Hydroxypropyl acrylate

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Hydroxypropyl acrylate

Product Name: Hydroxypropyl acrylate
CAS No.: 25584-83-2
Chemical Name: Hydroxypropyl acrylate
Synonyms: Viscoat HPA;Hydroxypropylacrylat;1,2(or3)-propanediol;Hydroypropyl acrylate;Hydroxypropyl acrylate;2-HYDROXYPROYL ACRYLATE;propyleneglycolacrylate;2-HYDROXYPROPYL ACRYALTE;Hydroxypropyl acrylate,HPA;1,2-Propanediol, monoacrylate
CBNumber: CB1499179
Molecular Formula: C6H10O3
Formula Weight: 130.14
MOL File: 25584-83-2.mol

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Hydroxypropyl acrylate Property

Melting point:: -92°C
Boiling point:: 77 °C5 mm Hg(lit.)
Density: 1.044 g/mL at 25 °C(lit.)
vapor density: 4.5 (vs air)
vapor pressure: 1Pa at 20℃
refractive index: n20/D 1.445(lit.)
Flash point:: 193 °F
form: clear liquid
color: Colorless to Almost colorless
Water Solubility: The water solubility of hydroxypropyl acrylate is estimated to be 307g/L(25°C)
InChIKey: QZPSOSOOLFHYRR-UHFFFAOYSA-N
LogP: 0.2 at 25℃
CAS DataBase Reference: 25584-83-2(CAS DataBase Reference)
NIST Chemistry Reference: 2-Hydroxypropyl acrylate(25584-83-2)
EPA Substance Registry System: Hydroxypropyl acrylate (25584-83-2)

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Safety

Hazard Codes: T
Risk Statements: 23/24/25-34-43
Safety Statements: 26-36/37/39-45
RIDADR: UN 1760 8/PG 3
WGK Germany: 1
RTECS: UD3610000
TSCA: TSCA listed
HazardClass: 8
PackingGroup: II
HS Code: 29161290
Hazardous Substances Data: 25584-83-2(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 370932
Product name: Hydroxypropyl acrylate, mixture of isomers
Purity: contains 200 ppm hydroquinone monomethyl ether as inhibitor, 95%
Packaging: 1l
Price: $102
Updated: 2024/03/01

Sigma-Aldrich

Product number: 370932
Product name: Hydroxypropyl acrylate, mixture of isomers
Purity: contains 200 ppm hydroquinone monomethyl ether as inhibitor, 95%
Packaging: 18l
Price: $738
Updated: 2024/03/01

TCI Chemical

Product number: A0744
Product name: Hydroxypropyl Acrylate (mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl Acrylate)(stabilized with MEHQ)
Purity: >90.0%(GC)
Packaging: 25mL
Price: $17
Updated: 2024/03/01

TCI Chemical

Product number: A0744
Product name: Hydroxypropyl Acrylate (mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl Acrylate)(stabilized with MEHQ)
Purity: >90.0%(GC)
Packaging: 500mL
Price: $50
Updated: 2024/03/01

scipoly

Product number: M-143
Product name: 2-Hydroxypropyl acrylate
Packaging: 200g
Price: $33
Updated: 2024/07/03

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Hydroxypropyl acrylate Chemical Properties,Usage,Production

Chemical Properties

Hydroxypropyl acrylate is a clear, colourless liquid, miscible with water and soluble in most organic solvents. It is a versatile difunctional acrylate monomer with a characteristic high reactivity. Hydroxypropyl acrylate is mainly used either as a co-monomer in the manufacture of polymers or as a chemical reactant in the manufacture of chemical intermediates. In the manufacture of polymers, hydroxypropyl acrylate can be co-polymerized with acrylic acid, acrylates, methacrylates, vinyl acetate, vinyl chloride, vinylidene chloride, styrene, butadiene, and the like. Co-reactants with hydroxypropyl acrylate include aromatic and aliphatic isocyanates, anhydrides, and epoxides. The polymers and chemical intermediates made with hydroxypropyl acrylate find applications in automotive top coatings, architectural coatings, photocure resins, and adhesives.

Uses

Hydroxypropyl acrylate is an acrylic monomer for use in UV inks, lacquers, adhesives, etc. [2-Hydroxy-1-propylacrylate (67%)+1-hydroxy-2-propylacrylate(33%).

Uses

Hydroxypropyl acrylates may be used for the synthesis of a number of acrylates. The presence of both vinyl and hydroxyl allows copolymerization of the acrylate with vinyl monomers as well as with di- or polyisocyanates, anhydrides, or epoxides.

General Description

A clear colorless liquid. Toxic by inhalation and skin absorption. Corrosive to tissue. Flash point 136°F. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently. Vapors heavier than air. Used to make plastics.

Air & Water Reactions

Flammable. Less dense than water and slightly soluble in water.

Reactivity Profile

Hydroxypropyl acrylate polymerizes readily in the presence of heat and light generating much heat; reacts with strong oxidants. REF [Handling Chemicals Safely, 1980. p. 235].

Health Hazard

Inhalation irritates nose and throat and causes coughing; lung injury may occur. Ingestion causes irritation and burning of mouth and stomach. Vapor irritates eyes. Contact with liquid causes severe burns of eyes and burns of skin.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

Flammability and Explosibility

Non flammable

Potential Exposure

Hydroxypropyl acrylate is a chemical monomer, manufactured and processed within closed systems. The primary routes of potential exposure to hydroxypropyl acrylate are skin contact and vapor inhalation. The lower vapor pressure (0.038 hPa at 25oC) helps reduce potential vapor inhalation exposure. In an industrial setting, ingestion is not an anticipated route of exposure. The primary use of hydroxypropyl acrylate in the production of polymeric coatings (used predominantly in the automotive industry) results in virtually no unreacted monomer in the finished coatings. The potential exposure to aerosols of hydroxypropyl acrylate is, therefore, highly unlikely.

Carcinogenicity

No carcinogenicity studies were identified for hydroxypropyl acrylate. As reviewed for Repeated Dose toxicity, no evidence of carcinogenicity was observed for the closely related, hydroxyethyl acrylate, following 18 months of inhalation exposure (Kociba et al., 1979; Rampy et al., 1978).

Solubility in water

The hydrolysis rate of hydroxypropyl acrylate, as with other acrylates, is pH dependent with little hydrolysis at acid and neutral pH and rapid hydrolysis in alkaline conditions. The hydrolysis halflives determined at pH 3, 7, and 11 were > 490 days, >230 days, and 0.056 days, respectively (Gonsior et al., 1997).

Hydroxypropyl acrylate Preparation Products And Raw materials

Raw materials

Hydroquinone Acrylic acid Propylene oxide

Preparation Products

water stabilizing agent YSS-93 Acrylic acid-hydroxypropyl acrylate copolymer Poly(acrylic acid)

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View Lastest Price from Hydroxypropyl acrylate manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD

Product: Hydroxypropyl acrylate 25584-83-2
Price: US $100.00-75.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5000Ton
Release date: 2024-08-12

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Hydroxypropyl acrylate 25584-83-2
Price: US $60.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 5000
Release date: 2024-05-07

Hebei Weibang Biotechnology Co., Ltd

Product: Hydroxypropyl acrylate 25584-83-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-01

25584-83-2, Hydroxypropyl acrylateRelated Search:

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2-Hydroxypropyl acrylate(mixture of isomers)

25584-83-2

H2CCHCO2C3H6OH

AcrylateCarbonyl Compounds

Acrylic Monomers

C6 to C7

Esters

Monomers