4-METHYL-2,2'-BIPYRIDINE
Uses- Product Name
- 4-METHYL-2,2'-BIPYRIDINE
- CAS No.
- 56100-19-7
- Chemical Name
- 4-METHYL-2,2'-BIPYRIDINE
- Synonyms
- 4-methyl-2,2'-dipyridyl;4-METHYL-2,2'-BIPYRIDINE;4-Methyl-2,2'-bipyridine;2,2'-bipyridine, 4-methyl-;4-Methyl-[2,2']bipyridinyl;4-methyl-2-pyridin-2-ylpyridine;2-(4-methylpyridin-2-yl)pyridine
- CBNumber
- CB1186446
- Molecular Formula
- C11H10N2
- Formula Weight
- 170.21
- MOL File
- 56100-19-7.mol
4-METHYL-2,2'-BIPYRIDINE Property
- Melting point:
- 62-64 °C(Solv: ligroine (8032-32-4))
- Boiling point:
- 296.6±25.0 °C(Predicted)
- Density
- 1.081±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 4.73±0.18(Predicted)
- Appearance
- White to off-white Solid
- InChI
- InChI=1S/C11H10N2/c1-9-5-7-13-11(8-9)10-4-2-3-6-12-10/h2-8H,1H3
- InChIKey
- OHSRAWAUPZWNKY-UHFFFAOYSA-N
- SMILES
- C1(C2=NC=CC=C2)=NC=CC(C)=C1
Safety
- HS Code
- 9999999999
N-Bromosuccinimide Price
- Product number
- 11145
- Product name
- 4-Methyl-2,2'-bipyridine
- Purity
- 97%
- Packaging
- 1g
- Price
- $355
- Updated
- 2021/12/16
- Product number
- 106102
- Product name
- 4-Methyl-[2,2']bipyridinyl
- Purity
- 97%
- Packaging
- 1g
- Price
- $385
- Updated
- 2021/12/16
- Product number
- 11145
- Product name
- 4-Methyl-2,2'-bipyridine
- Purity
- 97%
- Packaging
- 2g
- Price
- $490
- Updated
- 2021/12/16
- Product number
- 106102
- Product name
- 4-Methyl-[2,2']bipyridinyl
- Purity
- 97%
- Packaging
- 2g
- Price
- $500
- Updated
- 2021/12/16
- Product number
- CHM0075432
- Product name
- 4-METHYL-[2,2']BIPYRIDINYL
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $958.07
- Updated
- 2021/12/16
4-METHYL-2,2'-BIPYRIDINE Chemical Properties,Usage,Production
Uses
4-Methyl-2,2'-bipyridine is a useful compound for research.
Synthesis
2732-35-6
56100-19-7
Example 2 Synthesis of 4-methyl-2-(2'-pyridinyl)pyridine: Tetrahydrofuran (10 ml) and isopropylmagnesium chloride (2.0 M, 7.7 ml, 15.5 mmol) were added to a 50 ml flask under nitrogen protection. Subsequently, a solution prepared from 2-bromopyridine (2.45 g, 15.5 mmol) dissolved in tetrahydrofuran (3 ml) was added slowly and dropwise over 10 min. The reaction mixture was stirred for 1 hour and then a solution prepared from 4-methyl-2-benzenesulfonylpyridine (3.00 g, 12.9 mmol) dissolved in tetrahydrofuran (5 ml) was added dropwise over 10 minutes. The reaction mixture was continued to be stirred at room temperature for 5 h. Isopropanol (1 ml) was added at the termination of the reaction. The reaction mixture was poured into water and extracted with ethyl acetate (15 ml x 2). The organic phases were combined, concentrated and purified by silica gel column chromatography to afford the target product 4-methyl-2,2'-bipyridine (1.51 g, 89% yield, based on 4-methyl-2-phenylsulfonylpyridine) as a white solid. The product was characterized by 1H-NMR (CDCl3): δ 2.36 (s, 3H), 7.06 (d, 1H, J = 5.0 Hz), 7.20-7.25 (m, 1H), 7.69-7.74 (m, 1H), 8.16 (s, 1H), 8.32 (d, 1H, J = 8.0 Hz), 8.46 (d, 1H, J = 4.6 Hz) , 8.57-8.63 (m, 1H).
References
[1] Patent: EP1548005, 2005, A1. Location in patent: Page/Page column 11
4-METHYL-2,2'-BIPYRIDINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-METHYL-2,2'-BIPYRIDINE manufacturers
- Product
- 4-Methyl-2,2'-bipyridine 56100-19-7
- Price
- US $232.00-878.00/g
- Min. Order
- 1g
- Purity
- 0.98
- Supply Ability
- 10kg
- Release date
- 2024-04-12
- Product
- 4-METHYL-2,2'-BIPYRIDINE 56100-19-7
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 100KG
- Release date
- 2019-08-07