DIETHYL ISOCYANOMETHYLPHOSPHONATE

Product Name: DIETHYL ISOCYANOMETHYLPHOSPHONATE
CAS No.: 41003-94-5
Chemical Name: DIETHYL ISOCYANOMETHYLPHOSPHONATE
Synonyms: Diethyl (isocyanomethyl);Diethyleisocyanomethylphosphonate;DIETHYL ISOCYANOMETHYLPHOSPHONATE;Diethoxyphosphinylmethyl isocyanide;Diethyl P-(isocyanomethyl)phosphonate;Diethyl isocyanomethylphosphonate 97%;Diethyl isocyanomethylphosphonate,97%;[(Diethoxyphosphinyl)methyl] isocyanide;ISOCYANOMETHYL-PHOSPHONIC ACID DIETHYL ESTER;1-[ethoxy(isocyanomethyl)phosphoryl]oxyethane
CBNumber: CB1169704
Molecular Formula: C6H12NO3P
Formula Weight: 177.14
MOL File: 41003-94-5.mol

More

Less

DIETHYL ISOCYANOMETHYLPHOSPHONATE Property

Boiling point:: 84-87 °C0.1 mm Hg(lit.)
Density: 1.105 g/mL at 25 °C(lit.)
refractive index: n20/D 1.433(lit.)
Flash point:: >230 °F
storage temp.: 2-8°C
form: Liquid
color: Clear colorless to yellow
BRN: 4674920
InChI: 1S/C6H12NO3P/c1-4-9-11(8,6-7-3)10-5-2/h4-6H2,1-2H3
InChIKey: ICURVXBGGDVHDT-UHFFFAOYSA-N
SMILES: CCOP(=O)(C[N+]#[C-])OCC
CAS DataBase Reference: 41003-94-5

More

Less

Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-20/21/22
Safety Statements: 26-36
RIDADR: UN2206
WGK Germany: 3
F: 8-9
HazardClass: 6.1
HS Code: 29319090
Storage Class: 10 - Combustible liquids
Hazard Classifications: Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 359866
Product name: Diethyl isocyanomethylphosphonate
Purity: 97%
Packaging: 1ml
Price: $283
Updated: 2023/06/20

American Custom Chemicals Corporation

Product number: CHM0156628
Product name: DIETHYL ISOCYANOMETHYLPHOSPHONATE
Purity: 95.00%
Packaging: 1ML
Price: $701.66
Updated: 2021/12/16

More

Less

DIETHYL ISOCYANOMETHYLPHOSPHONATE Chemical Properties,Usage,Production

Description

Diethyl isocyanoMethylphosphonate is a reagent for the elongation of aldehydes and ketones with a one-carbon unit; connective reagent; N,P-acetals; reagent for the conversion of nitroalkenes into 2-pyrrolephosphonates.

Chemical Properties

Clear colorless to yellow liquid

Uses

Reactant for:

Copper-catalyzed cycloaddition reactions
Preparation of orally bioavailable diamide prodrugs that lower glucose in diabetic animals through inhibition of fructose-1,6-bisphosphatase
Synthesis of sterol analogs as antifungal agents against plant pathogens
Asymmetric synthesis of steroidal 2,5-diketopiperazines prepared via isocyanide chemistry based on stereoselective Ugi four component condensation and subsequent cyclocondensation reactions
The Passerini reaction

reaction suitability

reaction type: C-C Bond Formation

Synthesis

Diethyl isocyanoMethylphosphonate is prepared by dehydration of N-(diethoxyphosphorylmethyl)formamide.

storage

Stored for long periods of time at 0 °C or below

DIETHYL ISOCYANOMETHYLPHOSPHONATE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

DIETHYL ISOCYANOMETHYLPHOSPHONATE Suppliers

Belgium 1 China 18 Germany 3 India 1 Switzerland 1 United Kingdom 1 United States 5 Global 30

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44802
Advantage: 61

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14435
Advantage: 57

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17770
Advantage: 75

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22514
Advantage: 55

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51395
Advantage: 80

Shenzhen Polymeri Biochemical Technology Co., Ltd.

Tel: +86-400-002-6226 +86-13028896684;
Email: sales@rrkchem.com
Country: China
ProdList: 57422
Advantage: 58

CONIER CHEM AND PHARMA LIMITED

Tel: +8618523575427
Email: sales@conier.com
Country: China
ProdList: 49977
Advantage: 58

Shanghai Xiushi Biomedical Co., LTD

Tel: 15002184385 15021598081 15002184385
Email: product001@xiushipharm.com
Country: China
ProdList: 4664
Advantage: 58

41003-94-5, DIETHYL ISOCYANOMETHYLPHOSPHONATERelated Search:

DIETHYL PHOSPHATE METHYL ISOCYANIDE DIETHYL ISOCYANOMETHYLPHOSPHONATE (Aminomethyl)phosphonic acid

[(Diethoxyphosphinyl)methyl] isocyanide

Diethoxyphosphinylmethyl isocyanide

Diethyl isocyanomethylphosphonate,97%

DIETHYL ISOCYANOMETHYLPHOSPHONATE

ISOCYANOMETHYL-PHOSPHONIC ACID DIETHYL ESTER

ISOCYANOMETHYLPHOSPHONONIC ACID DIETHYL ESTER

Diethyl isocyanomethylphosphonate 97%

Diethyl (isocyanomethyl)

Diethyleisocyanomethylphosphonate

1-[ethoxy(isocyanomethyl)phosphoryl]oxyethane

Diethyl P-(isocyanomethyl)phosphonate

41003-94-5

CNCH2POOC2H52

Horner-Wadsworth-Emmons Reagents

Olefination

Synthetic Reagents

C-C Bond Formation