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Tetramethylammonium fluoride

Product Name
Tetramethylammonium fluoride
CAS No.
373-68-2
Chemical Name
Tetramethylammonium fluoride
Synonyms
TetraMethylaMMoniuM fluorid;Tetramethylaminium·fluoride;Tetramethylazanium fluoride;TETRAMETHYLAMMONIUM FLUORIDE;Tetramethylammonium Fluoridede;Tetramethylammonium fluoride (7CI);n,n,n-trimethyl-methanaminiufluoride;N,N,N-Trimethylmethanaminium fluoride;Tetramethylammonium fluoride, anhydrous;Methanaminium, N,N,N-trimethyl-, fluoride
CBNumber
CB1235483
Molecular Formula
C4H12FN
Formula Weight
93.14
MOL File
373-68-2.mol
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Tetramethylammonium fluoride Property

Melting point:
170 °C (dec.) (lit.)
InChIKey
HQFTZNVQVRRDLN-UHFFFAOYSA-M
CAS DataBase Reference
373-68-2(CAS DataBase Reference)
EPA Substance Registry System
Tetramethylammonium fluoride (373-68-2)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36
RIDADR 
2811
WGK Germany 
3
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29239000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
459135
Product name
Tetramethylammonium fluoride
Purity
97%
Packaging
1g
Price
$110
Updated
2024/03/01
Sigma-Aldrich
Product number
459135
Product name
Tetramethylammonium fluoride
Purity
97%
Packaging
5g
Price
$516
Updated
2024/03/01
TRC
Product number
T303855
Product name
Tetramethylammonium fluoride
Packaging
500mg
Price
$45
Updated
2021/12/16
TRC
Product number
T303855
Product name
Tetramethylammonium fluoride
Packaging
1g
Price
$50
Updated
2021/12/16
SynQuest Laboratories
Product number
3133-3-10
Product name
Tetramethylammonium fluoride, anhydrous
Purity
97%
Packaging
250mg
Price
$65
Updated
2021/12/16
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Tetramethylammonium fluoride Chemical Properties,Usage,Production

Description

Tetramethylammonium fluoride is the quaternary ammonium salt with the formula (CH3)4NF. This hygroscopic white solid is a source of "naked fluoride", that is fluoride ions not connected to a metal atom in a complex. Most other soluble salts of fluoride are in fact bifluorides, HF2–. Historically, there has been two main approaches to prepare TMAF:
(i) Via neutralization of tetramethylammonium hydroxide (TMAOH) with HF.
(ii) through the metathesis reaction of different ammonium salts with inorganic sources of fluoride such as KF or CsF.
Due to the high basicity of the fluoride anion, the salt reacts slowly with acetonitrile, inducing its dimerization to CH3C(NH2)=CHCN, which co-crystallizes.

Uses

Tetramethylammonium fluoride may be used in combination with sulfuryl fluoride for the conversion of aryl phenols to aryl fluorides. It can react with aminosilanes to generate onium amide bases in situ, which can deprotonate heteroarenes.

Uses

Reactant for:

  • Halide-induced ring opening of 2-substituted aziridinium salts
  • Synthesis of fluoro aromatics via fluorodenitration reactions
  • Synthesis of sevoflurane in ionic liquids by halogen-exchange fluorination
  • Synthesis of fluorinated Poly(oxomolybdates)

Tetramethylammonium fluoride Preparation Products And Raw materials

Raw materials

Preparation Products

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Tetramethylammonium fluoride Suppliers

Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
Jiaxing Zhejia Biotechnology Co., LTD
Tel
0573-85609002
Email
zhejia01@163.com
Country
China
ProdList
8869
Advantage
58
Changzhou Zeyuan Pharmaceutical Technology Co., Ltd
Tel
190-26388314 19015480862
Email
2589694173@qq.com
Country
China
ProdList
255
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
SelectLab Chemicals GmbH
Tel
+49-(0)2383-919350
Fax
+49-(0)2383-919354
Email
info@selectlab.de
Country
Germany
ProdList
394
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12438
Advantage
60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9414
Advantage
66
Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
ProdList
10186
Advantage
62
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View Lastest Price from Tetramethylammonium fluoride manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Tetramethylammonium fluoride 373-68-2
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-02
Hebei Weibang Biotechnology Co., Ltd
Product
Tetramethylammonium fluoride tetrahydrate 373-68-2
Price
US $19.90/Kg/Drum
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2021-04-25
Hebei Mojin Biotechnology Co., Ltd
Product
Tetramethylammonium fluoride tetrahydrate 373-68-2
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-08

373-68-2, Tetramethylammonium fluorideRelated Search:


  • Tetramethylammonium Fluoridede
  • n,n,n-trimethyl-methanaminiufluoride
  • TETRAMETHYLAMMONIUM FLUORIDE
  • Tetramethylammoniumfluoride,20%AqueousSolution
  • Tetramethylammonium fluoride, anhydrous
  • Methanaminium, N,N,N-trimethyl-, fluoride
  • Tetramethylazanium fluoride
  • Tetramethylaminium·fluoride
  • TetraMethylaMMoniuM fluorid
  • N,N,N-Trimethylmethanaminium fluoride
  • Tetramethylammonium fluoride ISO 9001:2015 REACH
  • 373-68-2 Tetramethylammonium fluoride C4H12FN
  • Tetramethylammonium fluoride (7CI)
  • 373-68-2
  • C4H12NF
  • CH34NF
  • Protection and Derivatization
  • Synthetic Reagents
  • Deprotection
  • Fluoride Sources
  • Deprotecting Reagents
  • Fluoride Sources
  • Protection and Derivatization
  • quarternary ammonium salts