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Boc-D-Phenylglycine

Product Name
Boc-D-Phenylglycine
CAS No.
33125-05-2
Chemical Name
Boc-D-Phenylglycine
Synonyms
BOC-D-PHG-OH;BOC-PHG-OH;(R)-2-((tert-butoxycarbonyl)aMino)-2-phenylacetic acid;FS000066;BOC-L-PHG;ST5210539;BOC-L-PHG-OH;Boc-D-PhenyL;BOC-PHENYLGLYCINE;BOC-(PHENYL)GLY-OH
CBNumber
CB1176908
Molecular Formula
C13H17NO4
Formula Weight
251.28
MOL File
33125-05-2.mol
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Boc-D-Phenylglycine Property

Melting point:
88-91 °C
alpha 
-142 º (c=1% in ethanol)
Boiling point:
407.2±38.0 °C(Predicted)
Density 
1.182±0.06 g/cm3(Predicted)
refractive index 
-140 ° (C=1, EtOH)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
DMSO, Methanol
pka
3.51±0.10(Predicted)
form 
Crystalline Powder
color 
White
optical activity
[α]20/D 141.0±5.0°, c = 1% in ethanol
Water Solubility 
Insoluble in water. Slightly soluble in DMSO and methanol.
BRN 
3033982
CAS DataBase Reference
33125-05-2(CAS DataBase Reference)
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Safety

Safety Statements 
24/25
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29242990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.53101-M
Product name
Boc-D-Phg-OH
Purity
Novabiochem?
Packaging
5G
Price
$196
Updated
2024/03/01
Sigma-Aldrich
Product number
8.53101-M
Product name
Boc-D-Phg-OH
Purity
Novabiochem?
Packaging
25g
Price
$920
Updated
2024/03/01
Sigma-Aldrich
Product number
15487
Product name
Boc-D-Phg-OH
Purity
≥99.0% (TLC)
Packaging
1g
Price
$65
Updated
2023/06/20
Sigma-Aldrich
Product number
15487
Product name
Boc-D-Phg-OH
Purity
≥99.0% (TLC)
Packaging
5g
Price
$135
Updated
2023/06/20
TCI Chemical
Product number
B3230
Product name
N-(tert-Butoxycarbonyl)-D-2-phenylglycine
Purity
>98.0%(T)
Packaging
1g
Price
$17
Updated
2024/03/01
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Boc-D-Phenylglycine Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

It is a reagent of choice for assignment of absolute configuration of chiral primary amines by 1H NMR, giving better results than Mosher's acid ((R)-(+)-?-Methoxy-?-(trifluoromethyl)-phenyl-acetic acid. αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is D-(+)-2-Phenylglycine with Boc protecting group. (αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is used as part of a catalyst combination to catalyze regioselective [4 + 2] cycloadditions of β-substituted cyclic enones and polyconjugated malononitriles. It can also be used to catalyze stereoselective preparation of polyfunctional nitrocyclohexene carboxaldehydes.

Boc-D-Phenylglycine Preparation Products And Raw materials

Raw materials

Preparation Products

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Boc-D-Phenylglycine Suppliers

NeoMPS SA
Tel
--
Fax
--
Email
neo@neomps.com
Country
France
ProdList
2083
Advantage
71
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View Lastest Price from Boc-D-Phenylglycine manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Boc-D-Phenylglycine 33125-05-2
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
98%min
Supply Ability
500kgs
Release date
2021-09-23
Sichuan HongRi Pharma-Tech Co.,Ltd
Product
Boc-D-Phg-OH 33125-05-2
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1T+
Release date
2023-10-11
Henan Aochuang Chemical Co.,Ltd.
Product
Boc-D-Phenylglycine 33125-05-2
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-12

33125-05-2, Boc-D-PhenylglycineRelated Search:


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  • N-(tert-Butoxycarbonyl)-D-2-phenylglycine
  • N-Boc-D-2-phenylglycine
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  • N-Boc-D-phenylglycine (Boc-D-Phg-OH)
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  • BOC-L-ALPHA-PHENYLGLYCINE
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  • Benzeneacetic acid, a-[[(1,1-diMethylethoxy)carbonyl]aMino]-,(aR)-
  • Boc-D-Phg-OH, >=99.0% (TLC)
  • BOC-PHG-OH, >=99.0% (TLC)
  • 2-[(2-methylpropan-2-yl)oxycarbonylamino]-2-phenylacetic acid
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  • 2-[(tert-butoxy-oxomethyl)amino]-2-phenylacetic acid
  • FS000066
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  • Boc-D-phenylglycine≥ 99% (HPLC)
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  • N-BOC-L-PHENYLGLYCINE
  • N-ALPHA-T-BOC-L-PHENYLGLYCINE
  • N-ALPHA-(T-BUTYLOXYCARBONYL)-L-PHENYLGLYCINE
  • N-ALPHA-T-BUTOXYCARBONYL-T-PHENYLGLYCINE
  • N-ALPHA-TERT-BUTYLOXYCARBONYL-L-PHENYLGLYCINE
  • RARECHEM EM WB 0179
  • (S)-TERT-BUTOXYCARBONYLAMINO-PHENYL-ACETIC ACID
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  • Boc-D-α-phenylglycine
  • (2R)-2-[(2-methylpropan-2-yl)oxycarbonylamino]-2-phenylaceticaci
  • Boc-D-Phenylglycine USP/EP/BP
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  • (R)-N-tert-butoxycarbonyl-2-phenylglycine
  • 33125-05-2