2-Bromo-9-phenyl-9H-carbazole
- Product Name
- 2-Bromo-9-phenyl-9H-carbazole
- CAS No.
- 94994-62-4
- Chemical Name
- 2-Bromo-9-phenyl-9H-carbazole
- Synonyms
- 2-Bromo-9-phenylcarbazole;2-Brom-xanthen-9-on;2-bromo-N-phenylcoumarin;2-BroMo-N-phenylcarbazole;N-Phenyl-2-bromocarbazole;2-Bromo-9-phenyl-9H-carba;Phenyl-2-bromo-N- carbazole;2-Bromo-9-phenyl-9H-carbazol;Carbazole, 2-bromo-9-phenyl-;2-Bromo-9-phenyl-9H-carbazole
- CBNumber
- CB42614371
- Molecular Formula
- C18H12BrN
- Formula Weight
- 322.2
- MOL File
- 94994-62-4.mol
2-Bromo-9-phenyl-9H-carbazole Property
- Melting point:
- 88.0 to 92.0 °C
- Boiling point:
- 461.7±27.0 °C(Predicted)
- Density
- 1.39
- storage temp.
- Sealed in dry,Room Temperature
- form
- powder to crystal
- color
- White to Almost white
- InChI
- InChI=1S/C18H12BrN/c19-13-10-11-16-15-8-4-5-9-17(15)20(18(16)12-13)14-6-2-1-3-7-14/h1-12H
- InChIKey
- SOODLDGRGXOSTA-UHFFFAOYSA-N
- SMILES
- N1(C2=CC=CC=C2)C2=C(C=CC=C2)C2=C1C=C(Br)C=C2
Safety
- HS Code
- 2933.99.8290
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- B4439
- Product name
- 2-Bromo-9-phenylcarbazole
- Purity
- >98.0%(GC)(N)
- Packaging
- 1g
- Price
- $37
- Updated
- 2025/07/31
- Product number
- B4439
- Product name
- 2-Bromo-9-phenylcarbazole
- Purity
- >98.0%(GC)(N)
- Packaging
- 5g
- Price
- $110
- Updated
- 2025/07/31
- Product number
- B678358
- Product name
- 2-Bromo-9-phenyl-9H-carbazole
- Packaging
- 500mg
- Price
- $175
- Updated
- 2021/12/16
- Product number
- J57244
- Product name
- 2-Bromo-9-phenyl-9H-carbazole
- Packaging
- 25g
- Price
- $189
- Updated
- 2021/12/16
- Product number
- 30932
- Product name
- 2-Bromo-9-phenylcarbazole,≥98%(GC)
- Purity
- ≥98%(GC)
- Packaging
- 1G
- Price
- $50.17
- Updated
- 2021/12/16
2-Bromo-9-phenyl-9H-carbazole Chemical Properties,Usage,Production
Chemical Properties
off-white powder
Uses
2-Bromo-9-phenyl-9H-carbazole is used as a reactant for the preparation of OLED screens and electronic devices.
Synthesis
3652-90-2
591-50-4
94994-62-4
2-Bromocarbazole (10 mmol), iodobenzene (20 mmol), potassium carbonate (20 mmol), L-proline (2 mmol), copper(I) iodide (1 mmol), and dimethyl sulfoxide (25 mL) were added to the pressure vessel. After evacuation and replacement with nitrogen three times, the vessel was sealed and the reaction was stirred at 90°C for 72 hours. After completion of the reaction, it was cooled to room temperature, the reaction mixture was diluted with dichloromethane (200 mL), washed four times sequentially with water (200 mL) and the organic phase was dried with anhydrous magnesium sulfate. After concentration under reduced pressure to remove the solvent, the crude product was purified by silica gel column chromatography using hexane as eluent to give 2-bromo-9-phenyl-9H-carbazole in 85% yield.
References
[1] Patent: WO2013/122402, 2013, A1. Location in patent: Paragraph 196; 201; 202
[2] Patent: WO2013/162284, 2013, A1. Location in patent: Paragraph 164; 165
[3] Journal of Materials Chemistry, 2012, vol. 22, # 1, p. 215 - 224
[4] Patent: WO2015/99484, 2015, A1. Location in patent: Paragraph 181-182
[5] Patent: WO2014/3440, 2014, A1. Location in patent: Paragraph 172; 173; 178; 179
2-Bromo-9-phenyl-9H-carbazole Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-Bromo-9-phenyl-9H-carbazole manufacturers
- Product
- 2-Bromo-9-phenyl-9H-carbazole 94994-62-4
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 5tons
- Release date
- 2024-12-04
- Product
- 9H-Carbazole, 2-bromo-9-phenyl- 94994-62-4
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.00%
- Supply Ability
- 150KG /month
- Release date
- 2021-11-17
- Product
- 2-Bromo-9-phenyl-9H-carbazole 94994-62-4
- Price
- US $200.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%, 99.5% Sublimated
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-31