Methyl 2-bromo-6-methylbenzoate
- Product Name
- Methyl 2-bromo-6-methylbenzoate
- CAS No.
- 99548-56-8
- Chemical Name
- Methyl 2-bromo-6-methylbenzoate
- Synonyms
- Methyl 2-bromo-6-methylbenzoate;2-BROMO-6-METHYLBENZOIC ACID METHYL ESTER;Benzoic acid, 2-broMo-6-Methyl-, Methyl ester;Methyl 6-bromo-o-toluate, 3-Bromo-2-(methoxycarbonyl)toluene
- CBNumber
- CB11484363
- Molecular Formula
- C9H9BrO2
- Formula Weight
- 229.07
- MOL File
- 99548-56-8.mol
Methyl 2-bromo-6-methylbenzoate Property
- Boiling point:
- 141 °C(Press: 21 Torr)
- Density
- 1.433±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- Colorless to light yellow Liquid
- InChI
- InChI=1S/C9H9BrO2/c1-6-4-3-5-7(10)8(6)9(11)12-2/h3-5H,1-2H3
- InChIKey
- DDJSNWUTQDNGIZ-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=C(C)C=CC=C1Br
Safety
- HS Code
- 2916399090
N-Bromosuccinimide Price
- Product number
- M295843
- Product name
- Methyl2-Bromo-6-methylbenzoate
- Packaging
- 5g
- Price
- $145
- Updated
- 2021/12/16
- Product number
- CS-W004694
- Product name
- Methyl2-bromo-6-methylbenzoate
- Purity
- ≥98.0%
- Packaging
- 10g
- Price
- $69
- Updated
- 2021/12/16
- Product number
- FB66994
- Product name
- 2-Bromo-6-methylbenzoic acid methyl ester
- Packaging
- 10g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- CS-W004694
- Product name
- Methyl2-bromo-6-methylbenzoate
- Purity
- ≥98.0%
- Packaging
- 25g
- Price
- $123
- Updated
- 2021/12/16
- Product number
- FB66994
- Product name
- 2-Bromo-6-methylbenzoic acid methyl ester
- Packaging
- 25g
- Price
- $125
- Updated
- 2021/12/16
Methyl 2-bromo-6-methylbenzoate Chemical Properties,Usage,Production
Synthesis
67-56-1
90259-31-7
99548-56-8
To a dichloromethane (50 mL) suspension of 2-bromo-6-methylbenzoic acid (5.05 g, 23.48 mmol) was sequentially added oxalyl chloride (2.67 mg, 30.5 mmol) and N,N-dimethylformamide (DMF, 2 drops) at room temperature. The reaction mixture was stirred at room temperature for 2 hours and then concentrated under reduced pressure to remove the solvent. Methanol (10 mL) was added to the resulting residue and stirring was continued overnight. Upon completion of the reaction, the reaction mixture was concentrated under reduced pressure. To the concentrated residue was added saturated aqueous sodium bicarbonate (20 mL) and the mixture was extracted with ethyl acetate. The organic layer was dried with anhydrous magnesium sulfate and the solvent was removed under reduced pressure. The resulting methyl 2-bromo-6-methylbenzoate (5.04 g, 94% yield) was used directly in the subsequent reaction without further purification.
References
[1] Patent: EP2455370, 2012, A1. Location in patent: Page/Page column 101
[2] Patent: WO2007/47646, 2007, A2. Location in patent: Page/Page column 52
Methyl 2-bromo-6-methylbenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Methyl 2-bromo-6-methylbenzoate manufacturers
- Product
- Methyl 2-bromo-6-methylbenzoate 99548-56-8
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-11
- Product
- Methyl 2-bromo-6-methylbenzoate 99548-56-8
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09
- Product
- Methyl 2-bromo-6-methylbenzoate 99548-56-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-12