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6-Benzylaminopurine

Product Name
6-Benzylaminopurine
CAS No.
1214-39-7
Chemical Name
6-Benzylaminopurine
Synonyms
BA;6-BA;N-BUTYL ACRYLATE;BAP;6-BENZYLADENINE;aminopurine;BENZYLADENINE;6BAP;BUTYL 2-PROPENOATE;ACRYLIC ACID BUTYL ESTER
CBNumber
CB6740007
Molecular Formula
C12H11N5
Formula Weight
225.25
MOL File
1214-39-7.mol
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6-Benzylaminopurine Property

Melting point:
230-233 °C
Boiling point:
145 °C(lit.)
Density 
0.899 g/mL at 20 °C
vapor density 
>1 (vs air)
vapor pressure 
3.3 mm Hg ( 20 °C)
refractive index 
n20/D 1.418(lit.)
Flash point:
103 °F
storage temp. 
2-8°C
solubility 
H2O: soluble
form 
Liquid
pka
9.36±0.20(Predicted)
color 
White to very faint yellow
Odor
Characteristic acrylic.
Water Solubility 
Soluble in water, methanol and acetone. Slightly soluble in ethyl acetate and dichloromethane and toluene. Insoluble in n-hexane.
BRN 
19406
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
NWBJYWHLCVSVIJ-UHFFFAOYSA-N
LogP
1.570
CAS DataBase Reference
1214-39-7(CAS DataBase Reference)
NIST Chemistry Reference
1H-purin-6-amine, n-(phenylmethyl)-(1214-39-7)
EPA Substance Registry System
N-Benzyladenine (1214-39-7)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22-22
Safety Statements 
9-24/25-37/39-26-36-23
RIDADR 
UN 2348 3/PG 3
WGK Germany 
3
RTECS 
UD3150000
8
TSCA 
Yes
HS Code 
29335995
Hazardous Substances Data
1214-39-7(Hazardous Substances Data)
Toxicity
LD50 orl-rat: 2125 mg/kg TOIZAG 19,336,72
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
13151
Product name
6-Benzylaminopurine
Purity
ReagentPlus?, ≥99.0% (HPLC)
Packaging
1g
Price
$36.4
Updated
2024/03/01
Sigma-Aldrich
Product number
13151
Product name
6-Benzylaminopurine
Purity
ReagentPlus?, ≥99.0% (HPLC)
Packaging
5G
Price
$85.1
Updated
2024/03/01
Sigma-Aldrich
Product number
200241
Product name
6-Benzylaminopurine - CAS 1214-39-7 - Calbiochem
Purity
Plant cell division factor.
Packaging
1G
Price
$55.2
Updated
2024/03/01
Sigma-Aldrich
Product number
13151
Product name
6-Benzylaminopurine
Purity
ReagentPlus?, ≥99.0% (HPLC)
Packaging
25g
Price
$163
Updated
2024/03/01
TCI Chemical
Product number
B1088
Product name
N6-Benzyladenine
Purity
>99.0%(HPLC)(T)
Packaging
5g
Price
$60
Updated
2024/03/01
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6-Benzylaminopurine Chemical Properties,Usage,Production

Chemical Properties

Colorless to off-white or yellow powder. Corrosive. Insoluble in water, slightly soluble in ethanol, stable in acid and alkali.

Uses

6-Benzylaminopurine is a plant growth regulator that belongs to the class of first generation synthetic cytokinin used in agriculture.
6-Benzylaminopurine has been used:
to induce sprouting in plant materials.
in seed germination medium for culturing of seeds.
to modify Murashige and Skoog (MS) media for shoot initiation.
inhibitor of respiratory kinase in plants.
6-Benzylaminopurine, benzyl adenine (BAP) is a synthetic cytokinin which together with auxins elicits plant growth and development responses. BAP is a widely use cytokinin supplement to plant growth media such as Murashige and Skoog medium, Gamborg’s medium, and Chu’s N6 medium.

Application

6-Benzylaminopurine solution has been used as a component in the Murashige & Skoog medium (MS) for culturing mandarin explants and plantlets of Dendrocalamus asper (Schultes f.). It has also been used as a supplement in Nitsch and Nitsch medium (NN) of grapevine explants.

Preparation

synthesis of 6-benzylaminopurine: To 5g hypoxanthine, add 20mL SOCl2, 0.25g DMAP, 10gBTC dissolved in 20mL SOCl2. Heat and add BTC/SOCl2 dropwise. Reflux (refrigerant cooling) to complete dissolution, steam out SOCl2 (containing phosgene, which is used for recovery), evaporated (drained), cooled to room temperature to obtain a milky yellow solid (6-chloropurine and DMAP.Hcl). Directly add 4g benzylamine and 25g triethylamine to it, heat to 70~80 ℃, or microwave heating, until the 6-chloropurine reaction is complete (TLC monitoring), add ethanol, the solid filtered out is washed with ethanol, and dried to obtain 7 g of product 6-benzylaminopurine with a brown color.
Preparation and biological activity of 6-benzylaminopurine derivatives in plants and human cancer cells

Definition

ChEBI: 6-Benzylaminopurine is a member of the class of 6-aminopurines that is adenine in which one of the hydrogens of the amino group is replaced by a benzyl group. It has a role as a plant metabolite and a cytokinin. It derives from an adenine.

General Description

6-Benzylaminopurine is a plant growth regulator that belongs to the class of first generation synthetic cytokinin used in agriculture commodities.

Health Hazard

6-benzylaminopurine (6-BA) is widely used in agriculture and horticulture as plant growth regulator. Its excessive use may pose a potential risk to both environment and human health, which is causing great concern. Vapor is irritating when breathed at high concentrations. Contact with liquid causes irritation of skin and burning of eyes; Vapors cause a slight smarting of the eyes or respiratory system if present in high concentrations; If spilled on clothing and allowed to remain, may cause smarting and reddening of the skin.

Agricultural Uses

6-Benzylaminopurine is a plant growth promoter, is the first applied synthetic cytokinin, mainlyused as a broad- spectrum plant growth regulator. It can be used inagriculture, horticulture, for plants at different stages, from germination to harvest. It enhance the shape of apples and to increase the fruit set in pears. It increases the yield of pistachios and tomatoes. Not listed for use in EU countries. Registered for use in the U.S.

Trade name

ABG® 3034; ACCEL®; AGTROL®; 6-BA®; BA® (growth stimulant); CHRYSAL BVB®; EXILIS®; PERLAN®; PROMALIN®; SD® 4901; SQ® 4609

Safety Profile

Moderately toxic by ingestion andskin contact. Human mutation data reported. Whenheated to decomposition it emits toxic vapors of NOx.

Potential Exposure

A polyamine plant growth regulator used to lengthen and enhance the shape of apples and to increase the fruit set in pears. It increases the yield of pistachios and tomatoes. Not listed for use in the EU countries.

Shipping

UN3259 Amines, solid, corrosive, n.o.s, or Polyamines, solid, corrosive, n.o.s., Hazard class: 8; Labels: 8—Corrosive material, Technical Name Required.

Purification Methods

It is purified by recrystallisation from aqueous EtOH. It has at 207 and 270nm (H2O), 268 nm max (pH 6), 274nm (0.1 N HCl) and 275nm (0.1 N NaOH). [Daly J Org Chem 21 1553 1956, Bullock et al. J Am Chem Soc 78 3693 1956, Beilstein 26 III/IV 3575.]

Incompatibilities

May react with strong oxidizers such as chlorates, peroxides, nitrates, etc. May release heat on contact with water. Solid and corrosive amines are chemical bases. Neutralize acids to form salts plus water in exothermic reactions. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate flammable gaseous hydrogen in combination with strong reducing agents, such as hydrides.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

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6-Benzylaminopurine Suppliers

Zhejiang Dapeng Pharmaceutical Co., Ltd.
Tel
0086-576-85588223 13625762091
Fax
576-85588108
Email
dapeng@dppharm.com
Country
China
ProdList
1
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58
Hefei Bomei Biotechnology Co., Ltd.
Tel
13856598764
Email
531626407@qq.com
Country
China
ProdList
3007
Advantage
58
Hubei kangen Pharmaceutical Chemical Co., Ltd
Tel
15337215803 15337215803
Fax
027-89771658
Email
3357312443@qq.com
Country
China
ProdList
232
Advantage
56
Chongqing Yuanyuanxiang Technology Development Co. LTD
Tel
023-55703781 15320534687
Fax
023-55703781
Email
2022434087@qq.com
Country
China
ProdList
4100
Advantage
58
SHANGHAI YUANJU BIO-TECH CO., LTD
Tel
62750277 15618798178
Email
362310313@qq.com
Country
China
ProdList
469
Advantage
58
Changzhou Siyou Chemical Technology Co., Ltd
Tel
13706143322
Email
178601697@qq.com
Country
China
ProdList
28
Advantage
58
Shanghai Boyle Chemical Co., Ltd.
Tel
021-50182298 021-50180596
Fax
+86-21-57758967
Email
sales@boylechem.com
Country
China
ProdList
2208
Advantage
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J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
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View Lastest Price from 6-Benzylaminopurine manufacturers

Hebei Longbang Technology Co., Ltd
Product
Benzyladenine 1214-39-7
Price
US $6.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20TONS
Release date
2024-05-28
HebeiShuoshengImportandExportco.,Ltd
Product
Benzyladenine 1214-39-7
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000KG/Month
Release date
2024-08-06
Hebei Zhuanglai Chemical Trading Co Ltd
Product
6-Benzylaminopurine 1214-39-7
Price
US $45.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 tons
Release date
2024-12-04

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