ChemicalBook > CAS DataBase List > 2-Bromo-9-phenyl-9H-carbazole

2-Bromo-9-phenyl-9H-carbazole

Product Name
2-Bromo-9-phenyl-9H-carbazole
CAS No.
94994-62-4
Chemical Name
2-Bromo-9-phenyl-9H-carbazole
Synonyms
2-Bromo-9-phenylcarbazole;2-Brom-xanthen-9-on;2-bromo-N-phenylcoumarin;2-BroMo-N-phenylcarbazole;N-Phenyl-2-bromocarbazole;2-Bromo-9-phenyl-9H-carba;Phenyl-2-bromo-N- carbazole;2-Bromo-9-phenyl-9H-carbazol;Carbazole, 2-bromo-9-phenyl-;2-Bromo-9-phenyl-9H-carbazole
CBNumber
CB42614371
Molecular Formula
C18H12BrN
Formula Weight
322.2
MOL File
94994-62-4.mol
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2-Bromo-9-phenyl-9H-carbazole Property

Melting point:
88.0 to 92.0 °C
Boiling point:
461.7±27.0 °C(Predicted)
Density 
1.39
storage temp. 
Sealed in dry,Room Temperature
form 
powder to crystal
color 
White to Almost white
InChI
InChI=1S/C18H12BrN/c19-13-10-11-16-15-8-4-5-9-17(15)20(18(16)12-13)14-6-2-1-3-7-14/h1-12H
InChIKey
SOODLDGRGXOSTA-UHFFFAOYSA-N
SMILES
N1(C2=CC=CC=C2)C2=C(C=CC=C2)C2=C1C=C(Br)C=C2
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Safety

HS Code 
2933.99.8290
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B4439
Product name
2-Bromo-9-phenylcarbazole
Purity
>98.0%(GC)(N)
Packaging
1g
Price
$37
Updated
2025/07/31
TCI Chemical
Product number
B4439
Product name
2-Bromo-9-phenylcarbazole
Purity
>98.0%(GC)(N)
Packaging
5g
Price
$110
Updated
2025/07/31
TRC
Product number
B678358
Product name
2-Bromo-9-phenyl-9H-carbazole
Packaging
500mg
Price
$175
Updated
2021/12/16
AK Scientific
Product number
J57244
Product name
2-Bromo-9-phenyl-9H-carbazole
Packaging
25g
Price
$189
Updated
2021/12/16
Chem-Impex
Product number
30932
Product name
2-Bromo-9-phenylcarbazole,≥98%(GC)
Purity
≥98%(GC)
Packaging
1G
Price
$50.17
Updated
2021/12/16
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2-Bromo-9-phenyl-9H-carbazole Chemical Properties,Usage,Production

Chemical Properties

off-white powder

Uses

2-Bromo-9-phenyl-9H-carbazole is used as a reactant for the preparation of OLED screens and electronic devices.

Synthesis

3652-90-2

591-50-4

94994-62-4

2-Bromocarbazole (10 mmol), iodobenzene (20 mmol), potassium carbonate (20 mmol), L-proline (2 mmol), copper(I) iodide (1 mmol), and dimethyl sulfoxide (25 mL) were added to the pressure vessel. After evacuation and replacement with nitrogen three times, the vessel was sealed and the reaction was stirred at 90°C for 72 hours. After completion of the reaction, it was cooled to room temperature, the reaction mixture was diluted with dichloromethane (200 mL), washed four times sequentially with water (200 mL) and the organic phase was dried with anhydrous magnesium sulfate. After concentration under reduced pressure to remove the solvent, the crude product was purified by silica gel column chromatography using hexane as eluent to give 2-bromo-9-phenyl-9H-carbazole in 85% yield.

References

[1] Patent: WO2013/122402, 2013, A1. Location in patent: Paragraph 196; 201; 202
[2] Patent: WO2013/162284, 2013, A1. Location in patent: Paragraph 164; 165
[3] Journal of Materials Chemistry, 2012, vol. 22, # 1, p. 215 - 224
[4] Patent: WO2015/99484, 2015, A1. Location in patent: Paragraph 181-182
[5] Patent: WO2014/3440, 2014, A1. Location in patent: Paragraph 172; 173; 178; 179

2-Bromo-9-phenyl-9H-carbazole Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Bromo-9-phenyl-9H-carbazole Suppliers

Qinghai Syan Biotechology Co.,Ltd
Tel
13897237054
Email
market@qhsyan.com
Country
China
ProdList
109
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58
Zhengzhou HQ Material Co., Ltd.
Tel
0371-67759225 13526468238
Fax
+86-37155919558
Email
sales@hqmat.com
Country
China
ProdList
812
Advantage
55
Puyang Huicheng Electronic Material Co. Ltd.
Tel
0393-0393-0393-8910800 15039333257
Fax
0393-8912775
Email
info@huichengchem.com
Country
China
ProdList
569
Advantage
64
SHAANXI LIGHTE OPTOELECTRONICS MATERIAL CO., LTD
Tel
029-88320727 17691239725
Fax
Q: 915385738
Email
915385738@qq.com
Country
China
ProdList
423
Advantage
58
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
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81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
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61
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9883
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Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Xi’an Caijing Opto-Electrical Science and Technology Co.,Ltd
Tel
029-88294447 029-88292246 029-88296135
Fax
029-88292246
Email
cjoesale@xacjoe.com
Country
China
ProdList
221
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Springchem New Material Technology Co.,Limited
Tel
+86-021-62885108 +8613917661608
Email
info@spring-chem.com
Country
China
ProdList
2068
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57
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View Lastest Price from 2-Bromo-9-phenyl-9H-carbazole manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
2-Bromo-9-phenyl-9H-carbazole 94994-62-4
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5tons
Release date
2024-12-04
Shanghai Daken Advanced Materials Co.,Ltd
Product
9H-Carbazole, 2-bromo-9-phenyl- 94994-62-4
Price
US $0.00/KG
Min. Order
1KG
Purity
98.00%
Supply Ability
150KG /month
Release date
2021-11-17
Henan Fengda Chemical Co., Ltd
Product
2-Bromo-9-phenyl-9H-carbazole 94994-62-4
Price
US $200.00-1.00/KG
Min. Order
1KG
Purity
99%, 99.5% Sublimated
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-31

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