3-BROMO-2-NITROTOLUENE

Product Name: 3-BROMO-2-NITROTOLUENE
CAS No.: 52414-97-8
Chemical Name: 3-BROMO-2-NITROTOLUENE
Synonyms: 1-BroMo-3-Methyl-2-nitrobenzene;3-bromo-2-nitrobenzene;3-BROMO-2-NITROTOLUENE;2-Nitro-3-Bromo Toluene;3-Bromo-2-nitrotoluene,98%;3-BROMO-2-NITROTOLUENE 98%;3-BROMO-2-NITROTOLUENE,97% min;6-Bromo-2-methyl-1-nitrobenzene;Benzene, 1-bromo-3-methyl-2-nitro-
CBNumber: CB1169663
Molecular Formula: C7H6BrNO2
Formula Weight: 216.03
MOL File: 52414-97-8.mol

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3-BROMO-2-NITROTOLUENE Property

Melting point:: 25-29 °C (lit.)
Boiling point:: 267℃
Density: 1.612 g/mL at 25 °C (lit.)
refractive index: 1.6120 (estimate)
Flash point:: >230 °F
storage temp.: Sealed in dry,Room Temperature
Specific Gravity: 1.612
Appearance: Colorless to off-white <26.8°C Solid,>29°C Liquid
CAS DataBase Reference: 52414-97-8(CAS DataBase Reference)

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Safety

Hazard Codes: Xn
Risk Statements: 36/37/38-20/21/22
Safety Statements: 36/37/39-26-22
WGK Germany: 3
HS Code: 29049090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P322Specific measures (see …on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 545732
Product name: 3-Bromo-2-nitrotoluene
Purity: 97%
Packaging: 5g
Price: $135
Updated: 2023/06/20

Sigma-Aldrich

Product number: 545732
Product name: 3-Bromo-2-nitrotoluene
Purity: 97%
Packaging: 25g
Price: $418
Updated: 2022/05/15

TRC

Product number: B750243
Product name: 3-Bromo-2-nitrotoluene
Packaging: 100mg
Price: $60
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK189688
Product name: 3-Bromo-2-nitrotoluene
Purity: 98%
Packaging: 1g
Price: $60
Updated: 2021/12/16

Apolloscientific

Product number: OR930058
Product name: 3-Bromo-2-nitrotoluene
Purity: 97+%
Packaging: 5g
Price: $89
Updated: 2021/12/16

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3-BROMO-2-NITROTOLUENE Chemical Properties,Usage,Production

Chemical Properties

yellow crystalline low melting mass

Synthesis

540-80-7

601-87-6

52414-97-8

Example 1 7-Bromo-2H-indazole Step 1 3-Bromo-2-nitrotoluene (Scheme 1; IC) - Copper (II) bromide (3.52 g, 15.7 mmol) was dissolved in 20 mL of anhydrous acetonitrile, under nitrogen protection, and heated to 65°C. Subsequently, tert-butyl nitrite (2.35 mL, 2.03 g, 19.7 mmol) was added all at once. 3-Methyl-2-nitroaniline (LB; 2.00 g, 13.1 mmol; J. Org. Chem. 1976, 41, 3357) was dissolved in 15 mL of acetonitrile and slowly added dropwise to the above solution, maintaining gentle reflux. After dropwise addition, the reaction was continued under mild reflux conditions for 15 min. After the reaction mixture was cooled to room temperature, it was separated by extraction with 6N hydrochloric acid solution (150 mL) and ether (150 mL). The ether phase was collected, washed with saturated brine and dried over anhydrous magnesium sulfate. The solvent was removed by concentration under reduced pressure to give 2.76 g of crude product. Purification by silica gel column chromatography with 10% acetone/hexane as eluent gave 1.62 g (57% yield) of the target product 1c as a light yellow-green liquid.

References

[1] Patent: WO2005/16892, 2005, A1. Location in patent: Page/Page column 68

3-BROMO-2-NITROTOLUENE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BROMO-2-NITROTOLUENE Suppliers

Belgium 1 China 96 Germany 2 India 3 Slovakia 1 Switzerland 1 United Kingdom 10 United States 15 Global 129

J & K SCIENTIFIC LTD.

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View Lastest Price from 3-BROMO-2-NITROTOLUENE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: 3-BROMO-2-NITROTOLUENE 52414-97-8
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Career Henan Chemical Co

Product: 3-BROMO-2-NITROTOLUENE 52414-97-8
Price: US $1.00/g
Min. Order: 100g
Purity: 98%min
Supply Ability: G/KG/T
Release date: 2019-12-23

52414-97-8, 3-BROMO-2-NITROTOLUENERelated Search:

6-BROMO-2-NITROTOLUENE,2-BROMO-6-NITROTOLUENE,2-BROMO-6-NITROTOLUENE,2-NITRO-6-BROMOTOLUENE,2-BROMO-6-NITROTOLUENE 98+% 2-BROMO-3-NITROTOLUENE 3-BROMO-2-NITROTOLUENE 4-BROMO-2-METHYL-1-NITROBENZENE 3-Nitrobenzyl bromide 4-BROMO-6-NITROTOLUENE,4-BROMO-2-NITROTOLUENE,4-Bromo-2-nitrotoluene, 99+%,4-BROMO-2-NITROTOLUENE 99% 4-Nitrobenzyl bromide 2,6-DIBROMO-4-NITROTOLUENE 2-BROMO-4-NITROTOLUENE a-Bromo-2-nitrotoluene,α-Bromo-2-nitrotoluene,à-bromo-2-nitrotoluene,A-BROMO-O-NITROTOLUENE,ALPHA-BROMO-O-NITROTOLUENE,ALPHA-BROMO-2-NITROTOLUENE 4-BROMO-3-NITROTOLUENE,4-BROMO-3-NITROTOLUENE 99%,4-BROMO-3-NITROTOLUENE, TECH., 90% 5-BROMO-2-NITROTOLUENE,2-BROMO-5-NITROTOLUENE 3-BROMO-5-NITROTOLUENE (5-BROMO-3-METHYL-1-NITROBENZENE),3-BROMO-5-NITROTOLUENE 2-Nitrotoluene 3-BROMO-5-HYDROXY-2,6-DINITRO-BENZOIC ACID 3-bromo-2-nitrobenzaldehyde 3-BROMO-2-NITRO-5-AMINOBENZOIC ACID 3-BROMO-5-METHOXY-2,6-DINITRO-BENZOIC ACID METHYL ESTER

3-BROMO-2-NITROTOLUENE 98%

3-BROMO-2-NITROTOLUENE

3-bromo-2-nitrobenzene

3-Bromo-2-nitrotoluene,98%

1-BroMo-3-Methyl-2-nitrobenzene

6-Bromo-2-methyl-1-nitrobenzene

2-Nitro-3-Bromo Toluene

Benzene, 1-bromo-3-methyl-2-nitro-

3-BROMO-2-NITROTOLUENE,97% min

52414-97-8

CH3C6H3NO2Br

C7H6BrNO2

Nitro Compounds

Organic Building Blocks

Nitrogen Compounds

Building Blocks

Nitro Compounds

Nitrogen Compounds

Organic Building Blocks

Aromatic Hydrocarbons (substituted) & Derivatives