Tetramethylammonium fluoride
- Product Name
- Tetramethylammonium fluoride
- CAS No.
- 373-68-2
- Chemical Name
- Tetramethylammonium fluoride
- Synonyms
- TetraMethylaMMoniuM fluorid;Tetramethylaminium·fluoride;Tetramethylazanium fluoride;TETRAMETHYLAMMONIUM FLUORIDE;Tetramethylammonium Fluoridede;Tetramethylammonium fluoride (7CI);n,n,n-trimethyl-methanaminiufluoride;N,N,N-Trimethylmethanaminium fluoride;Tetramethylammonium fluoride, anhydrous;Methanaminium, N,N,N-trimethyl-, fluoride
- CBNumber
- CB1235483
- Molecular Formula
- C4H12FN
- Formula Weight
- 93.14
- MOL File
- 373-68-2.mol
Tetramethylammonium fluoride Property
- Melting point:
- 170 °C (dec.) (lit.)
- InChIKey
- HQFTZNVQVRRDLN-UHFFFAOYSA-M
- CAS DataBase Reference
- 373-68-2(CAS DataBase Reference)
- EPA Substance Registry System
- Tetramethylammonium fluoride (373-68-2)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-36
- RIDADR
- 2811
- WGK Germany
- 3
- HazardClass
- 6.1(b)
- PackingGroup
- III
- HS Code
- 29239000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 459135
- Product name
- Tetramethylammonium fluoride
- Purity
- 97%
- Packaging
- 1g
- Price
- $110
- Updated
- 2024/03/01
- Product number
- 459135
- Product name
- Tetramethylammonium fluoride
- Purity
- 97%
- Packaging
- 5g
- Price
- $516
- Updated
- 2024/03/01
- Product number
- T303855
- Product name
- Tetramethylammonium fluoride
- Packaging
- 500mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- T303855
- Product name
- Tetramethylammonium fluoride
- Packaging
- 1g
- Price
- $50
- Updated
- 2021/12/16
- Product number
- 3133-3-10
- Product name
- Tetramethylammonium fluoride, anhydrous
- Purity
- 97%
- Packaging
- 250mg
- Price
- $65
- Updated
- 2021/12/16
Tetramethylammonium fluoride Chemical Properties,Usage,Production
Description
Tetramethylammonium fluoride is the quaternary ammonium salt with the formula (CH3)4NF. This hygroscopic white solid is a source of "naked fluoride", that is fluoride ions not connected to a metal atom in a complex. Most other soluble salts of fluoride are in fact bifluorides, HF2–. Historically, there has been two main approaches to prepare TMAF:
(i) Via neutralization of tetramethylammonium hydroxide (TMAOH) with HF.
(ii) through the metathesis reaction of different ammonium salts with inorganic sources of fluoride such as KF or CsF.
Due to the high basicity of the fluoride anion, the salt reacts slowly with acetonitrile, inducing its dimerization to CH3C(NH2)=CHCN, which co-crystallizes.
Uses
Tetramethylammonium fluoride may be used in combination with sulfuryl fluoride for the conversion of aryl phenols to aryl fluorides. It can react with aminosilanes to generate onium amide bases in situ, which can deprotonate heteroarenes.
Uses
Reactant for:
- Halide-induced ring opening of 2-substituted aziridinium salts
- Synthesis of fluoro aromatics via fluorodenitration reactions
- Synthesis of sevoflurane in ionic liquids by halogen-exchange fluorination
- Synthesis of fluorinated Poly(oxomolybdates)
Tetramethylammonium fluoride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Tetramethylammonium fluoride manufacturers
- Product
- Tetramethylammonium fluoride 373-68-2
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-02-02
- Product
- Tetramethylammonium fluoride tetrahydrate 373-68-2
- Price
- US $19.90/Kg/Drum
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2021-04-25
- Product
- Tetramethylammonium fluoride tetrahydrate 373-68-2
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-09-08