFFFAOYSA-N
LogP
0.2 at 25℃
CAS DataBase Reference
25584-83-2(CAS DataBase Reference)
NIST Chemistry Reference
2-Hydroxypropyl acrylate(25584-83-2)
EPA Substance Registry System
Hydroxypropyl acrylate (25584-83-2)
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Safety

Hazard Codes 
T
Risk Statements 
23/24/25-34-43
Safety Statements 
26-36/37/39-45
RIDADR 
UN 1760 8/PG 3
WGK Germany 
1
RTECS 
UD3610000
TSCA 
TSCA listed
HazardClass 
8
PackingGroup 
II
HS Code 
29161290
Hazardous Substances Data
25584-83-2(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
370932
Product name
Hydroxypropyl acrylate, mixture of isomers
Purity
contains 200 ppm hydroquinone monomethyl ether as inhibitor, 95%
Packaging
1l
Price
$102
Updated
2024/03/01
Sigma-Aldrich
Product number
370932
Product name
Hydroxypropyl acrylate, mixture of isomers
Purity
contains 200 ppm hydroquinone monomethyl ether as inhibitor, 95%
Packaging
18l
Price
$738
Updated
2024/03/01
TCI Chemical
Product number
A0744
Product name
Hydroxypropyl Acrylate (mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl Acrylate)(stabilized with MEHQ)
Purity
>90.0%(GC)
Packaging
25mL
Price
$17
Updated
2024/03/01
TCI Chemical
Product number
A0744
Product name
Hydroxypropyl Acrylate (mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl Acrylate)(stabilized with MEHQ)
Purity
>90.0%(GC)
Packaging
500mL
Price
$50
Updated
2024/03/01
scipoly
Product number
M-143
Product name
2-Hydroxypropyl acrylate
Packaging
200g
Price
$33
Updated
2024/07/03
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Hydroxypropyl acrylate Chemical Properties,Usage,Production

Chemical Properties

Hydroxypropyl acrylate is a clear, colourless liquid, miscible with water and soluble in most organic solvents. It is a versatile difunctional acrylate monomer with a characteristic high reactivity. Hydroxypropyl acrylate is mainly used either as a co-monomer in the manufacture of polymers or as a chemical reactant in the manufacture of chemical intermediates. In the manufacture of polymers, hydroxypropyl acrylate can be co-polymerized with acrylic acid, acrylates, methacrylates, vinyl acetate, vinyl chloride, vinylidene chloride, styrene, butadiene, and the like. Co-reactants with hydroxypropyl acrylate include aromatic and aliphatic isocyanates, anhydrides, and epoxides. The polymers and chemical intermediates made with hydroxypropyl acrylate find applications in automotive top coatings, architectural coatings, photocure resins, and adhesives.

Uses

Hydroxypropyl acrylate is an acrylic monomer for use in UV inks, lacquers, adhesives, etc. [2-Hydroxy-1-propylacrylate (67%)+1-hydroxy-2-propylacrylate(33%).

Uses

Hydroxypropyl acrylates may be used for the synthesis of a number of acrylates. The presence of both vinyl and hydroxyl allows copolymerization of the acrylate with vinyl monomers as well as with di- or polyisocyanates, anhydrides, or epoxides.

General Description

A clear colorless liquid. Toxic by inhalation and skin absorption. Corrosive to tissue. Flash point 136°F. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently. Vapors heavier than air. Used to make plastics.

Air & Water Reactions

Flammable. Less dense than water and slightly soluble in water.

Reactivity Profile

Hydroxypropyl acrylate polymerizes readily in the presence of heat and light generating much heat; reacts with strong oxidants. REF [Handling Chemicals Safely, 1980. p. 235].

Health Hazard

Inhalation irritates nose and throat and causes coughing; lung injury may occur. Ingestion causes irritation and burning of mouth and stomach. Vapor irritates eyes. Contact with liquid causes severe burns of eyes and burns of skin.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

Flammability and Explosibility

Non flammable

Potential Exposure

Hydroxypropyl acrylate is a chemical monomer, manufactured and processed within closed systems. The primary routes of potential exposure to hydroxypropyl acrylate are skin contact and vapor inhalation. The lower vapor pressure (0.038 hPa at 25oC) helps reduce potential vapor inhalation exposure. In an industrial setting, ingestion is not an anticipated route of exposure. The primary use of hydroxypropyl acrylate in the production of polymeric coatings (used predominantly in the automotive industry) results in virtually no unreacted monomer in the finished coatings. The potential exposure to aerosols of hydroxypropyl acrylate is, therefore, highly unlikely.

Carcinogenicity

No carcinogenicity studies were identified for hydroxypropyl acrylate. As reviewed for Repeated Dose toxicity, no evidence of carcinogenicity was observed for the closely related, hydroxyethyl acrylate, following 18 months of inhalation exposure (Kociba et al., 1979; Rampy et al., 1978).

Solubility in water

The hydrolysis rate of hydroxypropyl acrylate, as with other acrylates, is pH dependent with little hydrolysis at acid and neutral pH and rapid hydrolysis in alkaline conditions. The hydrolysis halflives determined at pH 3, 7, and 11 were > 490 days, >230 days, and 0.056 days, respectively (Gonsior et al., 1997).

Hydroxypropyl acrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Hydroxypropyl acrylate Suppliers

Liaoning kelong Fine Chemical Co.,Ltd
Tel
18841966869
Email
carrie@kelongchem.com
Country
China
ProdList
24
Advantage
58
Changzhou Xintong Chemical Co., Ltd.
Tel
0519-82319070 18006146622
Email
493379833@qq.com
Country
China
ProdList
171
Advantage
58
Guangzhou Nalong Chemical Co.Ltd
Tel
13192879270; 13192879270
Email
1525037351@qq.com
Country
China
ProdList
3498
Advantage
58
Nantong Zhonghe Chemical New Materials Co., Ltd
Tel
13003551299 13003551299
Email
2369399482@qq.com
Country
China
ProdList
7566
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8415
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
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View Lastest Price from Hydroxypropyl acrylate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Hydroxypropyl acrylate 25584-83-2
Price
US $60.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-05-07
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
Hydroxypropyl acrylate 25584-83-2
Price
US $100.00-75.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000Ton
Release date
2024-08-12
Hebei Weibang Biotechnology Co., Ltd
Product
Hydroxypropyl acrylate 25584-83-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-01

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