Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
- Product Name
- Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
- CAS No.
- 31277-98-2
- Chemical Name
- Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
- Synonyms
- Pd(dppe)2;PD(DIPHOS)2;Bis[1,2-bis(diphenyL;phosphino)ethane]paL;Pd(DIPHOS)2 Pd(dppe)2;Bisbisdiphenylphosphi;BIS(DIPHOS)PALLADIUM(0);Bis[1,2-bis(diphenylphosphino);Bis(DIPHOS)palladium(0), Pd(DIPHOS)2;Bis[1,2-bis(diphenylphosphino)ethane]
- CBNumber
- CB1230635
- Molecular Formula
- C52H48P4Pd
- Formula Weight
- 903.25
- MOL File
- 31277-98-2.mol
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Property
- Melting point:
- 219-225 °C
- storage temp.
- -20°C
- solubility
- sol nonprotic solvents
- form
- Powder
- color
- orange
- Water Solubility
- insoluble
- Sensitive
- Air Sensitive
- InChI
- InChI=1S/2C26H24P2.Pd/c2*1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;/h2*1-20H,21-22H2;
- InChIKey
- UTBLWXFSGOYWOH-UHFFFAOYSA-R
- SMILES
- P(CCP(C1=CC=CC=C1)C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=CC=C1.P(CCP(C1=CC=CC=C1)C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Pd]
- CAS DataBase Reference
- 31277-98-2
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 36-37/39-26
- RIDADR
- 1479
- WGK Germany
- 3
- HazardClass
- 5.1
- PackingGroup
- III
- HS Code
- 28439000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
N-Bromosuccinimide Price
- Product number
- 230278
- Product name
- Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
- Packaging
- 1g
- Price
- $100
- Updated
- 2023/01/07
- Product number
- B3224
- Product name
- Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
- Purity
- >96.0%(T)
- Packaging
- 1g
- Price
- $86
- Updated
- 2025/07/31
- Product number
- B3224
- Product name
- Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
- Purity
- >96.0%(T)
- Packaging
- 5g
- Price
- $293
- Updated
- 2025/07/31
- Product number
- 46-0200
- Product name
- Bis[1,2-bis(diphenylphosphino)ethane]palladium(0), 98%
- Packaging
- 1g
- Price
- $97
- Updated
- 2024/03/01
- Product number
- 46-0200
- Product name
- Bis[1,2-bis(diphenylphosphino)ethane]palladium(0), 98%
- Packaging
- 5g
- Price
- $388
- Updated
- 2024/03/01
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Chemical Properties,Usage,Production
Chemical Properties
yellow to orange crystalline powder
Uses
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) is a homogeneous catalyst most widely used in allylic substitution reactions; good catalyst for bulky substrates; slowly dissociating ligand that gives good stereoselectivity.
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
storage
air and light sensitive. If stored under nitrogen or argon it is stable for about one month. Avoid inhalation. Use in a fume hood.
Purification Methods
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) can be recrystallized from benzene-ethanol or ethanol.
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) manufacturers
- Product
- Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) 31277-98-2
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2022-09-23
- Product
- Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) 31277-98-2
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11
- Product
- Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) 31277-98-2
- Price
- US $20.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000KG
- Release date
- 2020-11-11