2-AMINO-4-METHOXY-BENZOIC ACID METHYL ESTER
- Product Name
- 2-AMINO-4-METHOXY-BENZOIC ACID METHYL ESTER
- CAS No.
- 50413-30-4
- Chemical Name
- 2-AMINO-4-METHOXY-BENZOIC ACID METHYL ESTER
- Synonyms
- METHYL 2-AMINO-4-METHOXYBENZOATE;methyl2-amino-4-methoxylbenzoate;2-amino-4-methoxybenzoate, methyl ester;2-AMINO-4-METHOXY-BENZOIC ACID METHYL ESTER;Benzoic acid, 2-amino-4-methoxy-, methyl ester
- CBNumber
- CB1195664
- Molecular Formula
- C9H11NO3
- Formula Weight
- 181.19
- MOL File
- 50413-30-4.mol
2-AMINO-4-METHOXY-BENZOIC ACID METHYL ESTER Property
- Melting point:
- 116-118 °C
- Boiling point:
- 313.7±22.0 °C(Predicted)
- Density
- 1.179±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- form
- solid
- pka
- 2.17±0.10(Predicted)
- Appearance
- Off-white to yellow Solid
Safety
- HS Code
- 2922500090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242Use only non-sparking tools.
P243Take precautionary measures against static discharge.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- M328633
- Product name
- Methyl2-amino-4-methoxybenzoate
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- M328633
- Product name
- Methyl2-amino-4-methoxybenzoate
- Packaging
- 500mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- J90945
- Product name
- Methyl2-amino-4-methoxylbenzoate
- Packaging
- 1g
- Price
- $30
- Updated
- 2021/12/16
- Product number
- FA51189
- Product name
- 2-Amino-4-methoxy-benzoic acid methyl ester
- Packaging
- 2g
- Price
- $50
- Updated
- 2021/12/16
- Product number
- FA51189
- Product name
- 2-Amino-4-methoxy-benzoic acid methyl ester
- Packaging
- 5G
- Price
- $100
- Updated
- 2021/12/16
2-AMINO-4-METHOXY-BENZOIC ACID METHYL ESTER Chemical Properties,Usage,Production
Synthesis
4294-95-5
18107-18-1
50413-30-4
(Trimethylmethylsilyl) diazomethane (2.0 M ethyl ether solution, 18.0 mL, 36.0 mmol) was added slowly and dropwise to a 10% methanolic tetrahydrofuran solution (100 mL) of 4-methoxyanthranilic acid (5.0 g, 30.0 mmol) at 0 °C. The reaction mixture was kept stirred at room temperature for 16 h. The reaction was subsequently terminated by addition of glacial acetic acid (0.1 mL). The reaction mixture was concentrated and the residue was partitioned between saturated sodium bicarbonate solution (50 mL) and ethyl acetate (250 mL). The organic layer was separated and washed sequentially with water (50 mL), saturated sodium bicarbonate solution (50 mL) and brine (50 mL), dried over anhydrous sodium sulfate, filtered and concentrated to afford methyl 2-amino-4-methoxybenzoate as an oil (5.4 g, quantitative). Mass spectrometry (EI) analysis showed a molecular ion peak (MH+) of 182 for C9H11NO3.
References
[1] Patent: WO2010/135524, 2010, A1. Location in patent: Page/Page column 219
[2] Patent: WO2013/25958, 2013, A1. Location in patent: Page/Page column 69; 70
[3] Patent: WO2014/43446, 2014, A1. Location in patent: Page/Page column 31
[4] Patent: EP2744501, 2016, B1. Location in patent: Paragraph 0204; 0205
[5] Journal of Medicinal Chemistry, 2012, vol. 55, # 7, p. 3170 - 3181
2-AMINO-4-METHOXY-BENZOIC ACID METHYL ESTER Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-AMINO-4-METHOXY-BENZOIC ACID METHYL ESTER manufacturers
- Product
- 2-AMINO-4-METHOXY-BENZOIC ACID METHYL ESTER 50413-30-4
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2019-12-30