ChemicalBook > CAS DataBase List > 1-(TRIISOPROPYLSILYL)PYRROLE

1-(TRIISOPROPYLSILYL)PYRROLE

Product Name
1-(TRIISOPROPYLSILYL)PYRROLE
CAS No.
87630-35-1
Chemical Name
1-(TRIISOPROPYLSILYL)PYRROLE
Synonyms
DK940;TIPS-pyrrole;N-TRIISOPROPYLSILYL PYRROLE;1-(TRIISOPROPYLSILYL)PYRROLE;1-TRIISOPROPYLSILANYL-1H-PYRROLE;1-(Triisopropylsilyl)pyrrole 95%;1-(Triisopropylsilyl)-1H-pyrrole;Tri-iso-propyl(pyrrol-1-yl)silane;tri(propan-2-yl)-pyrrol-1-ylsilane;tri(propan-2-yl)-(1-pyrrolyl)silane
CBNumber
CB1250712
Molecular Formula
C13H25NSi
Formula Weight
223.43
MOL File
87630-35-1.mol
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1-(TRIISOPROPYLSILYL)PYRROLE Property

Boiling point:
78 °C0.4 mm Hg(lit.)
Density 
0.904 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.492(lit.)
Flash point:
224 °F
storage temp. 
Inert atmosphere,2-8°C
pka
-2.55±0.70(Predicted)
form 
clear liquid
color 
Colorless to Almost colorless
Specific Gravity
0.904
Water Solubility 
Not miscible in water.
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
BRN 
3540663
CAS DataBase Reference
87630-35-1(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
20-22-36
Safety Statements 
24/25-26
WGK Germany 
3
HS Code 
2933998090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
377945
Product name
1-(Triisopropylsilyl)pyrrole
Purity
95%
Packaging
5ml
Price
$47.6
Updated
2024/03/01
Sigma-Aldrich
Product number
377945
Product name
1-(Triisopropylsilyl)pyrrole
Purity
95%
Packaging
25ml
Price
$80
Updated
2024/03/01
TCI Chemical
Product number
T1677
Product name
1-(Triisopropylsilyl)pyrrole
Purity
>96.0%(GC)
Packaging
5mL
Price
$106
Updated
2024/03/01
TCI Chemical
Product number
T1677
Product name
1-(Triisopropylsilyl)pyrrole
Purity
>96.0%(GC)
Packaging
25mL
Price
$340
Updated
2024/03/01
Alfa Aesar
Product number
L13152
Product name
1-(Triisopropylsilyl)pyrrole, 95%
Packaging
5g
Price
$85.65
Updated
2024/03/01
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1-(TRIISOPROPYLSILYL)PYRROLE Chemical Properties,Usage,Production

Uses

1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2?-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).

Uses

1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of:

  • ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate
  • heterocyclic base, 3-nitropyrrole
  • 3-nitropyrrole, required for the synthesis of 1 -(2′-deoxy-β-D-ribofuranosyl)-3-nitropyrrole

General Description

1-(Triisopropylsilyl)pyrrole (TISP), a heterocyclic building block, is a pyrrole derivative. TISP has been reported to generate pyrrolic cation radicals during cyclovoltammetric studies, via electroreduction. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).

1-(TRIISOPROPYLSILYL)PYRROLE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-(TRIISOPROPYLSILYL)PYRROLE Suppliers

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View Lastest Price from 1-(TRIISOPROPYLSILYL)PYRROLE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
1-(TRIISOPROPYLSILYL)PYRROLE 87630-35-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

87630-35-1, 1-(TRIISOPROPYLSILYL)PYRROLERelated Search:


  • 1-TRIISOPROPYLSILANYL-1H-PYRROLE
  • 1-(TRIISOPROPYLSILYL)PYRROLE
  • N-TRIISOPROPYLSILYL PYRROLE
  • tri(propan-2-yl)-(1-pyrrolyl)silane
  • 1-[tris(propan-2-yl)silyl]-1H-pyrrole
  • 1-(Triisopropylsilyl)pyrrole 95%
  • 1H-Pyrrole, 1-[tris(1-Methylethyl)silyl]-
  • 1-(Triisopropylsilyl)-1H-pyrrole
  • TIPS-pyrrole
  • Tri-iso-propyl(pyrrol-1-yl)silane
  • 1-[Tris(1-Methylethyl)silyl]-1H-pyrrole
  • tri(propan-2-yl)-pyrrol-1-ylsilane
  • <font color="#ff0000">87630-35-1</font>
  • DK940
  • 87630-35-1
  • 87630-35-0
  • C13H24NSi
  • Trimethylsilylazide, etc.
  • Si (Classes of Silicon Compounds)
  • Reagents for Conducting Polymer Research
  • Pyrroles (for Conduting Polymer Research)
  • Heterocyclic Building Blocks
  • Pyrroles
  • Si-N Compounds
  • Building Blocks
  • Pyrrole&Pyrrolidine&Pyrroline
  • Functional Materials
  • Pyrroles (for Conduting Polymer Research)
  • Reagents for Conducting Polymer Research
  • Si (Classes of Silicon Compounds)
  • Si-N Compounds
  • Trimethylsilylazide, etc.
  • Building Blocks
  • Heterocyclic Building Blocks
  • Pyrroles