Reaction
ChemicalBook > CAS DataBase List > (S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE

(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE

Reaction
Product Name
(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE
CAS No.
71423-54-6
Chemical Name
(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE
Synonyms
(S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(p;(S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(...;(S,S)-(+)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane(1,5-cyclooctadiene)rhodium(I) terafluoroborate;(1S,2S)-()-Bis[(2-methoxyphenyl)phenylphosphino]ethane -(1,5-cyclooctadiene) rhodium(I) tetrafluorobarate;(S,S)-(+)-1,2-Bis[(o-Methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate;(S,S)-(+)-1,2-Bis[(o-Methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,95%;(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE;[(S,S)-1,2-Ethanediyl-bis-[(2-methoxyphenyl)-phenylphosphine]]-(1,5-cyclooctadiene)-rhodium(Ⅰ)]-tetrafluoroborate;(S,S)-(+)-1,2-Bis[(o-Methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodiuM(I)tetrafluoroborate,Min.95%;(S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95%
CBNumber
CB11564694
Molecular Formula
C36H38BF4O2P2Rh
Formula Weight
754.35
MOL File
71423-54-6.mol
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(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE Property

form 
Powder
color 
orange
Sensitive 
air sensitive
CAS DataBase Reference
71423-54-6
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Safety

Safety Statements 
22-24/25
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H332Harmful if inhaled

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P322Specific measures (see …on this label).

P330Rinse mouth.

P363Wash contaminated clothing before reuse.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Strem Chemicals
Product number
45-0226
Product name
(S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95%
Packaging
100mg
Price
$139
Updated
2024/03/01
Strem Chemicals
Product number
45-0226
Product name
(S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95%
Packaging
500mg
Price
$554
Updated
2024/03/01
Chemenu
Product number
CM102889
Product name
(S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate
Purity
95%
Packaging
500mg
Price
$1152
Updated
2021/12/16
Chemenu
Product number
CM102889
Product name
(S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate
Purity
95%
Packaging
1g
Price
$1728
Updated
2021/12/16
Arctom
Product number
AS591136
Product name
(S,S)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate
Packaging
50mg
Price
$147
Updated
2021/12/16
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(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE Chemical Properties,Usage,Production

Reaction

  1. Highly reactive enantioselective catalyst for the asymmetric hydrogenation of various substituted dehydroalanines to Nprotected aminoacids. Also, catalyst is very effective in the asymmetric reduction of pentapetides that contain unsaturated Phe or Tyr linkages to enkephalin, a brain peptide hormone.
  2. Efficient catalyst for the asymmetric reduction of enol acetates to esters.
  3. Catalyst used to prepare chiral 2-substituted succinic acid derivatives.

(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE Suppliers

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71423-54-6, (S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATERelated Search:

(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE BIS(2-METHOXYPHENYL)PHENYLPHOSPHINE

  • (S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE
  • (S,S)-(+)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane(1,5-cyclooctadiene)rhodium(I) terafluoroborate
  • (S,S)-(+)-1,2-Bis[(o-Methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodiuM(I)tetrafluoroborate,Min.95%
  • (S,S)-(+)-1,2-Bis[(o-Methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,95%
  • [(S,S)-1,2-Ethanediyl-bis-[(2-methoxyphenyl)-phenylphosphine]]-(1,5-cyclooctadiene)-rhodium(Ⅰ)]-tetrafluoroborate
  • (S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)<br />rhodium(I) tetrafluoroborate, min. 95%
  • (S,S)-(+)-1,2-Bis[(o-Methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate
  • (1S,2S)-()-Bis[(2-methoxyphenyl)phenylphosphino]ethane -(1,5-cyclooctadiene) rhodium(I) tetrafluorobarate
  • (S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(p
  • (1Z,5Z)-cycloocta-1,5-diene,(S)-(2-methoxyphenyl)-[2-[(2-methoxyphenyl)-phenylphosphanyl]ethyl]-phenylphosphane,rhodium,tetrafluoroborate
  • (S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE ISO 9001：2015 REACH
  • (S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(...
  • 71423-54-6
  • C28H28O2P2C8H12BF4Rh
  • Rh
  • organometallic complex