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Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)

Product Name
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
CAS No.
31277-98-2
Chemical Name
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
Synonyms
Pd(dppe)2;PD(DIPHOS)2;Bis[1,2-bis(diphenyL;phosphino)ethane]paL;Pd(DIPHOS)2 Pd(dppe)2;Bisbisdiphenylphosphi;BIS(DIPHOS)PALLADIUM(0);Bis[1,2-bis(diphenylphosphino);Bis(DIPHOS)palladium(0), Pd(DIPHOS)2;Bis[1,2-bis(diphenylphosphino)ethane]
CBNumber
CB1230635
Molecular Formula
C52H48P4Pd
Formula Weight
903.25
MOL File
31277-98-2.mol
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Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Property

Melting point:
219-225 °C
storage temp. 
-20°C
solubility 
sol nonprotic solvents
form 
Powder
color 
orange
Water Solubility 
insoluble
Sensitive 
Air Sensitive
InChI
InChI=1S/2C26H24P2.Pd/c2*1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;/h2*1-20H,21-22H2;
InChIKey
UTBLWXFSGOYWOH-UHFFFAOYSA-R
SMILES
P(CCP(C1=CC=CC=C1)C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=CC=C1.P(CCP(C1=CC=CC=C1)C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Pd]
CAS DataBase Reference
31277-98-2
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
20/21/22-36/37/38
Safety Statements 
36-37/39-26
RIDADR 
1479
WGK Germany 
3
HazardClass 
5.1
PackingGroup 
III
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
230278
Product name
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
Packaging
1g
Price
$100
Updated
2023/01/07
TCI Chemical
Product number
B3224
Product name
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
Purity
>96.0%(T)
Packaging
1g
Price
$86
Updated
2025/07/31
TCI Chemical
Product number
B3224
Product name
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
Purity
>96.0%(T)
Packaging
5g
Price
$293
Updated
2025/07/31
Strem Chemicals
Product number
46-0200
Product name
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0), 98%
Packaging
1g
Price
$97
Updated
2024/03/01
Strem Chemicals
Product number
46-0200
Product name
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0), 98%
Packaging
5g
Price
$388
Updated
2024/03/01
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Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Chemical Properties,Usage,Production

Chemical Properties

yellow to orange crystalline powder

Uses

Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) is a homogeneous catalyst most widely used in allylic substitution reactions; good catalyst for bulky substrates; slowly dissociating ligand that gives good stereoselectivity.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

storage

air and light sensitive. If stored under nitrogen or argon it is stable for  about one month. Avoid inhalation. Use in a fume hood.

Purification Methods

Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) can be recrystallized from benzene-ethanol or ethanol.

Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Suppliers

Americas 1 Australia 1 Belgium 1 China 143 Europe 1 Germany 4 India 4 Japan 1 Switzerland 1 United Kingdom 2 United States 22 Global 181
TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23653
Advantage
75
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View Lastest Price from Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) manufacturers

henan kanbei chemical co.,ltd
Product
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) 31277-98-2
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-23
Zhuozhou Wenxi import and Export Co., Ltd
Product
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) 31277-98-2
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Longyan Tianhua Biological Technology Co., Ltd
Product
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) 31277-98-2
Price
US $20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-11

31277-98-2, Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)Related Search:

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  • BIS[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]-PALLADIUM
  • BIS[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]PALLADIUM(0)
  • BIS(DIPHOS)PALLADIUM(0)
  • PD(DIPHOS)2
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  • Bis[1,2-bis(diphenylphosphino)ethane]palladium(0),98%
  • Pd(dppe)2
  • Bis1,2-bis(diphenylphosphino)ethaneüpalladium (0)
  • Bis(DIPHOS)palladium(0), Pd(DIPHOS)2
  • 1,2-Bis(diphenylphosphino)ethaneüpalladium
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  • Bis{1,2-bis(diphenylphosphino)ethane}palladium (O), 98%
  • Bis[1,2-bis(diphenylphosphino)ethane]palladiuM (0),98% Pd(DPPE)2
  • Pd(DIPHOS)2 Pd(dppe)2
  • Bis[1,2-bis(diphenylphosphiNA)ethane]palladiuM(0)
  • Bis[1,2-bis(diphenylphosphino)
  • Bisbisdiphenylphosphi
  • 2-diphenylphosphanylethyl(diphenyl)phosphane,palladium
  • Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)&gt
  • Bis[1,2-bis(diphenyL
  • phosphino)ethane]paL
  • Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) ISO 9001：2015 REACH
  • 31277-98-2
  • PdC6H52PCH2CH2PC6H522
  • C6H52PCH2CH2PC6H522Pd
  • C52H48P4Pd
  • 2C26H24P2Pd
  • Homogeneous Pd Catalysts
  • Catalysis and Inorganic Chemistry
  • Pd
  • Pyrimidines
  • metal-phosphine complexes
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Pd (Palladium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds