ChemicalBook > CAS DataBase List > 1,2-Bis(p-tolylsulfonyl)hydrazine, N,Nμ-Ditosylhydrazine, 4-Methylbenzenesulfonic acid 2-[(4-methylphenyl)sulfonyl]hydrazide

1,2-Bis(p-tolylsulfonyl)hydrazine, N,Nμ-Ditosylhydrazine, 4-Methylbenzenesulfonic acid 2-[(4-methylphenyl)sulfonyl]hydrazide

Product Name
1,2-Bis(p-tolylsulfonyl)hydrazine, N,Nμ-Ditosylhydrazine, 4-Methylbenzenesulfonic acid 2-[(4-methylphenyl)sulfonyl]hydrazide
CAS No.
14062-05-6
Chemical Name
1,2-Bis(p-tolylsulfonyl)hydrazine, N,Nμ-Ditosylhydrazine, 4-Methylbenzenesulfonic acid 2-[(4-methylphenyl)sulfonyl]hydrazide
Synonyms
NSC 179371;N,N'-Ditosylhydrazine;N,N'-Bis(p-toluenesulfony;1,2-bis(p-tolysulfonyl)hydrazine;1,2-Bis(p-tolylsulfonyl)hydrazine;N,Nμ-Bis(p-toluenesulfonyl)hydrazine;N,N'-Bis(p-toluenesulfonyl)hydrazine;N,N'-Bis(p-toluenesulfonyl)hydrazine 97%;4-Methyl-N'-tosylbenzenesulfonohydrazide;4-methyl-N'-(p-tolylsulfonyl)benzenesulfonohydrazide
CBNumber
CB12097508
Molecular Formula
C14H16N2O4S2
Formula Weight
340.42
MOL File
14062-05-6.mol
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1,2-Bis(p-tolylsulfonyl)hydrazine, N,Nμ-Ditosylhydrazine, 4-Methylbenzenesulfonic acid 2-[(4-methylphenyl)sulfonyl]hydrazide Property

Melting point:
220-224 °C
Boiling point:
507.9±53.0 °C(Predicted)
Density 
1.355±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
pka
6.37±0.50(Predicted)
Appearance
White to off-white Solid
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B591935
Product name
N,N''-bis(p-Toluenesulfonyl)hydrazine
Packaging
500mg
Price
$130
Updated
2021/12/16
AK Scientific
Product number
J53244
Product name
N,N'-Bis(p-toluenesulfonyl)hydrazine
Packaging
10g
Price
$330
Updated
2021/12/16
AK Scientific
Product number
3673AL
Product name
N,N'-Bis(p-toluenesulfonyl)hydrazine
Packaging
10g
Price
$441
Updated
2021/12/16
AK Scientific
Product number
3673AL
Product name
N,N'-Bis(p-toluenesulfonyl)hydrazine
Packaging
1g
Price
$66
Updated
2021/12/16
AK Scientific
Product number
J53244
Product name
N,N'-Bis(p-toluenesulfonyl)hydrazine
Packaging
25g
Price
$655
Updated
2021/12/16
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1,2-Bis(p-tolylsulfonyl)hydrazine, N,Nμ-Ditosylhydrazine, 4-Methylbenzenesulfonic acid 2-[(4-methylphenyl)sulfonyl]hydrazide Chemical Properties,Usage,Production

Synthesis

98-59-9

1576-35-8

14062-05-6

Example 6 - Preparation of N,N'-bis(p-toluenesulfonyl)hydrazine: To a solution of dichloromethane (50 mL) containing p-toluenesulfonylhydrazine (9.32 g, 50 mmol) and p-toluenesulfonyl chloride (14.3 g, 75 mmol) was added pyridine (6 mL, 75 mmol). The reaction mixture was stirred at room temperature for 1.5 hours. Subsequently, ether (200 mL) and water (100 mL) were added and stirring was continued at 0°C for 15 minutes. After completion of the reaction, the mixture was filtered and the solid product was washed with ether. Finally, purification by recrystallization from methanol afforded N,N'-bis(p-toluenesulfonyl)hydrazine as a white solid (11.5 g, 68% yield).

References

[1] Beilstein Journal of Organic Chemistry, 2013, vol. 9, p. 1407 - 1413
[2] Chemical Communications, 2017, vol. 53, # 54, p. 7485 - 7488
[3] Organic Letters, 2007, vol. 9, # 16, p. 3195 - 3197
[4] Chemical Communications, 2018, vol. 54, # 28, p. 3516 - 3519
[5] Liebigs Annalen der Chemie, 1991, # 10, p. 983 - 986

1,2-Bis(p-tolylsulfonyl)hydrazine, N,Nμ-Ditosylhydrazine, 4-Methylbenzenesulfonic acid 2-[(4-methylphenyl)sulfonyl]hydrazide Preparation Products And Raw materials

Raw materials

Preparation Products

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1,2-Bis(p-tolylsulfonyl)hydrazine, N,Nμ-Ditosylhydrazine, 4-Methylbenzenesulfonic acid 2-[(4-methylphenyl)sulfonyl]hydrazide Suppliers

China 56 India 2 Switzerland 1 United States 8 Global 67
SIGMA-RBI
Tel
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Fax
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Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from 1,2-Bis(p-tolylsulfonyl)hydrazine, N,Nμ-Ditosylhydrazine, 4-Methylbenzenesulfonic acid 2-[(4-methylphenyl)sulfonyl]hydrazide manufacturers

Career Henan Chemical Co
Product
4-methyl-N'-(4-methylphenyl)sulfonylbenzenesulfonohydrazide 14062-05-6
Price
US $8.80/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
100kg
Release date
2019-07-09

14062-05-6, 1,2-Bis(p-tolylsulfonyl)hydrazine, N,Nμ-Ditosylhydrazine, 4-Methylbenzenesulfonic acid 2-[(4-methylphenyl)sulfonyl]hydrazideRelated Search:

Tosyl chloride 1,2-Bis(p-tolylsulfonyl)hydrazine, N,Nμ-Ditosylhydrazine, 4-Methylbenzenesulfonic acid 2-[(4-methylphenyl)sulfonyl]hydrazide 4-Methylbenzenesulfonhydrazide METHANESULFONYL HYDRAZIDE Benzenesulfonyl hydrazide

  • 1,2-Bis(p-tolylsulfonyl)hydrazine, N,Nμ-Ditosylhydrazine, 4-Methylbenzenesulfonic acid 2-[(4-methylphenyl)sulfonyl]hydrazide
  • Benzenesulfonic acid,4-methyl-, 2-[(4-methylphenyl)sulfonyl]hydrazide
  • N,N'-Bis(p-toluenesulfony
  • N,N'-Ditosylhydrazine
  • N,Nμ-Bis(p-toluenesulfonyl)hydrazine
  • 1,2-bis(p-tolysulfonyl)hydrazine
  • NSC 179371
  • N,N'-Bis(p-toluenesulfonyl)hydrazine 97%
  • 1,2-Bis(p-tolylsulfonyl)hydrazine
  • 4-Methyl-N'-tosylbenzenesulfonohydrazide
  • 4-Methylbenzenesulfonic acid 2-[(4-methylphenyl)sulfonyl]hydrazide
  • N,N'-Bis(p-toluenesulfonyl)hydrazine
  • 4-methyl-N'-(p-tolylsulfonyl)benzenesulfonohydrazide
  • <i>N</i>,<i>N</i>′-Bis(<i>p</i>-toluenesulfonyl)hydrazine
  • 14062-05-6