ChemicalBook > CAS DataBase List > (9-(4-BROMOPHENYL))-9H-CARBAZOLE

(9-(4-BROMOPHENYL))-9H-CARBAZOLE

Product Name
(9-(4-BROMOPHENYL))-9H-CARBAZOLE
CAS No.
57102-42-8
Chemical Name
(9-(4-BROMOPHENYL))-9H-CARBAZOLE
Synonyms
3-NBPC;9-(4-Bromophenyl)carbazole;9-(4-BroMophenyl)carbazole90%;9-(4-Bromophenyl)carbazole >N-(4-BroMophenyl)-9H-carbazole;9H-Carbazole,9-(4-broMophenyl)-;9-(4-Bromophenyl)carbazole (9-(4-BROMOPHENYL))-9H-CARBAZOLE;9-(4-Bromophenyl)-9H-carbazole 98%;9-(4-broMophenyl)-9H-carbazole 4BPC
CBNumber
CB12459465
Molecular Formula
C18H12BrN
Formula Weight
322.2
MOL File
57102-42-8.mol
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(9-(4-BROMOPHENYL))-9H-CARBAZOLE Property

Melting point:
147-151℃
Boiling point:
452.7±37.0 °C(Predicted)
Density 
1.39±0.1 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
Solid
color 
White to Light yellow
Water Solubility 
Slightly soluble in water.
InChIKey
XSDKKRKTDZMKCH-UHFFFAOYSA-N
CAS DataBase Reference
57102-42-8
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Safety

HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B3554
Product name
9-(4-Bromophenyl)carbazole
Purity
>98.0%(GC)
Packaging
1g
Price
$41
Updated
2025/07/31
TCI Chemical
Product number
B3554
Product name
9-(4-Bromophenyl)carbazole
Purity
>98.0%(GC)
Packaging
5g
Price
$119
Updated
2025/07/31
Biosynth Carbosynth
Product number
FB42951
Product name
(9-(4-Bromophenyl))-9H-carbazole
Packaging
5G
Price
$60
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK1023050
Product name
9-(4-Bromophenyl)carbazole
Purity
98%
Packaging
1g
Price
$84
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB42951
Product name
(9-(4-Bromophenyl))-9H-carbazole
Packaging
10g
Price
$100
Updated
2021/12/16
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(9-(4-BROMOPHENYL))-9H-CARBAZOLE Chemical Properties,Usage,Production

Chemical Properties

White to light yellow solid

Uses

It plays an important role as intermediate for pharmaceutical, organic synthesis and organic light-emitting diode(OLED).

Synthesis

106-37-6

86-74-8

57102-42-8

Step 2: Synthesis of 4-(carbazol-9-yl)diphenylamine (abbreviation: YGA); In Step 2, YGA was synthesized according to (i) and (ii) shown below. (i) Synthesis of 9-(4-bromophenyl)carbazole; First, 56 g (240 mmol) of 1,4-dibromobenzene, 31 g (180 mmol) of carbazole, 4.6 g (24 mmol) of copper iodide, 16 g (480 mmol) of potassium carbonate and 2.1 g (8 mmol) of 18-crown-6-ether were added to a 300 mL three-necked flask and air displaced with nitrogen. 66 g (480 mmol) of potassium carbonate and 2.1 g (8 mmol) of 18-crown-6-ether were added to a 300 mL three-necked flask and the air in the flask was replaced with nitrogen. Subsequently, 8 mL of N,N-dimethylpropyleneurea (abbreviation: DMPU) was added to the flask and the reaction mixture was stirred at 180 °C for 6 hours. After completion of the reaction, the mixture was cooled to room temperature and the precipitate was removed by filtration. The filtrate was washed sequentially with dilute hydrochloric acid, saturated aqueous sodium bicarbonate solution and saturated aqueous sodium chloride solution, and then dried with anhydrous magnesium sulfate. After drying, the solution was naturally filtered and concentrated, and the resulting oil was purified by silica gel column chromatography (eluent: hexane/ethyl acetate = 9:1) and finally recrystallized with chloroform and hexane. Finally, 21 g of light brown plate-like crystals of the target product 9-(4-bromophenyl)carbazole were obtained in 35% yield.

References

[1] Chemistry Letters, 2008, vol. 37, # 9, p. 986 - 987
[2] Patent: CN106883163, 2017, A. Location in patent: Paragraph 0030; 0031; 0032; 0033
[3] New Journal of Chemistry, 2010, vol. 34, # 7, p. 1317 - 1322
[4] Patent: CN105585577, 2016, A. Location in patent: Paragraph 0220; 0221; 0222; 0223; 0224
[5] Patent: EP2292618, 2011, A1. Location in patent: Page/Page column 17

(9-(4-BROMOPHENYL))-9H-CARBAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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(9-(4-BROMOPHENYL))-9H-CARBAZOLE Suppliers

Henan Jinbak New Material Technology Co., Ltd
Tel
18737135779
Email
1169001743@qq.com
Country
China
ProdList
95
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58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
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40228
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future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
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China
ProdList
1995
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New Energy Chemicals
Tel
0515-82159099 13770142076
Fax
86-0515-8215909
Email
info@njuchem.com
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China
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242
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Alfa Aesar
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400-6106006
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021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
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84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
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Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
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China
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Jilin OLED Material Tech Co., Ltd
Tel
0431-85877181
Fax
0431-85804772
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sales@jl-oled.com
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China
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Accela ChemBio Co.,Ltd.
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021-50795510 4000665055
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021-50795055
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sales@accelachem.com
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China
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View Lastest Price from (9-(4-BROMOPHENYL))-9H-CARBAZOLE manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
(9-(4-BROMOPHENYL))-9H-CARBAZOLE 57102-42-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2025-05-16
Hebei Chuanghai Biotechnology Co., Ltd
Product
9-(4-Bromophenyl)carbazole 57102-42-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-25
Zhengzhou Anbu Chem Co.,Ltd
Product
(9-(4-BROMOPHENYL))-9H-CARBAZOLE 57102-42-8
Price
US $0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1000KGS
Release date
2023-04-24

57102-42-8, (9-(4-BROMOPHENYL))-9H-CARBAZOLERelated Search:


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  • 57102-42-8
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  • S-7102-42-8
  • C18H12BrN
  • OLED
  • organic chemicals and derivatives/others
  • OLED materials,pharm chemical,electronic