(9-(4-BROMOPHENYL))-9H-CARBAZOLE

Product Name: (9-(4-BROMOPHENYL))-9H-CARBAZOLE
CAS No.: 57102-42-8
Chemical Name: (9-(4-BROMOPHENYL))-9H-CARBAZOLE
Synonyms: 3-NBPC;9-(4-Bromophenyl)carbazole;9-(4-BroMophenyl)carbazole90%;9-(4-Bromophenyl)carbazole >N-(4-BroMophenyl)-9H-carbazole;9H-Carbazole,9-(4-broMophenyl)-;9-(4-Bromophenyl)carbazole (9-(4-BROMOPHENYL))-9H-CARBAZOLE;9-(4-Bromophenyl)-9H-carbazole 98%;9-(4-broMophenyl)-9H-carbazole 4BPC
CBNumber: CB12459465
Molecular Formula: C18H12BrN
Formula Weight: 322.2
MOL File: 57102-42-8.mol

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(9-(4-BROMOPHENYL))-9H-CARBAZOLE Property

Melting point:: 147-151℃
Boiling point:: 452.7±37.0 °C(Predicted)
Density: 1.39±0.1 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
form: Solid
color: White to Light yellow
Water Solubility: Slightly soluble in water.
InChIKey: XSDKKRKTDZMKCH-UHFFFAOYSA-N
CAS DataBase Reference: 57102-42-8

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Safety

HS Code: 29339900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: B3554
Product name: 9-(4-Bromophenyl)carbazole
Purity: >98.0%(GC)
Packaging: 1g
Price: $41
Updated: 2025/07/31

TCI Chemical

Product number: B3554
Product name: 9-(4-Bromophenyl)carbazole
Purity: >98.0%(GC)
Packaging: 5g
Price: $119
Updated: 2025/07/31

Biosynth Carbosynth

Product number: FB42951
Product name: (9-(4-Bromophenyl))-9H-carbazole
Packaging: 5G
Price: $60
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK1023050
Product name: 9-(4-Bromophenyl)carbazole
Purity: 98%
Packaging: 1g
Price: $84
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB42951
Product name: (9-(4-Bromophenyl))-9H-carbazole
Packaging: 10g
Price: $100
Updated: 2021/12/16

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(9-(4-BROMOPHENYL))-9H-CARBAZOLE Chemical Properties,Usage,Production

Chemical Properties

White to light yellow solid

Uses

It plays an important role as intermediate for pharmaceutical, organic synthesis and organic light-emitting diode(OLED).

Synthesis

106-37-6

86-74-8

57102-42-8

Step 2: Synthesis of 4-(carbazol-9-yl)diphenylamine (abbreviation: YGA); In Step 2, YGA was synthesized according to (i) and (ii) shown below. (i) Synthesis of 9-(4-bromophenyl)carbazole; First, 56 g (240 mmol) of 1,4-dibromobenzene, 31 g (180 mmol) of carbazole, 4.6 g (24 mmol) of copper iodide, 16 g (480 mmol) of potassium carbonate and 2.1 g (8 mmol) of 18-crown-6-ether were added to a 300 mL three-necked flask and air displaced with nitrogen. 66 g (480 mmol) of potassium carbonate and 2.1 g (8 mmol) of 18-crown-6-ether were added to a 300 mL three-necked flask and the air in the flask was replaced with nitrogen. Subsequently, 8 mL of N,N-dimethylpropyleneurea (abbreviation: DMPU) was added to the flask and the reaction mixture was stirred at 180 °C for 6 hours. After completion of the reaction, the mixture was cooled to room temperature and the precipitate was removed by filtration. The filtrate was washed sequentially with dilute hydrochloric acid, saturated aqueous sodium bicarbonate solution and saturated aqueous sodium chloride solution, and then dried with anhydrous magnesium sulfate. After drying, the solution was naturally filtered and concentrated, and the resulting oil was purified by silica gel column chromatography (eluent: hexane/ethyl acetate = 9:1) and finally recrystallized with chloroform and hexane. Finally, 21 g of light brown plate-like crystals of the target product 9-(4-bromophenyl)carbazole were obtained in 35% yield.

References

[1] Chemistry Letters, 2008, vol. 37, # 9, p. 986 - 987
[2] Patent: CN106883163, 2017, A. Location in patent: Paragraph 0030; 0031; 0032; 0033
[3] New Journal of Chemistry, 2010, vol. 34, # 7, p. 1317 - 1322
[4] Patent: CN105585577, 2016, A. Location in patent: Paragraph 0220; 0221; 0222; 0223; 0224
[5] Patent: EP2292618, 2011, A1. Location in patent: Page/Page column 17

(9-(4-BROMOPHENYL))-9H-CARBAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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(9-(4-BROMOPHENYL))-9H-CARBAZOLE Suppliers

Americas 1 China 288 Europe 1 Germany 1 India 3 Japan 2 South Korea 1 United Kingdom 2 United States 15 Global 314

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View Lastest Price from (9-(4-BROMOPHENYL))-9H-CARBAZOLE manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: (9-(4-BROMOPHENYL))-9H-CARBAZOLE 57102-42-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-05-16

Hebei Chuanghai Biotechnology Co., Ltd

Product: 9-(4-Bromophenyl)carbazole 57102-42-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-25

Zhengzhou Anbu Chem Co.,Ltd

Product: (9-(4-BROMOPHENYL))-9H-CARBAZOLE 57102-42-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1000KGS
Release date: 2023-04-24

57102-42-8, (9-(4-BROMOPHENYL))-9H-CARBAZOLERelated Search:

3-bromo-9-phenyl-9H-carbazole Carbazole 9,9'-(5-bromo-1,3-phenylene)bis(9H-carbazole) 9,9-dimethylcarbazine 9-[1,1'-biphenyl]-4-yl-3,3'-Bi-9H-carbazole N-(2-BroMophenyl)-9H-carbazole 9-(3-bromophenyl)carbazole 2-Bromo-9-phenyl-9H-carbazole 3-broMo-9-(naphthalen-1-yl)-9H-carbazole 3-Iodo-N-phenylcarbazole N,N'-Bis(3-methylphenyl)-N,N'-bis(phenyl)benzidine

N-(4-BroMophenyl)-9H-carbazole

9H-Carbazole, 9-(4-broMophenyl)- Carbazole, 9-(p-broMophenyl)- (6CI)

9-(4-broMophenyl)-9H-carbazole 4BPC

9-(4-BroMophenyl)carbazole90%

9H-Carbazole,9-(4-broMophenyl)-

(9-(4-BROMOPHENYL))-9H-CARBAZOLE

9-(4-Bromophenyl)carbazole

3-NBPC

9-(4-Bromophenyl)carbazole&nbsp

9-(4-Bromophenyl)carbazole &gt

(9-(4-BROMOPHENYL))-9H-CARBAZOLE ISO 9001：2015 REACH

9-(4-Bromophenyl)-9H-carbazole 98%

57102-42-8

57102-42-7

S-7102-42-8

C18H12BrN

OLED

organic chemicals and derivatives/others

OLED materials,pharm chemical,electronic